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Ether type lipid


DATA No : EEL0003 INFORMANT : Yosuke Koga

NAME : 1-b-D-glucopyranosyl-2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-b-D-glucopyranosyl-2,3-di-O-phytanylglycerol(Ref. 0002)

COMMON NAME: glucosyl archaeol(Ref. 0002)
SYMBOL: Glc ArOH(Ref. 0002)
FORMULA: C49H98O8 MOL.WT (average) : 815.298

BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
MELTING POINT:

BOILING POINT:

REFRACTIVE INDEX:

OPTICAL ROTATION:[a]D = -11.30; MD = -91.98(Ref. 0002)

DENSITY:

SOLUBILITY:
SPECTRAL DATA
UV SPECTRA:

IR SPECTRA:

NMR SPECTRA:13C-NMR, 68.84 (C-1 of sn-2 phytanyl chain), 70.18 (C-1 of sn-3 phytanyl chain), 69.42 (C-1 of glycerol), 78.39 (C-2 of glycerol), 70.84 (C-3 of glycerol), 103.87 (C-1 of sugar), 74.10 (C-2 of sugar), 76.90 (C-3 of sugar), 70.38 (C-4 of sugar), 76.68 (C-5 of sugar), 61.82 (C-6 of sugar)(Ref. 0002)

MASS SPECTRA:

OTHER SPECTRA:
CHROMATOGRAM DATA
TLC chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf=0.95(Ref. 0002)chromatogram :
[Chromatogram 0001]
SOURCE
Methanococcus voltae(Ref. 0002)
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE

REFERENCES
[0002]
AUTHOR:Ferrante,G., Ekiel,I., and Sprott,G.D.
TITLE:Structural Characterization of the Lipids of Methanococcus voltae, Including a Novel N-Acetylglucosamine 1-Phosphate Diether. PubMed ID:3782154
JOURNAL:J. Biol. Chem.
VOL:261 PAGE : 17062 -17066 (1986)
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Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.