Long chain base and Ceramide
DATA No : DLB0017
INFORMANT : Akira Hayashi
NAME : Hexadeca-X-4-sphingenine/ D-Erythro-1,3-dihydroxy-2-amino-trans-4-hexadecene (
Ref. 0016)
| COMMON NAME | : | |
| SYMBOL | : | d16:1(4) |
| FORMULA | : | C16H33O2N1 MOL.WT (average) : 271.439 |
| PHYSICAL AND CHEMICAL PROPERTIES |
| MELTING POINT | : | |
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| BOILING POINT | : | |
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| REFRACTIVE INDEX | : | |
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| OPTICAL ROTATION | : | |
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| DENSITY | : | |
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| SOLUBILITY | : | |
| UV SPECTRA | : | |
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| IR SPECTRA | : | |
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| NMR SPECTRA | : |
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| MASS SPECTRA | : | Ei/MS of N-acetyl-O-TMS derivative (Ref. 0031); EI/MS of O-TMS derivative (Ref. 0030).
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| OTHER SPECTRA | : |
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Sphingomyelin of cow milk(21.0 mole%) (
Ref. 0016); Sphingomyelin fo human serum (
Ref. 0022); Mild alkali stable lipids of larvae of house fly, Musca domestica (23%) (
Ref. 0019); Sphingolipids of atherosclerotic human aorta (
Ref. 0017); Sphingomyelin of human plasma(
Ref. 0014/
0020); Vental cord of Procambarus clark II (crawfish) ; Ceramide aminoethylphosphonate isolated from the oyster(adductor muscle 75.9%, gills 18.4%, mantle 20.4%, viscera 10.8%)(
Ref. 0005); Five kinds of glycolipids from Turbo cornutus (9.7-23.2%) (
Ref. 0010); Aminoalkylphosphonyl cerebroside isolated from the viscera of Turbo cornutus (2.7%) (
Ref. 0008); Aminoalkylphosphonyl cerebroside of the muscle of Turbo cornutus (5.3%) (
Ref. 0007); Sphingophosphonolipid obtained from 8 kinds of shellfish (
Ref. 0006); Sphingolipids of Barnea dilatata (cerebroside 20.7%, ceramide aminoethylphosphonate 5.1%) (
Ref. 0003); five kinds of Gala-6 series sphingoglycolipids (1.9-5.0%) (
Ref. 0011); N-methylaminoethyl trigalactosylceramide of Turbo cornutus (6.0%) (
Ref. 0009).
[0003]
| AUTHOR | : | Karlsson, K.-A. |
| TITLE | : | On the chemistry and occurrence of sphingolipid long-chain bases. PubMed ID:4394487 |
| JOURNAL | : | Chem. Phys. Lipids |
| VOL | : | 5 PAGE : 6 -43 (1970) |
[0005]
| AUTHOR | : | Matsubara, T. |
| TITLE | : | The structure and distribution of ceramide aminoethylphosphonates in the oyster (Ostrea gigas). PubMed ID:1137715 |
| JOURNAL | : | Biochim. Biophys. Acta |
| VOL | : | 388 PAGE : 353 -360 (1975) |
[0006]
| AUTHOR | : | Matsubara, T. |
| TITLE | : | Distribution of the dienic long chain bases in shellfish sphingophosphonolipids. |
| JOURNAL | : | Chem. Phys. Lipids |
| VOL | : | 14 PAGE : 247 -259 (1975) |
[0007]
| AUTHOR | : | Hayashi, A. and Matsuura, F. |
| TITLE | : | Characterization of aminoalkylphophonyl cerebrosides in muscle tissue of Turbo cornutus. PubMed ID:699219 |
| JOURNAL | : | Chem. Phys. Lipids |
| VOL | : | 22 PAGE : 9 -23 (1978) |
[0008]
| AUTHOR | : | Matsuura, F. |
| TITLE | : | Phosphonosphingoglycolipid, a novel sphingolipid from the viscera of Turbo cornutus. PubMed ID:890866 |
| JOURNAL | : | Chem. Phys. Lipids |
| VOL | : | 19 PAGE : 223 -242 (1977) |
[0009]
| AUTHOR | : | Hayashi, A. and Matsubara, T. |
| TITLE | : | A new homologue of phosphonosphingolipid, N-methylaminoethyl-phosphonyltrigalactosylceramide. |
| JOURNAL | : | Biochim. Biophys. Acta |
| VOL | : | 1006 PAGE : 89 -96 (1989) |
[0010]
| AUTHOR | : | Matsubara, T., and Hayashi, A. |
| TITLE | : | Structural studies on glycolipid of shellfish. III. Novel glycolipids from Turbo cornutus PubMed ID:6263873 |
| JOURNAL | : | J Biochem (Tokyo). |
| VOL | : | 89 PAGE : 645-650 (1981) |
[0011]
| AUTHOR | : | Matsubara, T., and Hayashi, A. |
| TITLE | : | Structural studies on glycolipids of shellfish. V. Gala-6 series glycosphingolipids of the marine snail, Chlorostoma argyrostoma turbinatum PubMed ID:3011773 |
| JOURNAL | : | J Biochem (Tokyo). |
| VOL | : | 99 PAGE : 1401-1408 (1986) |
[0014]
| AUTHOR | : | Polito, A. J., Akita, T., and Sweeley, C. C. |
| TITLE | : | Gas chromatography and mass spectrometry of sphingolipid bases. Characterization of sphinga-4,14-dienine from plasma sphingomyelin PubMed ID:5660077 |
| JOURNAL | : | Biochemistry. |
| VOL | : | 7 PAGE : 2609-2614 (1968) |
[0016]
| AUTHOR | : | Morrison, W. R. |
| TITLE | : | Polar lipids in bovine milk. I. Long-chain bases in sphingomyelin PubMed ID:5816447 |
| JOURNAL | : | Biochim Biophys Acta. |
| VOL | : | 176 PAGE : 537-546 (1969) |
[0017]
| AUTHOR | : | Panganamala, R. V., Geer, J. C., and Cornwell, D. G. |
| TITLE | : | Long-chain bases in the sphingolipids of atherosclerotic human aorta PubMed ID:4307832 |
| JOURNAL | : | J Lipid Res. |
| VOL | : | 10 PAGE : 445-455 (1969) |
[0019]
| AUTHOR | : | Bieber, L. L., O'Connor, J. D., and Sweeley, C. C. |
| TITLE | : | The occurrence of tetradecasphing-4-enine and hexadecasphing-4-enine as the principal sphingosines of Musca domestica larvae and adults PubMed ID:5811205 |
| JOURNAL | : | Biochim Biophys Acta. |
| VOL | : | 187 PAGE : 157-159 (1969) |
[0020]
| AUTHOR | : | Karlsson, K.-A. |
| TITLE | : | Studies on sphingosines. 6. C16- and C17-sphingosines, hitherto unknown sphingosines. |
| JOURNAL | : | Acta Chem. Scand. |
| VOL | : | 18 PAGE : 2395 -2396 (1964) |
[0022]
| AUTHOR | : | Hirvisalo, E. L., and Renkonen, O. |
| TITLE | : | Composition of human serum sphingomyelins PubMed ID:4312626 |
| JOURNAL | : | J Lipid Res. |
| VOL | : | 11 PAGE : 54-59 (1970) |
[0030]
| AUTHOR | : | Matsubara, T. and Hayashi, A. |
| TITLE | : | Identification of molecular species of ceramide aminoethyl phosphonate from oyster adductor by gas-liquid chromatography-mass spectrometry. PubMed ID:4693503 |
| JOURNAL | : | Biochim. Biophys. Acta |
| VOL | : | 296 PAGE : 171 -178 (1973) |
[0031]
| AUTHOR | : | Mishima, Y. and Hayashi, A. |
| TITLE | : | Studies on sphingolipids of Barnea (Umitakea) dilatata japonica I. Cerebroside and Ceramide aminoethylphosphonate (in Japanene ) |
| JOURNAL | : | Japan. Oil Chem. Soc. (Yukagaku ) |
| VOL | : | 27 PAGE : 92 -97 (1978) |
Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.
