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Glycoglycerolipid and others


DATA No : GGG0015 INFORMANT : Ineo Ishizuka

NAME : 6-Sulfo-a-D-quinovopyranosyl-(1-3')-1',2'-di-O-acyl-sn-glycerol

COMMON NAME: 6-Sulfoquinovosyldiacylglycerol, SQDG
SYMBOL: Acidic lipid K
FORMULA: MOL.WT (average) :


Download ChemDraw structure data
BIOLOGICAL ACTIVITY
Relation with photosynthesis (Ref. 0208).
PHYSICAL AND CHEMICAL PROPERTIES
MELTING POINT:

BOILING POINT:

REFRACTIVE INDEX:

OPTICAL ROTATION:

DENSITY:

SOLUBILITY:
SPECTRAL DATA
UV SPECTRA:

IR SPECTRA:1160, 1030-1050, sulfonate; 1730, acyl ester (Ref. 0107)

NMR SPECTRA:1-NMR: 4.87ppm, H-1; 13C-NMR (Ref. 0123) 1H-NMR (2D) (Ref. 0242)

MASS SPECTRA:FDMS: m/z 601, [M+Na]+ (Ref. 0123) FAB-MS (Ref. 0242)

OTHER SPECTRA:Absorption of the anthrone sulfuric acid assay, 592 nm (Ref. 0107)
CHROMATOGRAM DATA

SOURCE
Review (Ref. 0208). Bacillus acidocaldarius, 43.2% of the acidic lipid fraction (Ref. 0107); plant chloroplast membrane (Ref. 0208); sea urchin Anthocidaris crassispina, the shell, 30 nmol/g (Ref. 0123); sea urchin Pseudocentrotus depressus, eggs and sperms (Ref. 0124). Sea urchin, Strongylocentrotus intermedius (Ref. 0242).
CHEMICAL SYNTHESIS

METABOLISM

GENETIC INFORMATION

NOTE
Determination of molecular species by hydrazinolysis (Ref. 0122)
Fattu acids(Ref. 0210)
REFERENCES
[0107]
AUTHOR:Langworthy, T. A., Mayberry, W. R., and Smith, P. F.
TITLE:A sulfonolipid and novel glucosamidyl glycolipids from the extreme thermoacidophile Bacillus acidocaldarius PubMed ID:7302
JOURNAL:Biochim Biophys Acta.
VOL:431 PAGE : 550-569 (1976)
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[0122]
AUTHOR:Heinze, F. J., Linscheid, M., and Heinz, E.
TITLE:Release of diacylglycerol moieties from various glycosyl diacylglycerols PubMed ID:6331223
JOURNAL:Anal Biochem.
VOL:139 PAGE : 126-133 (1984)
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[0123]
AUTHOR:Kitagawa,I.,Hamamoto,Y., and Kobayashi,M.
TITLE:Sulfoglycolipid from the sea urcin Anthocidaris crassispina A. Agassiz.
JOURNAL:Chem. Pharm. Bull.
VOL:27 PAGE : 1934 -1937 (1979)
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[0124]
AUTHOR:Isono, Y., and Nagai, Y.
TITLE:Biochemistry of glycolipids of sea urchin gametes. I. Separation and characterization of new type of sulfolipid and sialoglycolipid PubMed ID:4291271
JOURNAL:Jpn J Exp Med.
VOL:36 PAGE : 461-476 (1966)
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[0208]
AUTHOR:Ishizuka, I.
TITLE:Chemistry and functional distribution of sulfoglycolipids.
JOURNAL:Progr. Lipid Res.
VOL:36 PAGE : 245 -319 (1998)
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[0210]
AUTHOR:Gigg, J., And Gigg, R.(1990) Synthesis of glycoglycerolipids (Kates, M. ed.), pp489-506, Plenum Press, New York
TITLE:
JOURNAL:
VOL: PAGE : - (1990)
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[0242]
AUTHOR:Sahara, H., Ishikawa, M., Takahashi, N., Ohtani, S., Sato, N., Gasa, S., Akino, T. and Kikuchi, K.
TITLE:In vivo anti-tumour effect of 3'-sulphonoquinovosyl 1'-monoacylglyceride isolated from sea urchin (Strongylocentrotus intermedius) intestine. PubMed ID:9020475
JOURNAL:Brit. J. Cancer
VOL:75 PAGE : 324 -332 (1997)
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Last updated June 19, 2007. Copyright © 1989-2007 Japanese Conference on the Biochemistry of Lipids (JCBL). All rights reserved.