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Ether type lipid


DATA No : EEL0006 INFORMANT : Yosuke Koga

NAME : 2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phospho-1''-[6''-O-(2'''-amino-deoxy-a-D-glucopyranosyl)]-1''-D-myo-inositol/2,3-di-O-phytanyl-sn-glycerol-1-phospho(glucosaminyl)-myo-inositol(Ref. 0009)

COMMON NAME: archaetidyl(glucosaminyl)-myo-inositol(Ref. 0009)
SYMBOL: Ar(GlcN)I(Ref. 0009)
FORMULA: C55H110NO15P MOL.WT (average) : 1056.433

BIOLOGICAL ACTIVITY

PHYSICAL AND CHEMICAL PROPERTIES
MELTING POINT:

BOILING POINT:

REFRACTIVE INDEX:

OPTICAL ROTATION:

DENSITY:

SOLUBILITY:
SPECTRAL DATA
UV SPECTRA:

IR SPECTRA:-CH3 and -CH2-, 2840-2950, 1465, 1375cm-1; -CH(CH3)2, 1360cm-1; ether C-O-C, 1110 cm-1; P=O, P-O, P-O-C, 1220, 1100, 1050cm-1; -NH2, 3390, 1640, 1560cm-1; -OH, 3400cm-1;(Ref. 0009)

NMR SPECTRA:spectra :
[Spectrum 0002],
[Spectrum 0003] (Ref. 0009)

MASS SPECTRA:positive FAB m/z 1056 (m+1),

OTHER SPECTRA:
CHROMATOGRAM DATA
chromatogram :
[Chromatogram 0002] (Ref. 0003)
SOURCE
Methanosarcina barkeri(Ref. 0009)
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE

REFERENCES
[0003]
AUTHOR:Nishihara,M., and Koga,Y.
TITLE:Hydroxyarchaetidylserine and Hydroxyarchaetidyl-myo-Inositol in Methanosarcina barkeri: Polar Lipids with a New Ether Core Portion. PubMed ID:1901027
JOURNAL:Biochim. Biophys. Acta
VOL:1082 PAGE : 211 -217 (1991)
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[0009]
AUTHOR:Nishihara,M., Utagawa,M., Akutsu,H., and Koga,Y.
TITLE:Archaea Contain a Novel Diether Phosphoglycolipid with a Polar Head Group Identical to the Conserved Core of Eucaryal Glycosyl Phosphatidylinositol. PubMed ID:1535621
JOURNAL:J. Biol. Chem.
VOL:267 PAGE : 12432 -12435 (1992)
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Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.