Difference between revisions of "LBF18203HP01"
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|Chemical Synthesis= | |Chemical Synthesis= | ||
|Metabolism= | |Metabolism= | ||
| + | |Biological Activity=It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]]. | ||
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{{Lipid/Footer}} | {{Lipid/Footer}} | ||
Revision as of 06:00, 7 January 2010
| LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
| IDs and Links | |
|---|---|
| LipidBank | |
| DFA8056 | |
| LipidMaps | |
| LMFA01040040 | |
| CAS | |
| KEGG | |
| {{{KEGG}}} | |
| KNApSAcK | |
| LBF18203HP01.mol | |
| Methyl-10,12-Epidioxy-9-Hydroperoxy-13,15-Octadecadienoate | |
|---|---|
| |
| Structural Information | |
| Systematic Name | Methyl-10,12-Epidioxy-9-Hydroperoxy-13,15-Octadecadienoate |
| Common Name |
|
| Symbol | |
| Formula | C19H32O6 |
| Exact Mass | 356.219888756 |
| Average Mass | 356.45378 |
| SMILES | C(O1)(CC(C=CC=CCC)O1)C(OO)CCCCCCCC(=O)OC |
| Physicochemical Information | |
| Melting Point | |
| Boiling Point | |
| Density | |
| Optical Rotation | |
| Refractive Index | |
| Solubility | |
| Source | Auto oxydation of linoleate Neff_WE et al. Coxon_DT et al.. Oxydation of linoleate in the presence of Fe(III)-ascorbic acid Toyoda_I et al.. Photoenhancemant of linoleate peroxydation[Type II] Neff_WE et al. Neff_WE et al.. Production mechanism Frankel_EN Frankel_EN . |
| Chemical Synthesis | |
| Metabolism | |
| Biological Activity | It reacts with DNA in the presence of Fe ions and ascorbic acid Fujimoto_K et al.. |
| Genetic Information | |
| Note | |
| Spectral Information | |
| Mass Spectra | GC-EI-MS(after reduction(PH3P) and TMS) Neff_WE et al.: m/e=397[M-CH3]; 259[SMTO=CH(CH2)7COOCH3]; GC-EI-MS(after reduction with NaBH4 or KI andTMS) Frankel_EN et al.: m/e=259[SMTO=CH(CH2)7COOCH3]; 183[SMTO=CH-CH=CH-CH=CH-CH2CH3] |
| UV Spectra | Conjugated diene: lmax=231-236nm ToyodaIet al. Neff_WE et al. Coxon_DT et al. Neff_WE et al. |
| IR Spectra | OOH group: 3520 cm-1[free], 3700-3100cm-1[bonded]; olefinic protons: 3020-3000cm-1; CONJUGATE TRANS, CIS DIENES: 990-980cm-1, 955-947cm-1 Neff_WE et al. Coxon_DT et al. Neff_WE et al. Neff_WE et al. |
| NMR Spectra | 1H-NMR Neff_WE et al. Neff_WE et al. Coxon_DT et al.: C9: 3.92-4.21; C10: 4.45-4.47; C11: 2.19-2.47, 2.81-2.87; C12: 4.77-4.80; C13: 5.57-5.62; C14: 6.65-6.68; C15: 5.96-6.65; C16: 5.50-5.55; OOH: 9.05-9.56ppm; J13-14=15Hz[C13-14 : trans]; J15-16=10Hz[C15-16: cis]13C-NMR Neff_WE et al. Neff_WE et al.: C9: 86.0; C10, 12: 83.8, 83.0 |
| Other Spectra | |
| Chromatograms | |
| Reported Metabolites, References | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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