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| No | Structure | COMMON NAME | NAME | DATA No | INFORMANT | SYMBOL | FORMULA | MOL.WT(ave) | Download | BIOOGICAL ACTIVITY | PHYSICAL AND CHEMICAL PROPERTIES | SPECTRAL DATA | CHROMATOGRAM DATA | SOURCE | CHEMICAL SYNTHESIS | METABOLISM | GENETIC INFORMATION | NOTE | REFERENCES | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| MELTING POINT | BOILING POINT | DENSITY | REFRACTIVE INDEX | OPTICAL ROTATION | SOLUBILITY | UV SPECTRA | IR SPECTRA | NMR SPECTRA | MASS SPECTRA | OTHER SPECTRA | ||||||||||||||||||
| 1 |  |
archaetidic acid/diether analog of phosphatidic acid(Ref. 0001) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphate/ 2,3-di-O-phytanyl-sn-glycerol-1-phosphate(Ref. 0001) |
EEL0001 | Yosuke Koga |
AA(Ref. 0001) |
C43H89O6P | 733.137 | -CH2-, 2830-2960, 1460, 1375cm-1; -CH(CH3)2, 1360cm-1; ether C-O-C, 1110 cm-1; P=O, P-0, P-O-C, 1210, 1100, 1050cm-1(Ref. 0001) |
31P-NMR: 0.92 ppm (pH1.6); 1.47 ppm (pH3.8); 2.07 ppm (pH7.5); 5.38 ppm (pH10.1); 5.63 ppm (pH12.8) (Ref. 0001)spectrum : [Spectrum 0001] |
FAB m/z 733.8 (M+1)+ |
TLC chloroform-methanol-14M aqueous ammonia (60:35:8) Rf=0.41; chloroform-methanol-acetic acid-water (85:30:15:5) Rf=0.85(Ref. 0001) |
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| 2 |  |
caldarchaetidic acid/tetraether analog of phosphatidic acid(Ref. 0001) |
EEL0002 | Yosuke Koga |
CA(Ref. 0001) |
C86H173O9P | 1382.262 | -OH, 3400, 1040cm-1; -CH2-, 2830-2960, 1460, 1375cm-1; ether C-O-C, 1110 cm-1; P=O, P-0, P-O-C, 1210, 1100, 1050cm-1; absence of -CH(CH3)2, 1360cm-1(Ref. 0001) |
31P-NMR: 0.92 ppm (pH1.6); 1.36 ppm (pH3.8); 2.05ppm (pH7.5); 5.30ppm (pH10.1); 5.66ppm (pH12.8)(Ref. 0001) |
FAB m/z 1381.9 (M+1)+ |
TLC chloroform-methanol-14M aqueous ammonia (60:35:8) Rf=0.45; chloroform-methanol-acetic acid-water (85:30:15:5) Rf=0.88(Ref. 0001) |
Methanobacterium thermoautotrophicum(Ref. 0001) |
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| 3 |  |
glucosyl archaeol(Ref. 0002) |
1-b-D-glucopyranosyl-2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-b-D-glucopyranosyl-2,3-di-O-phytanylglycerol(Ref. 0002) |
EEL0003 | Yosuke Koga |
Glc ArOH(Ref. 0002) |
C49H98O8 | 815.298 | [a]D = -11.30; MD = -91.98(Ref. 0002) |
13C-NMR, 68.84 (C-1 of sn-2 phytanyl chain), 70.18 (C-1 of sn-3 phytanyl chain), 69.42 (C-1 of glycerol), 78.39 (C-2 of glycerol), 70.84 (C-3 of glycerol), 103.87 (C-1 of sugar), 74.10 (C-2 of sugar), 76.90 (C-3 of sugar), 70.38 (C-4 of sugar), 76.68 (C-5 of sugar), 61.82 (C-6 of sugar)(Ref. 0002) |
TLC chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf=0.95(Ref. 0002)chromatogram : [Chromatogram 0001] |
Methanococcus voltae(Ref. 0002) |
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| 4 |  |
b-hydroxyarchaetidylserine(Ref. 0003) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphoserine/ 2,3-di-O-phytanyl-sn-glycerol-1-phosphoserine(Ref. 0003) |
EEL0004 | Yosuke Koga |
b-OH-AS(Ref. 0003) |
C46H94O9NP | 836.214 | positive FAB m/z 858 (M+Na) (Ref. 0003) |
TLC, chloroform-methanol-conc-aqueous ammonia (65:35:8) Rf=0.37; chloroform-methanol-acetic acid-water (80:30:15:5) Rf=0.38(Ref. 0003)chromatogram : [Chromatogram 0002] (Ref. 0003) |
Methanosarcina barkeri(Ref. 0003) |
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| 5 |  |
b-hydroxyarchaetidyl-myo-inositol(Ref. 0003) |
2-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phospho-myo-inositol |
EEL0005 | Yosuke Koga |
b-OH-AI(Ref. 0003) |
C49H99O12P | 911.277 | positive FAB m/z 933 (M+Na) |
TLC, chloroform-methanol-conc-aqueous ammonia (65:35:8) Rf=0.34; chloroform-methanol-acetic acid-water (80:30:15:5) Rf=0.30(Ref. 0003)chromatogram : [Chromatogram 0002] (Ref. 0003) |
Methanosarcina barkeri(Ref. 0003) |
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| 6 |  |
archaetidyl(glucosaminyl)-myo-inositol(Ref. 0009) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phospho-1''-[6''-O-(2'''-amino-deoxy-a-D-glucopyranosyl)]-1''-D-myo-inositol/2,3-di-O-phytanyl-sn-glycerol-1-phospho(glucosaminyl)-myo-inositol(Ref. 0009) |
EEL0006 | Yosuke Koga |
Ar(GlcN)I(Ref. 0009) |
C55H110NO15P | 1056.433 | -CH3 and -CH2-, 2840-2950, 1465, 1375cm-1; -CH(CH3)2, 1360cm-1; ether C-O-C, 1110 cm-1; P=O, P-O, P-O-C, 1220, 1100, 1050cm-1; -NH2, 3390, 1640, 1560cm-1; -OH, 3400cm-1;(Ref. 0009) |
positive FAB m/z 1056 (m+1), |
Methanosarcina barkeri(Ref. 0009) |
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| 7 |  |
b-hydroxyarchaetidylglycerol(Ref. 0010) |
2-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl)-3-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol-1-phospho-3'''-sn-glycerol/ 2-O-(3'-hydroxy)phytanyl-3-O-phytanyl-sn-glycerol-1-phospho-3''-sn-glycerol |
EEL0007 | Yosuke Koga |
b-OH-AG(Ref. 0010) |
C46H95O9P | 823.215 | TLC, chloroform-methanol-acetic acid-water (90:30:15:4) Rf=0.64; chloroform-methanol-conc-aqueous ammonia (65:35:8) Rf=0.67(Ref. 0010)chromatogram : [Chromatogram 0002] (Ref. 0003) |
Methanosarcina barkeri(Ref. 0010) |
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| 8 |  |
b-hydroxyarchaetidylethanolamine(Ref. 0010) |
2-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol-1-phosphoethanolamine/ 2-O-(3'-hydroxy)phytanyl-3-O-phytanyl-sn-glycerol-1-phosphoethanolamine |
EEL0008 | Yosuke Koga |
b-OH-AE(Ref. 0010) |
C45H94O7NP | 792.204 | TLC, chloroform-methanol-acetic acid-water (90:30:15:4) Rf=0.74; chloroform-methanol-conc-aqueous ammonia (65:35:8) Rf=0.72(Ref. 0010)chromatogram : [Chromatogram 0002] (Ref. 0003) |
Methanosarcina barkeri(Ref. 0010) |
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| 9 |  |
b-hydroxyarchaeol(Ref. 0003) |
2-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 2-O-(3'-hydroxy)phytanyl-3-O-phytanyl-sn-glycerol |
EEL0009 | Yosuke Koga |
b-OH-ArOH(Ref. 0003) |
C43H88O4 | 669.156 | [a]D=+5.65 degree |
13C-NMR, 67.49 (C1 sn-2), 70.23 (C1 sn-3), 39.97 (C2 sn-2), 36.59 (C2 sn-3), 72.47 (C3 sn-2), 29.92 (C3 sn-3), 43.12 (C4 sn-2), 37.31-37.48 (C4 sn-3), 21.49 (C5 sn-2), 24.39 (C5 sn-3), 26.66 (C17 sn-2), 19.76-19.71 (C17 sn-3). Carbon numbers of the hydrocarbon chains are shown. |
positive FAB m/z 691 ([M+Na]); GC-MS of acetylated derivative m/z 397 (M-OC20H40OCOCH3), m/z 355 (OC20H40OCOCH3) |
TLC, light petroleum-ethyl ether-acetic acid (50:50:1) Rf=0.19 (Ref. 0003)chromatogram: [Chromatogram 0003](Ref. 0003) |
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| 10 |  |
b-methoxyarchaeol(Ref. 0011) |
2-O-(3'-methoxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 2-O-(3'-methoxy)phytanyl-3-O-phytanyl-sn-glycerol |
EEL0010 | Yosuke Koga |
b-Me-OH-ArOH(Ref. 0011) |
C44H90O4 | 683.183 | ||||||||||||||||||||
| 11 |  |
b-hydroxyarchaeol methyl ether(Ref. 0011) |
1-O-methyl-2-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-O-methyl-2-O-(3'-hydroxy)phytanyl-3-O-phytanyl-sn-glycerol |
EEL0011 | Yosuke Koga |
b-OH-ArO-Me(Ref. 0011) |
C44H90O4 | 683.183 | Methanosarcina barkeri (methanolysis by-product) (Ref. 0011) |
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| 12 |  |
b-methoxyarchaeol methyl ether(Ref. 0011) |
1-O-methyl-2-O-(3'-methoxy-3',7',11',15'-tetramethyl)hexadecyl-3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-O-methyl-2-O-(3'-methoxy)phytanyl-3-O-phytanyl-sn-glycerol |
EEL0012 | Yosuke Koga |
DMe-OH-ArOH(Ref. 0011) |
C45H92O4 | 697.210 | Methanosarcina barkeri (methanolysis by-product)(Ref. 0011) |
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| 13 |  |
3-O-monophytanyl-sn-glycerol(Ref. 0011) |
3-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol |
EEL0013 | Yosuke Koga |
3-MAGro(Ref. 0011) |
C23H48O3 | 372.625 | chromatogram: [Chromatogram 0003] (Ref. 0003), [Chromatogram 0004]B, [Chromatogram 0005] (Ref. 0011) |
Methanosarcina barkeri (methanolysis by-product) (Ref. 0011) |
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| 14 |  |
glucosyl-galactosyl caldarchaetidyltrimethyl aminopentanetetrol(Ref. 0014) |
D-glucopyranosyl(a1-2)b-D-galactofuranosyl caldarchaetidyl-N,N,N-trimethyl aminopentanetetrol |
EEL0014 | Yosuke Koga |
Glc-Gal-CATMAPT/PGL III (Ref. 0014) |
C106H212O23NP | 1899.784 | 13C-NMR, 107.26 (C1 of Gal), 89.32 (C2 of Gal), 76.79(C3 of Gal), 83.39(C4 of Gal), 71.85 (C5 of Gal), 64.66 (C6of Gal), 99.79 (C1 of Glc), 72.93 (C2 of Glc), 74.60 (C3 of Glc), 71.60 (C4 of Glc), 73.79 (C5 of Glc), 62.73 (C6 of Glc), 67.83 (C1 of TMAPT), 72.35 (C2 of TMAPT), 73.52 (C3 of TMAPT), 73.22 (C4 of TMAPT), 64.66 (C5 of TMAPT), 54.33 (N-CH3of TMAPT), 67.87 (C1 of Gro), 78.68 (C2 of Gro), 71.88 (C3 of Gro), 65.92 (C1 of Gro), 78.95 (C2 of Gro), 71.49 (C3of Gro) (Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 15 |  |
galactosyl-galactosyl caldarchaetidyltrimethyl aminopentanetetrol(Ref. 0014) |
D-galctofuranosyl(b1-6)b-D-galactofuranosyl caldarchaetidyl-N,N,N-trimethyl aminopentanetetrol |
EEL0015 | Yosuke Koga |
Gal-Gal-CATMAPT/PGL IV (Ref. 0014) |
C106H212O23NP | 1899.784 | 13C-NMR, 109.25 (C1 of Gal), 81.92 (C2 of Gal), 79.06(C3 of Gal), 86.07(C4 of Gal), 70.97 (C5 of Gal), 70.42 (C6 of Gal), 109.68 (C1 of Gal), 81.92 (C2 of Gal), 79.06 (C3 of Gal), 85.51 (C4 of Gal), 72.12 (C5 of Gal), 64.03 (C6 of Gal), 67.72 (C1 of TMAPT), 62.33 (C2 of TMAPT), 73.47 (C3 of TMAPT), 73.19 (C4 of TMAPT), 64.6 (C5 of TMAPT), 54.21 (N-CH3 of TMAPT), 67.72 (C1 of Gro), 78.55(C2 of Gro), 71.69 (C3 of Gro), 65.87 (C1 of Gro), 78.90(C2 of Gro), 71.86 (C3of Gro) (Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 16 |  |
glucosyl-galactosyl caldarchaetidyldimethyl aminopentanetetrol(Ref. 0014) |
D-glucopyranosyl(a1-2)b-D-galactofuranosyl caldarchaetidyl-N,N-dimethyl aminopentanetetrol |
EEL0016 | Yosuke Koga |
Glc-Gal-CADMAPT/PGL VI (Ref. 0014) |
C105H208O22NP | 1867.742 | 13C-NMR, 107.19 (C1 of Gal), 89.11 (C2 of Gal), 76.81(C3 of Gal), 83.57 (C4 of Gal), 71.7 (C5 of Gal), 64.69 (C6of Gal), 99.70 (C1 of Glc), 72.85 (C2 of Glc), 74.55 (C3 of Glc), 71.61 (C4 of Glc), 73.78 (C5 of Glc), 62.77 (C6 of Glc), 60.48 (C1 of DMAPT), 72.05 (C2 of DMAPT), 73.20 (C3 of DMAPT), 72.85 (C4 of DMAPT), 64.37(C5 of DMAPT), 42.42,44.85 (N-CH3 of DMAPT), 67.83 (C1 of Gro), 78.63 (C2 of Gro), 71.86 (C3 of Gro), 66.30(C1 of Gro), 78.87 (C2 of Gro), 71.61C3of Gro) (Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 17 |  |
galactosyl-galactosyl caldarchaetidyl dimethylaminopentanetetrol(Ref. 0014) |
D-galactofuranosyl(b1-6)b-D-galactofuranosyl caldarchaetidyldimethyl aminopentanetetrol |
EEL0017 | Yosuke Koga |
Gal-Gal-CADMAPT/PGL VI I (Ref. 0014) |
C105H208O22NP | 1867.742 | 13C-NMR, 109.22 (C1 of Gal), 81.76 (C2 of Gal), 79.08 (C3 of Gal), 86.21 (C4 of Gal), 70.94 (C5 of Gal), 70.41 (C6 of Gal), 109.66(C1 of Gal), 81.76 (C2 of Gal), 79.08 (C3 of Gal), 85.59 (C4 of Gal), 72.09 (C5 of Gal), 64.03 (C6 of Gal), 60.60 (C1 of DMAPT), 71.81 (C2 of DMAPT), 73.40(C3 of DMAPT), 72.75 (C4 of DMAPT), 64.26 (C5 of DMAPT), 43.2 (N-CH3 of DMAPT), 67.67 (C1 of Gro), 78.50(C2 of Gro), 71.55 (C3 of Gro), 66.19 (C1 of Gro), 78.80(C2 of Gro), 71.55 (C3 of Gro) (Ref. 0014) |
Methanospirillum hungatei (Ref. 0014) |
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| 18 |  |
glucosyl-galactosyl-(galactosyl) caldarchaeol(Ref. 0014) |
1-D-glucopyranosyl(a1-2)-b-D-galactofuranosyl-(1'-b-D-galactofuranosyl) caldarchaeol |
EEL0018 | Yosuke Koga |
Glc-Gal-(Gal)-CA/TGT-I (Ref. 0014) |
C104H202O21 | 1788.704 | 13C-NMR, 107.16 (C1 of Gal), 89.28 (C2 of Gal), 76.75(C3 of Gal), 83.51 (C4 of Gal), 71.65 (C5 of Gal), 64.54 (C6 of Gal), 99.71 (C1 of Glc), 72.82 (C2 of Glc), 74.59(C3 of Glc), 71.65 (C4 of Glc), 73.68 (C5 of Glc), 62.76 (C6 of Glc), 109.13 (C1 of Gal), 81.55 (C2 of Gal), 73.96 (C3 of Gal), 85.86 (C4 of Gal), 72.11 (C5 of Gal), 64.25 (C6 of Gal), 67.79 (C1 of Gro), 78.57 (C2 of Gro), 71.65 (C3 of Gro), 67.46 (C1 of Gro), 78.45 (C2 of Gro), 71.65C3of Gro)(Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 19 |  |
glucosyl-6-acetylgalactosyl-caldarchaeol(Ref. 0014) |
D-glucopyranosyl(a1-2)-6-acetyl-b-D-galactofuranosyl caldarchaeol |
EEL0019 | Yosuke Koga |
Glc-6-AcGal-CAOH /Ac-DGT-I(Ref. 0014) |
C100H194O17 | 1668.600 | 13C-NMR, 107.17 (C1 of Gal), 89.08 (C2 of Gal), 76.47 (C3 of Gal), 83.26 (C4 of Gal), 68.42 (C5 of Gal), 66.34 (C6 of Gal), 99.78 (C1 of Glc), 72.72 (C2 of Glc), 74.84 (C3 of Glc), 71.66 (C4 of Glc), 73.58 (C5 of Glc), 62.73 (C6 of Glc), 67.84 (C1 of Gro), 78.46 (C2 of Gro), 71.66 (C3 of Gro), 62.64 (C1 of Gro), 79.87 (C2 of Gro), 71.66C3of Gro) (Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 20 |  |
glucosyl-6-acetylgalactosyl-archaeol(Ref. 0014) |
D-glucopyranosyl(a1-2)-6-acetyl-b-D-galactofuranosyl archaeol |
EEL0020 | Yosuke Koga |
Glc-6-AcGal-ArOH /Ac-DGD-I(Ref. 0014) |
C57H110O14 | 1019.475 | 13C-NMR, 107.33 (C1 of Gal), 89.22 (C2 of Gal), 76.55 (C3 of Gal), 83.23 (C4 of Gal), 68.45 (C5 of Gal), 66.51 (C6 of Gal), 99.71 (C1 of Glc), 72.85 (C2 of Glc), 74.54 (C3 of Glc), 71.62 (C4 of Glc), 73.70(C5 of Glc), 62.74 (C6 of Glc), 67.96 (C1 of Gro), 78.56 (C2 of Gro), 71.62 (C3 of Gro)(Ref. 0014) |
Methanospirillum hungatei(Ref. 0014) |
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| 21 |  |
caldarchaetidylglycerol(Ref. 0014) |
EEL0021 | Yosuke Koga |
CAG/TsPG(Ref. 0014) A1-1 |
C89H179O11P | 1456.341 | liquid SIMS 1454.8(M-H)- (Ref. 0168) |
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| 22 |  |
galactosyl-galactosyl a-hydroxyarchaeol(Ref. 0016) |
1-D-galactopyranosyl(b1-6)-b-D-galactopyranosyl 2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-D-galactopyranosyl(b1-6)-b-D-galactopyranosyl 2-O-phytanyl-3-O-(3'-hydroxy)phytanyl-sn-glycerol |
EEL0022 | Yosuke Koga |
Gal-Gal-a-OH-ArOH/GL-1(Ref. 0016) |
C55H108O14 | 993.438 | 13C-NMR, 104.73 (C1 of Gal), 71.96 (C2 of Gal), 74.00 (C3 of Gal), 68.89 (C4 of Gal), 74.14 (C5 of Gal), 68.45 (C6 of Gal), 104.56 (C1' of Gal), 71.96 (C2' of Gal), 74.28 (C3' of Gal), 69.75 (C4' of Gal), 75.82 (C5' of Gal), 62.22 (C6' of Gal), 69.45 (C1 of Gro), 78.39 (C2 of Gro), 71.40 (C3 of Gro), 69.10 (C1 of sn-3 phytanyl), 68.89 (C1 of sn-2 phytanyl)(Ref. 0016), 1H-NMR(Ref. 0016) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.46chromatogram: [Chromatogram 0007] (Ref. 0016) |
Methanosaeta concilii(Ref. 0016) |
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| 23 |  |
mannosyl-galactosyl archaeol(Ref. 0016) |
1-D-mannopyranosyl(a1-3)-b-D-galactopyranosyl 2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-D-mannopyranosyl(a1-3)-b-D-galactopyranosyl-2,3-di-O-phytanyl-sn-glycerol |
EEL0023 | Yosuke Koga |
Man-Gal-ArOH/GL-2(Ref. 0016) |
C55H108O13 | 977.438 | 13C-NMR, 104.77 (C1 of Gal), 70.25 (C2 of Gal), 77.51(C3 of Gal), 65.28 (C4 of Gal), 75.33 (C5 of Gal), 61.83 (C6 of Gal), 97.11 (C1' of Man), 71.56 (C2' of Man), 71.94 (C3' of Man), 67.98 (C4' of Man), 73.61 (C5' of Man), 62.26 (C6' of Man), 69.74 (C1 of Gro), 78.66 (C2 of Gro), 71.49 (C3 of Gro), 70.40 (C1 of sn-3 phytanyl), 69.11 (C1 of sn-2 phytanyl)(Ref. 0016), 1H-NMR(Ref. 0016) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.50chromatogram: [Chromatogram 0007](Ref. 0016) |
Methanosaeta concilii(Ref. 0016) |
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| 24 |  |
a-hydroxyarchaetidylethanolamine(Ref. 0017) |
2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphoethanolamine/ 2-O-phytanyl-3-O-(3'-hydroxy)phytanyl-sn-glycerol-1-phosphoethanolamine |
EEL0024 | Yosuke Koga |
a-OH-AE/PEDOH(Ref. 0017) |
C45H94O7NP | 792.204 | O-H, 3514cm-1; NH2, 3348, 1742, 1638, 1552cm-1; C-H, 2920, 2959, 1457cm-1; -CH(CH3)2, 1376, 1362cm-1; CH3, 2870cm-1; P=O, 1229cm-1; P-0, 1086cm-1, P-O-C, 1033cm-1(Ref. 0017) |
[Spectrum 0009]A1 (13C-NMR), [Spectrum 0009]A2 (DEPT) (Ref. 0017)13C-NMR, 65.29 (C1 of Gro), 78.38 (C2 of Gro), 70.89 (C3 of Gro), 68.83 (C1 of sn-2 phytanyl), 69.03 (C1 of sn-3 phytanyl), 40.79 (CH2-NH2), 62.79 (O-CH2), 72.39 (C3 of sn-3 phytanyl) (Ref. 0017) |
[Spectrum 0008]A(Ref. 0017)positive FAB, m/z 792, 774 (M-H2O), 757 (M-H2O-NH3), 496 (M-hydroxyphytanyl) |
Methanosaeta concilii(Ref. 0017) |
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| 25 |  |
galactosyl-archaeol(Ref. 0017) |
b-D-galactopyranosyl 2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/b-D-galactopyranosyl-2,3-di-O-phytanyl-sn-glycerol |
EEL0025 | Yosuke Koga |
Gal-ArOH/GalD(Ref. 0017) |
C49H98O8 | 815.298 | 13C-NMR, [Spectrum 0010]B(Ref. 0017)13C-NMR, 104.41 (C1 of Gal), 71.99 (C2 of Gal), 74.17 (C3 of Gal), 69.52 (C4 of Gal), 75.55 (C5 of Gal), 62.95 (C6 of Gal), 69.07 (C1 of Gro), 78.70 (C2 of Gro), 71.18 (C3 of Gro), 69.52 (C1 of sn-2 phytanyl), 70.39 (C1 of sn-3 phytanyl), 30.0 (C3 of sn-3 phytanyl) |
Methanosaeta concilii(Ref. 0017) |
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| 26 |  |
galactosyl-a-hydroxyarchaeol(Ref. 0017) |
1-b-D-galactopyranosyl 2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-b-D-galactopyranosyl-2-O-phytanyl-3-O-(3'-hydroxy)phytanyl-sn-glycerol |
EEL0026 | Yosuke Koga |
Gal-a-OH-ArOH/GalDOH(Ref. 0017) |
C49H98O9 | 831.297 | 13C-NMR, [Spectrum 0010]A2(Ref. 0017)13C-NMR, 104.41 (C1 of Gal), 71.91 (C2 of Gal), 74.23 (C3 of Gal), 69.73 (C4 of Gal), 75.69 (C5 of Gal), 62.14 (C6 of Gal), 68.81 (C1 of Gro), 78.20 (C2 of Gro), 71.99 (C3 of Gro), 69.93(C1 of sn-2 phytanyl), 69.73 (C1 of sn-3 phytanyl), 72.59 (C3 of sn-3 phytanyl)(Ref. 0017) |
Methanosaeta concilii(Ref. 0017) |
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| 27 |  |
galactosyl-glucosyl-galactosyl-a-hydroxyarchaeol(Ref. 0017) |
1-O-D-galactopyranosyl(b1-6)-[D-glucopyranosyl(b1-3)]-b-galactopyranosyl-2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 1-D-galactopyranosyl(b1-6)-[D-glucopyranosyl(b1-3)]-b-galactopyranosyl-2-O-phytanyl-3-O-(3'-hydroxy)phytanyl-sn-glycerol |
EEL0027 | Yosuke Koga |
Gal-(Glcp)-Galp-a-OH-ArOH/TGDOH(Ref. 0017) |
C61H118O19 | 1155.578 | 13C-NMR, [Spectrum 0010]C2(Ref. 0017)13C-NMR, 104.45 (C1 of Gal), 69.72 (C2 of Gal), 79.97 (C3 of Gal), 68.68 (C4 of Gal), 75.71 (C5 of Gal), 67.96 (C6 of Gal), 104.39 (C1' of 2nd Gal), 71.77 (C2' of 2nd Gal), 74.20 (C3' of 2nd Gal), 69.72 (C4' of 2nd Gal), 75.10 (C5' of 2nd Gal), 62.40 (C6' of 2nd Gal), 103.04 (C1 of Glc), 73.92 (C2 of Glc), 77.35 (C3 of Glc), 70.90 (C4 of Glc), 77.08 (C5 of Glc), 62.12 (C6 of Glc), 69.32 (C1 of Gro), 78.22 (C2 of Gro), 71.55 (C3 of Gro), 68.86 (C1 of sn-2 phytanyl), 69.03 (C1 of sn-3 phytanyl), 72.59 (C3 of sn-3 phytanyl) (Ref. 0017) |
Methanosaeta concilii(Ref. 0017) |
||||||||||||||||||
| 28 |  |
6-aminoethyl-phosphoryl-glucosyl-cyclic archaeol(Ref. 0019) |
1-6'-aminoethyl-phosphoryl-b-D-glucopyranosyl 2,3-O-(3',7',11',15',18',22',26',30'-octamethyl)dotriacontanediyl-sn-glycerol/ 6-aminoethyl-phosphoryl-b-D-glucopyranosyl-2,3-di-O-phytanediyl-sn-glycerol |
EEL0028 | Yosuke Koga |
6-aminoethyl-P-Glc-cycArOH/PEGlcDM(Ref. 0019) |
C51H102O11NP | 936.329 | O-H & N-H, 3064-3500cm-1; NH2, 1726, 1637, 1534cm-1; CH3, 2887, 1378cm-1; CH2, 2956, 1471cm-1; P=O, 1235cm-1; P-O & ether C-O-C, 1098cm-1; P-O-C, 1049cm-1; absence of isopropyl doublet |
[Spectrum 0011]A (Ref. 0019)13C-NMR, 69.99 (C1 of Gro), 78.59 (C2 of Gro), 71.75 (C3 of Gro), 70.27 (C1 of sn-3 alkyl), 68.93 (C1 of sn-2 alkyl), 104.47 (C1 of Glc), 74.35 (C2 of Glc), 76.89 (C3 of Glc), 69.92 (C4 of Glc), 75.92 (C5 of Glc), 65.17 (C6 of Glc) |
negative FAB, m/z 934 (M - 1), 891 (M - CH2=CH-NH2), 792 (M - phosphoethanolamine), 917 (M - NH3) |
chromatogram: [Chromatogram 0009]IV (Ref. 0019)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.16 (Ref. 0019) |
Methanococcus jannaschii(Ref. 0019) |
|||||||||||||||
| 29 |  |
glucosyl-cyclic archaeol(Ref. 0019) |
1-b-D-glucopyranosyl 2,3-O-(3',7',11',15',18',22',26',30'-octamethyl)dotriacontanediyl-sn-glycerol/ b-D-glucopyranosyl-2,3-di-O-phytanediyl-sn-glycerol |
EEL0029 | Yosuke Koga |
Glc-cycArOH/GlcDM(Ref. 0019) |
C49H96O8 | 813.282 | [a]D = -7.67 degree/MD = -62.28 degree (Ref. 0019) |
O-H, 3360cm-1; CH2, 2920, 2955, 1460cm-1; CH3, 2870cm-1; C-O-C, 1065cm-1; |
[Spectrum 0011]B, [Spectrum 0012]A (Ref. 0019)13C-NMR, 69.56 (C1 of Gro), 78.63 (C2 of Gro), 71.31 (C3 of Gro), 70.22 (C1 of sn-3 alkyl), 68.81 (C1 of sn-2 alkyl), 104.10 (C1 of Glc), 74.33 (C2 of Glc), 76.84 (C3 of Glc), 70.85 (C4 of Glc), 77.21 (C5 of Glc), 62.25 (C6 of Glc) |
chromatogram: [Chromatogram 0009] (Ref. 0019)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.88 (Ref. 0019) |
Methanococcus jannaschii(Ref. 0019) |
|||||||||||||||
| 30 |  |
gentiobiosyl-cyclic archaeol(Ref. 0019) |
D-glucopyranosyl-(b1-6)-D-glucopyranosyl 2,3-O-(3',7',11',15',18',22',26',30'-octamethyl)dotriacontanediyl-sn-glycerol/ b-D-glucopyranosyl-(b1-6)-D-glucopyranosyl -2,3-di-O-phytanediyl-sn-glycerol |
EEL0030 | Yosuke Koga |
Gen-cycArOH/GlcGlcDM(Ref. 0019) |
C55H106O13 | 975.422 | MD = -176.88 degree (Ref. 0019) |
[Spectrum 0012]B(Ref. 0019)13C-NMR, 69.88 (C1 of Gro), 78.61 (C2 of Gro), 71.50 (C3 of Gro), 70.23 (C1 of sn-3 alkyl), 68.87 (C1 of sn-2 alkyl), 104.32 (C1 of Glc), 74.31 (C2 of Glc), 76.95 (C3 of Glc), 70.16 (C4 of Glc), 75.07 (C5 of Glc), 68.99 (C6 of Glc), 104.11 (C1' of Glc), 74.26 (C2' of Glc), 77.03 (C3' of Glc), 70.62 (C4' of Glc), 77.11 (C5' of Glc), 62.06 (C6'of Glc) |
chromatogram: [Chromatogram 0009] (Ref. 0019)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.37 (Ref. 0019) |
Methanococcus jannaschii(Ref. 0019) |
||||||||||||||||
| 31 |  |
cyclic archaetidylethanolamine(Ref. 0019) |
2,3-O-(3',7',11',15',18',22',26',30'-octamethyl)dotriacontanediyl-sn-glycerol-1-phosphoethanolamine/ 2,3-di-O-phytanediyl-sn-glycerol-1-phosphoethanolamine |
EEL0031 | Yosuke Koga |
cycAE/PEDM(Ref. 0019) |
C45H92O6NP | 774.189 | N-H, 3350cm-1; NH2, 1740, 1640, 1550cm-1; P=O, 1229cm-1; P-O & ether C-O-C, 1090cm-1; P-O-C, 1030cm-1 |
[Spectrum 0012]C (Ref. 0019)13C-NMR, 65.85 (C1 of Gro), 78.71 (C2 of Gro), 71.57 (C3 of Gro), 70.21 (C1 of sn-3 alkyl), 68.96 (C1 of sn-2 alkyl), 40.82 (CH2-NH2) |
positive FAB, m/z 776 (M + 1), |
chromatogram: [Chromatogram 0009](Ref. 0019)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.48 (Ref. 0019) |
Methanococcus jannaschii(Ref. 0019) |
|||||||||||||||
| 32 |  |
2,3-di-geranylgeranyl-sn-glycerol(Ref. 0020) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadec-2',6',10',14'-tetraenyl-sn-glycerol |
EEL0032 | Yosuke Koga |
DGGG/unsaturated archaeol |
C43H72O3 | 637.030 | Methanopyrus kandleri(Ref. 0020) |
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| 33 |  |
archaetidylcholine(Ref. 0021) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphocholine/2,3-di-O-phytanyl-sn-glycerol-1-phosphocholine |
EEL0033 | Yosuke Koga |
AC(Ref. 0021) |
C48H101O6NP | 819.292 | Negative FAB, m/z 802.7 (M-H) (Ref. 0021) |
Methanopyrus kandleri(Ref. 0021) |
||||||||||||||||||
| 34 | No image | acetyldiglycosyl archaeol(Ref. 0021) |
EEL0034 | Yosuke Koga |
AcdiGly-ArOH(Ref. 0021) |
C57H110O14 | 1019.475 | negative FAB, m/z 1016.9 (Ref. 0021) |
Methanothermus fervidus(Ref. 0021) |
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| 35 | No image | acetyldiglycosyl caldarchaetidyl inositol (Ref. 0021) |
EEL0035 | Yosuke Koga |
AcdiGly-CAI(Ref. 0021) |
C106H205O25P | 1910.721 | negative FAB, m/z 1907.4 (Ref. 0021) |
Methanothermus fervidus(Ref. 0021) |
|||||||||||||||||||
| 36 |  |
archaetidyl glycero(methyl)phosphate(Ref. 0022) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphoglycerol-3''-(methyl)phosphate |
EEL0036 | Yosuke Koga |
AGPMe(Ref. 0022) |
C47H98O11P2 | 901.222 | ||||||||||||||||||||
| 37 |  |
EEL0037 | Yosuke Koga |
Glcp(b1-6)-Manp(a1-2)-aGlcp-ArOH/TGA-2 (Ref. 0024) |
C61H118O18 | 1139.579 | [a]D = +34.6 degree; MD = +394 degree (Ref. 0024) |
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| 38 |  |
2-HSO3-mannosyl glucosyl archaeol(Ref. 0025) |
1-[2'-hydroxysulfonyloxy-D-mannopyranosyl (a1'-2')a-D-glucopyranosyl]-2,3-di-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol |
EEL0038 | Yosuke Koga |
2-HSO3-Manp(a1-2)-aGlcp-ArOH/S-DGA-5 (Ref. 0025) |
C55H108O16S | 1057.502 | 13C-NMR, 68.92 (C1 of Gro), 78.52 (C2 of Gro), 72.27 (C3 of Gro), 70.11 (C1 of sn-3 alkyl), 68.92 (C1 of sn-2 alkyl), 97.69 (C1 of Glc), 78.18 (C2 of Glc), 73.52 (C3 of Glc), 71.45 (C4 of Glc), 74.11 (C5 of Glc), 61.65 (C6 of Glc), 97.69 (C1 of Man), 77.94 (C2 of Man), 71.88 (C3 of Man), 68.66 (C4 of Man), 74.84 (C5 of Man), 62.56 (C6 of Man) |
TLC, chloroform-methanol-water (65:25:4) Rf 0.26TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) Rf 0.30 |
Halobacterium trapanicum(Ref. 0025) |
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| 39 |  |
1-[6'-hydroxysulfonyloxy-D-mannopyranosyl (a1'-2')-a-D-glucopyranosyl] 2,3-di-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol |
EEL0039 | Yosuke Koga |
6-HSO3-Manp(a1-2)-aGlcp-ArOH/S-DGA-1/S-DGD-1 (Ref. 0026) |
C55H108O16S | 1057.502 | [a]D = +42.8degree; MD = +466.7 degree (Ref. 0026) |
[Spectrum 0015](Ref. 0029)O-H, 3420cm-1; CH3 & CH2, 2970, 2940, 2880, 1470cm-1; isopropyl, 1385, 1370cm-1; S=O, 1250cm-1; ether C-O-C, 1100cm-1; alcoholic C-O, 1070cm-1 (Ref. 0026) |
|||||||||||||||||||
| 40 |  |
mannosyl glucosyl archaeol(Ref. 0026) |
EEL0040 | Yosuke Koga |
Manp(a1-2)-aGlcp-ArOH/DGA-1(Ref. 0026) |
C55H108O13 | 977.438 | [a]D = +61.1 degree; MD = +597 degree (Ref. 0026) |
||||||||||||||||||||
| 41 |  |
2-HSO3-mannosyl glucosyl archaeol(Ref. 0027) |
1-[2'-hydroxysulfonyloxy-D-mannopyranosyl (a1'-4')a-D-glucopyranosyl] 2,3-di-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol |
EEL0041 | Yosuke Koga |
2-HSO3-Manp(a1-4)-a-Glcp-ArOH/S-DGA-3 (Ref. 0027) |
C55H108O16S | 1057.502 | [a]D = +26.4 degree (Ref. 0027) |
S=O, 1250cm-1; S-O-C, 830cm-1(Ref. 0027) |
1H-NMR, 4.78, 4.7313C-NMR, 71.5 (C1 of Gro), 78.4 (C2 of Gro), 72.27 (C3 of Gro), 70.7 (C1 of sn-3 alkyl), 68.5 (C1 of sn-2 alkyl), 96.9 (C1 of Glc), 72.0 (C2 of Glc), 72.2 (C3 of Glc), 77.1 (C4 of Glc), 70.5 (C5 of Glc), 61.5 (C6 of Glc), 96.9 (C1 of Man), 77.6 (C2 of Man), 71.8 (C3 of Man), 67.7 (C4 of Man), 73.4 (C5 of Man), 61.8 (C6 of Man) |
positive FAB, m/z 1078 (M+Na); negative FAB, 1055 (M-H) (Ref. 0027) |
TLC, chloroform-methanol-water (65:25:4) Rf 0.35 (Ref. 0027) |
|||||||||||||||
| 42 |  |
2,6-di-HSO3-mannosyl glucosyl archaeol (Ref. 0029) |
1-[2',6'-hydroxysulfonyloxy-D-mannopyranosyl (a1'-2')-a-D-glucopyranosyl] 2,3-di-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol |
EEL0042 | Yosuke Koga |
2,6-diHSO3-Manp(a1-2)-a-Glcp-ArOH/S2-DGA-1 (Ref. 0029) |
C55H108O19S2 | 1137.567 | 1H-NMR [Spectrum 0019](Ref. 0029)13C-NMR [Spectrum 0020](Ref. 0029)13C-NMR, 95.74 (C1 of Glc), 74.78 (C2 of Glc), 71.44 (C3 of Glc), 70.14 (C4 of Glc), 72.54 (C5 of Glc), 60.84 (C6 of Glc), 95.66 (C1 of Man), 75.41 (C2 of Man), 69.42 (C3 of Man), 67.76 (C4 of Man), 71.44 (C5 of Man), 66.08 (C6 of Man) (Ref. 0029) |
chromatogram, [Chromatogram 0012](Ref. 0029)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4, double development) Rf 0.18 |
Natrialba(Ref. 0029) |
|||||||||||||||||
| 43 |  |
2,6-di-HSO3-mannosyl glucosyl C20,C25-archaeol(Ref. 0029) |
1-[2',6'-hydroxysulfonyloxy-D-mannopyranosyl (a1'-2')-a-D-glucopyranosyl] 2-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-3-O-(3''',7''',11''',15''',19'''-pentamethyl)icosanyl-sn-glycerol |
EEL0043 | Yosuke Koga |
2,6-diHSO3-Manp(a1-2)-a-Glcp-C20,C25-ArOH/S2-DGA-1 (Ref. 0029) |
C60H118O19S2 | 1207.700 | 1H-NMR [Spectrum 0019](Ref. 0029)13C-NMR [Spectrum 0020] (Ref. 0029)13C-NMR, 95.74 (C1 of Glc), 74.78 (C2 of Glc), 71.44 (C3 of Glc), 70.14 (C4 of Glc), 72.54 (C5 of Glc), 60.84 (C6 of Glc), 95.66 (C1 of Man), 75.41 (C2 of Man), 69.42 (C3 of Man), 67.76 (C4 of Man), 71.44 (C5 of Man), 66.08 (C6 of Man) (Ref. 0029) |
chromatogram, [Chromatogram 0012](Ref. 0029)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4, double development) Rf 0.18 |
Natrialba(Ref. 0029) |
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| 44 |  |
C20,C25-archaetidylglycerol(Ref. 0029) |
2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'',7'',11'',15'',19''-pentamethyl)icosanyl-sn-glycerol-1-phosphoglycerol |
EEL0044 | Yosuke Koga |
C20,C25-AG(Ref. 0029) |
C51H105O8P | 877.348 | chromatogram, [Chromatogram 0012] (Ref. 0029)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4, double development) Rf 0.92 |
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| 45 |  |
C20,C25-archaetidyl glycero(methyl)phosphate(Ref. 0029) |
2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'',7'',11'',15'',19''-pentamethyl)icosanyl-sn-glycerol-1-phosphoglycerol-(methyl)phosphate |
EEL0045 | Yosuke Koga |
C20,C25-AGP-Me(Ref. 0029) |
C52H108O11P2 | 971.355 | chromatogram, [Chromatogram 0012] (Ref. 0029)TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4, double development) Rf 0.68 |
Natrialba(Ref. 0029) |
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| 46 |  |
glucosyl glucosyl archaeol(Ref. 0030) |
1-[D-glucopyranosyl-(b1-6)-a-D-glucopyranosyl]-2,3-di-O-(3'',7'',11'',15''-tetramethyl)hexadecyl-sn-glycerol |
EEL0046 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-C20,C20-ArOH/DGA-4 (Ref. 0030) |
C55H108O13 | 977.438 | 1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 976 (M-H); |
TLC, chloroform-methanol-conc.ammonia (65:35:5) Rf 0.20TLC, chloroform-methanol-acetic acid-water (85:22.5:8:3, ) Rf 0.39 |
Natronobacterium sp. from India(Ref. 0030) |
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| 47 |  |
glucosyl-glucosyl-tetraunsat.-C20,C20-archaeol(Ref. 0030) |
EEL0047 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-tetraunsat.-C20,C20-ArOH/DGA-4 (Ref. 0030) |
C60H118O13 | 1047.571 | 1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 967.8 (M-H); |
Natronobacterium sp. from India(Ref. 0030) |
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| 48 |  |
glucosyl-glucosyl-tetraunsat.-C20,C25-archaeol(Ref. 0030) |
EEL0048 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-tetraunsat.-C20,C25-ArOH/DGA-4 (Ref. 0030) |
C65H128O13 | 1117.704 | 1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 1037.6 (M-H); |
TLC, chloroform-methanol-conc.ammonia (65:35:5) Rf 0.20TLC, chloroform-methanol-acetic acid-water (85:22.5:8:3, ) Rf 0.44 |
Natronobacterium sp. from India(Ref. 0030) |
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| 49 |  |
glucosyl-glucosyl-monounsat.-C20,C20- hydroxyarchaeol(Ref. 0030) |
EEL0049 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-OH-C20, monounsat.-C20-ArOH/DGA-4 (Ref. 0030) |
C60H118O14 | 1063.571 | 1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 989.7 (M-H); |
Natronobacterium sp. from India(Ref. 0030) |
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| 50 |  |
glucosyl-glucosyl-diunsat. C20,C25- hydroxyarchaeol(Ref. 0030) |
EEL0050 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-OH-C20, diunsat.-C25-ArOH/DGA-4 (Ref. 0030) |
1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 1057 (M-H); |
Natronobacterium sp. from India(Ref. 0030) |
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| 51 |  |
glucosyl-glucosyl-diunsat. C25,C25-hydroxyarchaeol(Ref. 0030) |
EEL0051 | Yosuke Koga |
Glcp(b1-6)-a-Glcp-OH-C25, diunsat. C25-ArOH/DGA-4 (Ref. 0030) |
1H-NMR, 4.125-4.150 (doublet, J, 7.5Hz); 4.613-4.625 (doublet, J, 3.75 Hz) |
negative FAB, m/z 1127 (M-H); |
Natronobacterium sp. from India(Ref. 0030) |
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| 52 |  |
archaetidylglycero cyclic phosphate(Ref. 0031) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphoglycerol-1'',2''-cyclic phosphate |
EEL0052 | Yosuke Koga |
AGcycP(Ref. 0031)/PL2 |
C46H94O10P2 | 869.180 | 13C-NMR, 65.5 (C1 of Gro), 78.1 (C2 of Gro), 71.5 (C3 of Gro), 66.8 (C1' of Gro), 74.6 (C2' of Gro), 66.9 (C3' of Gro), 69.5 (C1 of sn-2 alkyl), 70.8 (C1 of sn-3 alkyl) |
chromatogram, [Chromatogram 0013](Ref. 0031)TLC, chloroform-methanol-water (65:25:4) Rf 0.3 (Ref. 0031) |
Natronococcus occultus(Ref. 0031) |
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| 53 |  |
C20,C25-archaetidyl glycero cyclic phosphate(Ref. 0031) |
2-O-(3',7',11',15'-tetramethyl)hexadecyl-3'- O-(3'',7'',11'',15'',19''-pentamethyl)icosanyl- sn-glycerol-1-phosphoglycerol-1''',2'''-cyclic phosphate |
EEL0053 | Yosuke Koga |
C20,C25-AGcycP(Ref. 0031) |
C51H104O10P2 | 939.313 | 13C-NMR, 65.5 (C1 of Gro), 78.1 (C2 of Gro), 71.5 (C3 of Gro), 66.8 (C1' of Gro), 74.6 (C2' of Gro), 66.9 (C3' of Gro), 69.5 (C1 of sn-2 alkyl), 70.8 (C1 of sn-3 alkyl) |
chromatogram, [Chromatogram 0013](Ref. 0031)TLC, chloroform-methanol-water (65:25:4) Rf 0.3 (Ref. 0031) |
Natronococcus occultus(Ref. 0031) |
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| 54 |  |
dihexadecylglycerol(Ref. 0032)/dipalmitylglycerol |
1,2-di-O-hexadecyl-sn-glycerol |
EEL0054 | Yosuke Koga |
diC16-Gro(Ref. 0032) |
C35H72O3 | 540.944 | [a]D = -3.1 degree; MD = -16.7 degree (Ref. 0032) |
GC-methane-CI-MS, 541 (M+1) |
chromatogram, [Chromatogram 0014] (component 2), [Chromatogram 0015] (Ref. 0032)TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.42 (Ref. 0032) |
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| 55 |  |
1-hexadecyl-2-heptadecyl-glycerol(Ref. 0032) |
1-O-hexadecyl-2-O-heptadecyl-sn-glycerol |
EEL0055 | Yosuke Koga |
C16, C17-Gro(Ref. 0032) |
C36H74O3 | 554.971 | [a]D = -3.1 degree; MD = -16.7 degree (Ref. 0032) |
GC-methane-CI-MS, 555 (M+1) |
chromatogram, [Chromatogram 0014](component 2), [Chromatogram 0015] (Ref. 0032)TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.42 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
||||||||||||||||
| 56 |  |
diheptadecyl-glycerol(Ref. 0032) |
1,2-di-O-heptadecyl-sn-glycerol |
EEL0056 | Yosuke Koga |
di-C17-Gro(Ref. 0032) |
C37H76O3 | 568.998 | [a]D = -3.1 degree; MD = -16.7 degree (Ref. 0032) |
chromatogram, [Chromatogram 0014] (component 2), [Chromatogram 0015] (Ref. 0032)TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.42 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 57 |  |
heptadecyl octadecyl glycerol(Ref. 0032) |
1-O-heptadecyl-2-O- octadecyl-sn-glycerol |
EEL0057 | Yosuke Koga |
C17,C18-Gro(Ref. 0032) |
C38H78O3 | 583.024 | [a]D = -3.1 degree; MD = -16.7 degree (Ref. 0032) |
GC-methane-CI-MS, 583 (M+1) |
chromatogram, [Chromatogram 0014](component 2), [Chromatogram 0015](Ref. 0032)TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.42 (Ref. 0032) |
|||||||||||||||||
| 58 |  |
dioctadecyl-glycerol(Ref. 0032) |
1,2-di-O-octadecyl-sn-glycerol |
EEL0058 | Yosuke Koga |
di-C18-Gro(Ref. 0032) |
C39H80O3 | 597.051 | [a]D = -3.1 degree; MD = -16.7 degree (Ref. 0032) |
GC-methane-CI-MS, 597 (M+1) |
chromatogram, [Chromatogram 0014](component 2), [Chromatogram 0015] (Ref. 0032)TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.42 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
||||||||||||||||
| 59 |  |
isohexadecyl-glycerol(Ref. 0032) |
1-O-(14'-methyl)pentadecyl-sn-glycerol(Ref. 0032) |
EEL0059 | Yosuke Koga |
isoC16-Gro(Ref. 0032) |
C19H40O3 | 316.519 | GC-ammonia-CI-MS, 418 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 60 |  |
hexadecyl-glycerol(Ref. 0032) |
1-O-hexadecyl-sn-glycerol |
EEL0060 | Yosuke Koga |
C16-Gro(Ref. 0032) |
C19H40O3 | 316.519 | GC-ammonia-CI-MS, 418 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 61 |  |
isoheptadecyl-glycerol(Ref. 0032) |
1-O-(15'-methyl)hexadecyl-sn-glycerol |
EEL0061 | Yosuke Koga |
isoC17-Gro(Ref. 0032) |
C20H42O3 | 330.546 | GC-ammonia-CI-MS, 432 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 62 |  |
anteisoheptadecyl-glycerol(Ref. 0032) |
1-O-(14'-methyl)hexadecyl-sn-glycerol |
EEL0062 | Yosuke Koga |
anteisoC17-Gro(Ref. 0032) |
C20H42O3 | 330.546 | chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
||||||||||||||||||
| 63 |  |
isooctadecyl-glycerol(Ref. 0032) |
1-O-(16-methyl)heptaptadecyl-sn-glycerol |
EEL0063 | Yosuke Koga |
isoC18-Gro(Ref. 0032) |
C21H44O3 | 344.572 | GC-ammonia-CI-MS, 446 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 64 |  |
octadecyl-glycerol(Ref. 0032) |
1-O-octadecyl-sn-glycerol |
EEL0064 | Yosuke Koga |
C18-Gro(Ref. 0032) |
C21H44O3 | 344.572 | GC-ammonia-CI-MS, 446 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 65 |  |
isononadecyl-glycerol(Ref. 0032) |
1-O-(17'-methyl)octadecyl-sn-glycerol |
EEL0065 | Yosuke Koga |
isoC19-Gro(Ref. 0032) |
C22H46O3 | 358.599 | GC-ammonia-CI-MS, 460 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 66 |  |
anteisononadecyl-glycerol(Ref. 0032) |
1-O-(16'-methyl)octadecyl-sn-glycerol |
EEL0066 | Yosuke Koga |
anteisoC19-sn-Gro(Ref. 0032) |
C22H46O3 | 358.599 | GC-ammonia-CI-MS, 460 (M+18) |
chromatogram, [Chromatogram 0014] (component 3), [Chromatogram 0016]TLC, n-hexane-diethyl ether-acetic acid (70:30:1) Rf 0.06 (Ref. 0032) |
Thermodesulfotobacterium commune(Ref. 0032) |
|||||||||||||||||
| 67 |  |
diabolic acid-containing lipid 22/di(butyroyl PlaG) diabolate(Ref. 0033) |
EEL0067 | Yosuke Koga |
di(acyl PlaG) diabolate(Ref. 0033) |
C84H160O20P2 | 1552.105 | Butyrivibrio sp.(Ref. 0033) |
||||||||||||||||||||
| 68 |  |
diabolic acid containing alkenyl galactophospholipid 14/(Ref. 0033) |
EEL0068 | Yosuke Koga |
C87H164O20P | 1561.195 | Butyrivibrio sp.(Ref. 0033) |
|||||||||||||||||||||
| 69 |  |
diheptadecyl-glycerol(Ref. 0034) |
1,2-di-O-heptadecyl-sn-glycerol |
EEL0069 | Yosuke Koga |
di-C17-Gro(Ref. 0034) |
C37H76O3 | 568.998 | Aquifex pyrophilus(Ref. 0034) |
|||||||||||||||||||
| 70 |  |
19:cyc acyl plasmenylglycerol(Ref. 0038) |
EEL0070 | Yosuke Koga |
19:cyc acyl PlaG(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 71 |  |
C20,C25-archaetidylglycerophosphate(Ref. 0036) |
2-(3'',7'',11''.15'',19''-pentamethyl)icosyl-3-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phosphoglycerophosphate |
EEL0071 | Yosuke Koga |
C20,C25-AGP(Ref. 0036) |
C51H106O11P2 | 957.328 | 1H-NMR, 0.82 (CH3); 1.0-1.1 ((CH3)2C-); 1.2-1.3 (CH2); 1.48-1.50 (CH-); 3.42-3.44 (RCH2-O-); 3.56-3.58 (-CH2-O-R, -CH-O-R); 3.9-4.0 (-CH2-O-P) |
negative FAB, m/z 972 (M-NH4) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) double development Rf 0.44 chloroform-methanol-acetic acid (65:4:35) Rf 0.54 chloroform-methanol-ammonia (65:35:5) double development Rf 0.27 (Ref. 0036) |
|||||||||||||||||
| 72 | No image | phospho-(galactosyl, mannosyl, glucosyl)-monounsaturated ArOH(Ref. 0036) |
EEL0072 | Yosuke Koga |
H2PO3-Gal-Man-Glc-ArOH/P-TGD(Ref. 0036) |
1H-NMR, 0.82 (CH3); 1.60-1.65 (allylic CH3); 2.0 (allylic CH2); 5.1-5.2 (olefinic isoprenoid H) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) double development Rf 0.14 chloroform-methanol-acetic acid (65:4:35) Rf 0.04 chloroform-methanol-ammonia (65:35:5) double development Rf 0.11(Ref. 0036) |
Halococcus(Ref. 0036) |
||||||||||||||||||||
| 73 |  |
C20,unsat.C20-archaetidylglycerophosphate(Ref. 0036) |
EEL0073 | Yosuke Koga |
C20,unsat.C20-AGP(Ref. 0036) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) double development Rf 0.39chloroform-methanol-acetic acid (65:4:35) Rf 0.50chloroform-methanol-ammonia (65:35:5) double development Rf 0.23(Ref. 0036) |
Halococcus(Ref. 0036) |
|||||||||||||||||||||
| 74 |  |
plasmenylserine(Ref. 0035) |
EEL0074 | Yosuke Koga |
PlaS(Ref. 0035) |
Megasphaera elsdenii(Ref. 0035) |
||||||||||||||||||||||
| 75 |  |
16:0 acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0075 | Yosuke Koga |
16:0 acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 76 |  |
16:1 acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0076 | Yosuke Koga |
16:1 acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 77 |  |
17:cyc acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0077 | Yosuke Koga |
17:cyc acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 78 |  |
18:0 acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0078 | Yosuke Koga |
18:0 acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 79 |  |
18:1 acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0079 | Yosuke Koga |
18:1 acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 80 |  |
19:cyc acyl plasmenylmethylethanolamine(Ref. 0038) |
EEL0080 | Yosuke Koga |
19:cyc acyl PlaME(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 81 |  |
16:0 acyl plasmenylethanolamine(Ref. 0038) |
EEL0081 | Yosuke Koga |
16:0 acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 82 |  |
16:1 acyl plasmenylethanolamine(Ref. 0038) |
EEL0082 | Yosuke Koga |
16:1 acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 83 |  |
17:cyc acyl plasmenylethanolamine(Ref. 0038) |
EEL0083 | Yosuke Koga |
17:cyc acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 84 |  |
18:0 acyl plasmenylethanolamine(Ref. 0038) |
EEL0084 | Yosuke Koga |
18:0 acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 85 |  |
18:1 acyl plasmenylethanolamine(Ref. 0038) |
EEL0085 | Yosuke Koga |
18:1 acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 86 |  |
19:cyc acyl plasmenylethanolamine(Ref. 0038) |
EEL0086 | Yosuke Koga |
19:cyc acyl PlaE(Ref. 0038) |
Clostridium butyricum(Ref. 0038) |
||||||||||||||||||||||
| 87 |  |
16:0 acyl plasmenylglycerol(Ref. 0038) |
EEL0087 | Yosuke Koga |
16:0 acyl PlaG(Ref. 0038) |
|||||||||||||||||||||||
| 88 |  |
16:1 acyl plasmenylglycerol(Ref. 0038) |
EEL0088 | Yosuke Koga |
16:1 acyl PlaG(Ref. 0038) |
|||||||||||||||||||||||
| 89 |  |
17:cyc acyl plasmenylglycerol(Ref. 0038) |
EEL0089 | Yosuke Koga |
17:cyc acyl PlaG(Ref. 0038) |
|||||||||||||||||||||||
| 90 |  |
18:0 acyl plasmenylglycerol(Ref. 0038) |
EEL0090 | Yosuke Koga |
18:0 acyl PlaG(Ref. 0038) |
|||||||||||||||||||||||
| 91 |  |
18:1 acyl plasmenylglycerol(Ref. 0038) |
EEL0091 | Yosuke Koga |
18:1 acyl PlaG(Ref. 0038) |
|||||||||||||||||||||||
| 92 |  |
diabolic acid-containing lipid 26/di-PlaG diabolate(Ref. 0033) |
EEL0092 | Yosuke Koga |
di-PlaG diabolate(Ref. 0033) |
C76H148O18P2 | 1411.925 | Butyrivibrio sp.(Ref. 0033) |
||||||||||||||||||||
| 93 |  |
diabolic acid-containing lipid 20/butyroyl PlaG, palmitoyl PlaG diabolate(Ref. 0033) |
EEL0093 | Yosuke Koga |
di(acylPlaG) diabolate(Ref. 0033) |
C96H184O20P2 | 1720.424 | Butyrivibrio sp.(Ref. 0033) |
||||||||||||||||||||
| 94 |  |
diabolic acid containing alkenyl galactophospholipid 11/(Ref. 0033) |
EEL0094 | Yosuke Koga |
C87H164O20P | 1561.195 | Butyrivibrio sp.(Ref. 0033) |
|||||||||||||||||||||
| 95 |  |
diabolic acid-containing lipid 25/butyroyl PlaG,PlaG diabolate(Ref. 0033) |
EEL0095 | Yosuke Koga |
acyl PlaG,PlaG diabolate(Ref. 0033) |
C80H154O19P2 | 1482.015 | Butyrivibrio sp.(Ref. 0033) |
||||||||||||||||||||
| 96 | No image | phospho-galactosyl-mannosyl-glucosyl-ArOH(Ref. 0036) |
EEL0096 | Yosuke Koga |
H2PO3-Gal-Man-Glc-ArOH/P-TGD(Ref. 0036) |
TLC, chloroform-methanol-acetic acid-water (85:22.5:10:4) double development Rf 0.14 chloroform-methanol-acetic acid (65:4:35) Rf 0.04 chloroform-methanol-ammonia (65:35:5) double development Rf 0.11(Ref. 0036) |
Halococcus(Ref. 0036) |
|||||||||||||||||||||
| 97 |  |
a-hydroxyarchaeol |
2-O-(3',7',11',15'-tetramethyl)hexadecyl-3-O-(3'-hydroxy-3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol/ 2-O-(3'-hydroxy)phytanyl-3-O-phytanyl-sn-glycerol(Ref. 0015) |
EEL0097 | Yosuke Koga |
a-OH-ArOH |
C43H88O4 | 669.156 | 13C-NMR, 68.77 (sn-2 C1), 68.90 (sn-3 C1), 37.10 (sn-2 C2), 39.78 (sn-3 C2), 29.90 (sn-2 C3), 72.37 (sn-3 C3), 37.32-37.57 (sn-2 C4), 42.92 (sn-2 C4), 24.39 (sn-2 C5), 21.51 (sn-3 C5), 37.32-37.57 (sn-2 C6), 37.71 (sn-3 C6) (Ref. 0015) [Spectrum 0024] [Spectrum 0025] [Spectrum 0026] (Ref. 0015) |
|||||||||||||||||||
| 98 |  |
3-palmitylglycerophosphate |
3-O-hexadecyl-sn-glycerol-1-phosphate(Ref. 0048) |
EEL0098 | Yosuke Koga |
C16:0-GP monoether/3Hx-GPA |
C19H41O6P | 396.499 | prepared by alkaline hydrolysis of 3-O-hexadecyl-2-acetyl GPC followed by hydrolysis with phospholipase D (Ref. 0048) |
prepared by alkaline hydrolysis of 3-O-hexadecyl-2-acetyl GPC followed by hydrolysis with phospholipase D (Ref. 0048) |
||||||||||||||||||
| 99 |  |
3-O-hexadecyl-sn-glycero-1-phosphocholine(Ref. 0048) |
EEL0099 | Yosuke Koga |
C16:0-GPC/3Hx-GPC |
C24H52O6PN | 481.647 | synthetic compound |
||||||||||||||||||||
| 100 |  |
1-O-hexadecylglycerol (Ref. 0040) |
EEL0100 | Yosuke Koga |
16:0-Gro monoether |
C19H40O3 | 316.519 | 58.5  C(Ref. 0067) |
TLC, THF-H2O (1:1) Rf 0.44 |
synthetic product |
||||||||||||||||||
| 101 |  |
1-O-octadecylglycerol (Ref. 0040) |
EEL0101 | Yosuke Koga |
18:0-Gro monoether |
C19H40O3 | 316.519 | 58.5 C(Ref. 0067) |
TLC, THF-H2O (1:1) Rf 0.34 |
synthetic product |
||||||||||||||||||
| 102 |  |
1-O-cis-9-hexadecenyglycerol (Ref. 0040) |
EEL0102 | Yosuke Koga |
16:1-Gro monoether |
C19H38O3 | 314.503 | 58.5 C(Ref. 0067) |
TLC, THF-H2O (1:1) Rf 0.51 |
synthetic product |
||||||||||||||||||
| 103 |  |
1-O-cis-9-octadecenyglycerol (Ref. 0040) |
EEL0103 | Yosuke Koga |
18:1-Gro monoether |
C21H42O3 | 342.556 | 58.5 C(Ref. 0067) |
TLC, THF-H2O (1:1) Rf 0.40 |
synthetic product |
||||||||||||||||||
| 104 |  |
1-O-trans-9-octadecenyglycerol (Ref. 0040) |
EEL0104 | Yosuke Koga |
18:1-Gro monoether |
C21H42O3 | 342.556 | 58.5 C(Ref. 0067) |
TLC, THF-H2O (1:1) Rf 0.42 |
synthetic product |
||||||||||||||||||
| 105 |  |
1-palmityl-2-acetylglycerophosphate |
1-O-hexadecyl-2-acetyl-sn-glycerol-3-phosphate(Ref. 0048) |
EEL0105 | Yosuke Koga |
C16:0-Ac-GP monoether/1Hx-2Ac-GPA |
C19H41O6P | 396.499 | prepared by acetylation of 1-O-hexadecyl-GPC with acetic anhydride followed by hydrolysis with phospholipase D (Ref. 0048) |
synthetic compound |
prepared by acetylation of 1-O-hexadecyl-GPC with acetic anhydride followed by hydrolysis with phospholipase D (Ref. 0048) |
|||||||||||||||||
| 106 |  |
3-palmityl-2-acetylglycerophosphate |
3-O-hexadecyl-2-acetyl-sn-glycerol-1-phosphate(Ref. 0048) |
EEL0106 | Yosuke Koga |
C16:0-Ac-GP monoether/3Hx-2Ac-GPA |
C19H41O6P | 396.499 | prepared by acetylation of 1-O-hexadecyl-GPC with acetic anhydride followed by hydrolysis with phospholipase D (Ref. 0048) |
synthetic compound |
prepared by acetylation of 1-O-hexadecyl-GPC with acetic anhydride followed by hydrolysis with phospholipase D (Ref. 0048) |
|||||||||||||||||
| 107 |  |
1-palmityl-2-acetylglycerophosphocholine |
3-O-hexadecyl-2-acetyl-sn-glycero-1-phosphocholine(Ref. 0048) |
EEL0107 | Yosuke Koga |
C16:0-Ac-GPC monoether/3Hx-2Ac-GPC |
C19H41O6P | 396.499 | prepared by acetylation of 1-O-HEXADECYL-GPC with acetic anhydride(Ref. 0048) |
synthetic compound |
prepared by acetylation of 1-O-HEXADECYL-GPC with acetic anhydride(Ref. 0048) |
|||||||||||||||||
| 108 |  |
PAF |
1-O-hexadecyl-2-acetyl-sn-glycero-3-phosphocholine(Ref. 0048) |
EEL0108 | Yosuke Koga |
C16:0-Ac-GPC/1Hx-2Ac-GPC |
C24H52O6PN | 481.647 | ||||||||||||||||||||
| 109 |  |
1-(9'-cis-octadecenyl)-2-octadecanoylglycerol/1-oleyl-2-stearoylglycerol |
1-O-(9'-cis-octadecenyl)-2-O-octadecanoylglycerol(Ref. 0049) |
EEL0109 | Yosuke Koga |
C39H76O4 | 609.018 | [a]D = -3.9 MD = -23.8 |
synthetic compound |
|||||||||||||||||||
| 110 |  |
1-(9'-cis-octadecenyl)-3-octadecanoylglycerol/1-oleyl-3-stearoylglycerol |
1-O-(9'-cis-octadecenyl)-3-O-octadecanoylglycerol(Ref. 0049) |
EEL0110 | Yosuke Koga |
C39H76O4 | 609.018 | 43.0-43.5 C |
[a]D = -0.7 /MD = -4.3 |
synthetic compound |
||||||||||||||||||
| 111 |  |
1-(9'-cis-octadecenyl)-2,3-di-hexadecanoylglycerol/1-oleyl-2,3-palmitoylglycerol |
1-O-(9'-cis-octadecenyl)-2,3-di-O-hextadecanoylglycerol(Ref. 0049) |
EEL0111 | Yosuke Koga |
C53H102O5 | 819.374 | 36.5-37.5 C |
[a]D = -6.6 /MD = -55.3 |
synthetic compound |
||||||||||||||||||
| 112 |  |
1-(9'-cis-octadecenyl)-2,3-di-octadecanoylglycerol/1-oleyl-2,3-stearoylglycerol |
1-O-(9'-cis-octadecenyl)-2,3-di-O-octadecanoylglycerol(Ref. 0049) |
EEL0112 | Yosuke Koga |
C57H110O5 | 875.480 | 37.0-38.0 C |
[a]D = -6.5 /MD = -56.4 |
synthetic compound |
||||||||||||||||||
| 113 |  |
1,2-di-(9'-cis-octadecenyl)-3-tritylglycerol/1,2-oleyl-3-tritylglycerol |
1,2-di-O-(9'-cis-octadecenyl)-3-O-tritylglycerol(Ref. 0049) |
EEL0113 | Yosuke Koga |
C58H90O3 | 835.333 | [a]D = +4.1 /MD = +28.5 |
synthetic compound |
|||||||||||||||||||
| 114 |  |
1,2-di-(9'-cis-octadecenyl)-3-acetylglycerol/1,2-oleyl-3-acetylglycerol |
1,2-di-O-(9'-cis-octadecenyl)-3-O-acetylglycerol(Ref. 0049) |
EEL0114 | Yosuke Koga |
C41H78O4 | 635.056 | [a]D = -5.2 /MD = -33.0 |
synthetic compound |
|||||||||||||||||||
| 115 |  |
3-octadecylglycerol/3-stearylglycerol(Ref. 0049) |
3-O-octadecylglycerol |
EEL0115 | Yosuke Koga |
3-C18:0-Gro monoether |
C21H44O3 | 344.572 | 70.5-71.5 C |
[a]D = +16.0 |
synthetic product |
|||||||||||||||||
| 116 |  |
3-hexadecylglycerol/3-palmitylglycerol(Ref. 0049) |
3-O-hexadecylglycerol |
EEL0116 | Yosuke Koga |
3-C16:0-Gro monoether |
C19H40O3 | 316.519 | 65.5-66.5 C |
[a]D = +17.5 |
synthetic product |
|||||||||||||||||
| 117 |  |
1,2-ditosyl-3-octadecylglycerol/1,2-ditosyl-3-stearylglycerol |
1,2-ditosyl-3-O-octadecylglycerol(Ref. 0049) |
EEL0117 | Yosuke Koga |
1,2-diTs-3-C18:0-Gro monoether |
C35H56O7S2 | 652.947 | |
[a]D = +0.6 |
synthetic product |
|||||||||||||||||
| 118 |  |
1,2-ditosyl-3-hexadecylglycerol/1,2-ditosyl-3-palmitylglycerol |
1,2-ditosyl-3-O-hexadecylglycerol(Ref. 0049) |
EEL0118 | Yosuke Koga |
1,2-diTs-3-C16:0-Gro monoether |
C33H52O7S2 | 624.894 | [a]D = +0.5 |
synthetic product |
||||||||||||||||||
| 119 |  |
1-octadecyl-2,3-di-O-acetylglycerol/1-stearyl-2,3-di-O-acetylglycerol |
1-O-octadecyl-2,3-di-O-acetylglycerol(Ref. 0049) |
EEL0119 | Yosuke Koga |
C25H48O5 | 428.646 | 39.0-40.0 C |
[a]D = -11.8 |
synthetic product |
||||||||||||||||||
| 120 |  |
1-hexadecyl-2,3-di-O-acetylglycerol/1-palmityl-2,3-di-O-acetylglycerol |
1-O-hexadecyl-2,3-di-O-acetylglycerol(Ref. 0049) |
EEL0120 | Yosuke Koga |
C23H44O5 | 400.592 | [a]D = -12.8 |
synthetic product |
|||||||||||||||||||
| 121 |  |
1-(9'-cis-octadecenyl)-2-octadecanoyl-3-glycerophosphoethanolamine/1-oleyl-2-stearoyl-3-glycerophosphoethanolamine |
1-O-(9'-cis-octadecenyl)-2-O-octadecanoyl-3-glycerophosphoethanolamine(Ref. 0049) |
EEL0121 | Yosuke Koga |
1-C18:1-2-C18:0-GPE monoether/ether analog of PE |
C41H84O7NP | 734.082 | 192-193 |
[a]D = +3.1 /MD = 22.6 |
synthetic product |
|||||||||||||||||
| 122 |  |
1-(9'-cis-octadecenyl)-2-octadecanoyl-3-glycerophosphocholine/1-oleyl-2-stearoyl-3-glycerophosphocholine |
1-O-(9'-cis-octadecenyl)-2-O-octadecanoyl-3-glycerophosphocholine(Ref. 0049) |
EEL0122 | Yosuke Koga |
1-C18:1-2-C18:0-GPC monoether/ether analog of PC |
C44H89O7NP | 775.154 | 232 |
[a]D = +2.6 /MD = 20.6 |
synthetic product |
|||||||||||||||||
| 123 |  |
3-O-{[2-(pyrrolidino)ethyl]-N-acetylcarbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL0123 | Yosuke Koga |
C32H61O6N3 | 583.843 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 124 |  |
3-O-{[2-(N-morphoryl)ethyl]-N-acetylcarbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL0124 | Yosuke Koga |
C32H61O7N3 | 599.843 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 125 |  |
EEL0125 | Yosuke Koga |
|
||||||||||||||||||||||||
| 126 |  |
alkenyl form of monogalactosyl diradylglycerol(Ref. 0148) |
1-O-alk-1'-enyl-2-O-acyl-3-O-galactosyl-sn-glycerol(Ref. 0148) |
EEL0126 | Yosuke Koga |
|
Clostridium acetobutylicum(Ref. 0148) |
|||||||||||||||||||||
| 127 |  |
alkenyl form of diglycosyl-diradylglycerol(Ref. 0148) |
1-O-alk-1'-enyl-2-O-acyl-3-O-b-glucosylgalactosyl-sn-glycerol(Ref. 0148) |
EEL0127 | Yosuke Koga |
|
Clostridium acetobutylicum(Ref. 0148) |
|||||||||||||||||||||
| 128 |  |
phosphatidylglycerol acetal of plasmenylethanolamine(Ref. 0149) |
EEL0128 | Yosuke Koga |
PGAPlaE(Ref. 0149) |
C83H157O17P2N | 1503.079 | |
1H-NMR [Spectrum 0032] (Ref. 0149), 13C-NMR [Spectrum 0033](Ref. 0149), 31P-NMR [Spectrum 0034] (Ref. 0149) |
positive FAB-MS [Spectrum 0035] (Ref. 0149), negative FAB-MS [Spectrum 0036] (Ref. 0149), [Spectrum 0037] (Ref. 0149) |
Clostridium butyricum(Ref. 0149) |
|||||||||||||||||
| 129 |  |
plasmenylglycerol acetal of plasmenylethanolamine(Ref. 0149) |
EEL0129 | Yosuke Koga |
PlaGAPlaE(Ref. 0149) |
C83H157O16P2N | 1487.079 | |
1H-NMR [Spectrum 0032] (Ref. 0149), 13C-NMR [Spectrum 0033] (Ref. 0149), 31P-NMR [Spectrum 0034] (Ref. 0149) |
Clostridium butyricum(Ref. 0149) |
||||||||||||||||||
| 130 |  |
phosphatidylglycerol acetal of plasmenylcardiolipin(Ref. 0150) |
EEL0130 | Yosuke Koga |
PGAPlaCL(Ref. 0150) |
|
1H-NMR, 3.53 ppm, 4.53 ppm, 5.9 ppm (a-vinyl ether proton), 5.1 ppm; 13C-NMR, 103 ppm, 65.3 ppm (Ref. 0150) |
Clostridium innocuum(Ref. 0150) |
||||||||||||||||||||
| 131 |  |
plasmenylglycerol acetal of plasmenylcardiolipin(Ref. 0150) |
EEL0131 | Yosuke Koga |
PlaGAPlaCL(Ref. 0150) |
|
1H-NMR, 3.53 ppm, 4.53 ppm, 5.9 ppm (a-vinyl ether proton), 5.1 ppm; 13C-NMR, 103 ppm, 65.3 ppm (Ref. 0150) |
Clostridium innocuum(Ref. 0150) |
||||||||||||||||||||
| 132 |  |
phosphatidylglycerol acetal of alkenylplasmenylcardiolipin(Ref. 0150) |
EEL0132 | Yosuke Koga |
PGAPlaCL(Ref. 0150) |
|
1H-NMR, 3.53 ppm, 4.53 ppm, 5.9 ppm (a-vinyl ether proton), 5.1 ppm; 13C-NMR, 103 ppm, 65.3 ppm (Ref. 0150) |
Clostridium innocuum(Ref. 0150) |
||||||||||||||||||||
| 133 | No image | lyso form of phosphatidylglycerol acetal of plasmenylcardiolipin(Ref. 0150) |
EEL0133 | Yosuke Koga |
LPGAPlaCL(Ref. 0150) |
1H-NMR, 3.53 ppm, 4.53 ppm, 3.6 ppm (Ref. 0150) |
Clostridium innocuum(Ref. 0150) |
|||||||||||||||||||||
| 134 |  |
phosphatidylglycerol acetal of plasmenylglycerol(Ref. 0150) |
EEL0134 | Yosuke Koga |
PGAPlaG(Ref. 0150) |
|
Clostridium innocuum(Ref. 0150) |
|||||||||||||||||||||
| 135 |  |
3-O-{2'-[6''-(s-2'''-amino-1''',3'''-dihydroxypropane-3'''-phospho)-a-D-galactopyranosyl]-a-D-glucopyranosyl}-1-alk-1''''-enyl-2-O-acyl-sn-glycerol(Ref. 0151) |
EEL0135 | Yosuke Koga |
Phosphoglycolipid I |
|
[Spectrum 0044] (Ref. 0151), [Spectrum 0045] (Ref. 0151), [Spectrum 0046](Ref. 0151) 13C-NMR (in ppm), 98.27 (C1 of D-Gal), 69.43 (C2of D-Gal), 70.18 (C3 of D-Gal), 69.57 (C4of D-Gal), 70.70 (C5 of D-Gal), 65.31 (C6 of D-Gal), 59.47 (C1 of aminopropanediol), 53.98 (C2 of aminopropanediol), 63.41 (C3 of aminopropanediol), 97.28 (C1 of D-Glc), 78.11 (C2 of D-Glc), 72.61 (C3 of D-Glc), 70.18 (C4 of D-Glc), 72.81 (C5 of D-Glc), 61.57 (C6 of D-Glc), 63.34 (C1 of Gro), 70.61 (C2 of Gro), 66.49 (C3 of Gro) 1H-NMR (in ppm), 4.95 (H1 of D-Gal), 3.74 (H2 of D-Gal), 3.80 (H3 of D-Gal), 3.94 (H4 of D-Gal), 4.25 (H5 of D-Gal), 3.97 (H6 of D-Gal), 3.97 (H6' of D-Gal), 3.68 (H1 of aminopropanediol), 3.75 (H1' of aminopropanediol), 3.42 (H2 of aminopropanediol), 3.98 (H3 of aminopropanediol), 4.03 (H3' of aminopropanediol), 4.98 (H1 of D-Glc), 3.55 (H2 of D-Glc), 3.75 (H3 of D-Glc), 3.43 (H4 of D-Glc), 3.54 (H5 of D-Glc), 3.79 (H6 of D-Glc), 3.79 (H6' of D-Glc), 4.16 (H1 of Gro), 4.42 (H1' of Gro), 5.20 (H2 of Gro), 3.62 (H3 of Gro), 3.80 (H3' of Gro), |
[Spectrum 0038] (Ref. 0151), [Spectra 0039 ] (Ref. 0151), [Spectrum 0040] (Ref. 0151), [Spectrum 0041] <0151>>, [Spectrum 0042] (Ref. 0151) |
Clostridium innocuum(Ref. 0151) |
|||||||||||||||||||
| 136 |  |
3-O-{2'-[6''-(s-2'''-amino-1''',3'''-dihydroxypropane-3'''-phospho)-a-D-galactopyranosyl]-6'-O-acyl-a-D-glucopyranosyl}-1-alk-1''''-enyl-2-O-acyl-sn-glycerol(Ref. 0151) |
EEL0136 | Yosuke Koga |
Phosphoglycolipid II |
|
[Spectrum 0038] (Ref. 0151), [Spectrum 0043] (Ref. 0151) 13C-NMR (in ppm), 98.77 (C1 of D-Gal), 69.27 (C2of D-Gal), 70.30 (C3 of D-Gal), 69.37 (C4of D-Gal), 70.58 (C5 of D-Gal), 64.89 (C6 of D-Gal), 59.39 (C1 of aminopropanediol), 54.05 (C2 of aminopropanediol), 63.21 (C3 of aminopropanediol), 97.17 (C1 of D-Glc), 77.79 (C2 of D-Glc), 72.59 (C3 of D-Glc), 70.29 (C4 of D-Glc), 70.50 (C5 of D-Glc), 70.86 (C6 of D-Glc), 63.33 (C1 of Gro), 70.95 (C2 of Gro), 66.40(C3 of Gro) 1H-NMR (in ppm), 4.93 (H1 of D-Gal), 3.73 (H2 of D-Gal), 3.79 (H3 of D-Gal), 3.94 (H4 of D-Gal), 4.24 (H5 of D-Gal), 3.97 (H6 of D-Gal), 3.93 (H6' of D-Gal), 3.66 (H1 of aminopropanediol), 3.74 (H1' of aminopropanediol), 3.41 (H2 of aminopropanediol), 3.96 (H3 of aminopropanediol), 4.03 (H3' of aminopropanediol), 4.94 (H1 of D-Glc), 3.56 (H2 of D-Glc), 3.72 (H3 of D-Glc), 3.29 (H4 of D-Glc), 3.75 (H5 of D-Glc), 4.18 (H6 of D-Glc), 4.36 (H6' of D-Glc), 4.20 (H1 of Gro), 4.42 (H1' of Gro), 5.20 (H2 of Gro), 3.62 (H3 of Gro), 3.78 (H3' of Gro), |
Clostridium innocuum(Ref. 0151) |
||||||||||||||||||||
| 137 |  |
alkenyl form of diglycosyl-diradylglycerol |
3-O-[2'-a-D-galactopyranosyl-a-D-glucopyranosyl]-2-O-acyl-1-O-alk-1''-enyl-sn-glycerol(Ref. 0152) |
EEL0137 | Yosuke Koga |
|
Clostridium innocuum(Ref. 0152) |
|||||||||||||||||||||
| 138 |  |
alkenyl form of monoglycosyl-diradylglycerol |
3-O-a-D-glucopyranosyl-2-O-acyl-1-O-alk-1''-enyl-sn-glycerol(Ref. 0152) |
EEL0138 | Yosuke Koga |
|
Clostridium innocuum(Ref. 0152) |
|||||||||||||||||||||
| 139 |  |
EEL0139 | Yosuke Koga |
C43H86O3 | 651.141 | |
||||||||||||||||||||||
| 140 |  |
EEL0140 | Yosuke Koga |
C43H86O3 | 651.141 | |
||||||||||||||||||||||
| 141 |  |
H-shaped caldarchaeol(Ref. 0155) |
EEL0141 | Yosuke Koga |
C86H170O6 | 1300.266 | |
Methanothermus fervidus(Ref. 0155) |
||||||||||||||||||||
| 142 |  |
C25,C25-archaetidyl(glucosyl)inositol(Ref. 0156) |
2,3-di-O-sesterterpanyl-sn-glycerol-1-phospho-1'-(2'-O-a-D-glucosyl)-myo-inositol(Ref. 0156) |
EEL0142 | Yosuke Koga |
AGI(Ref. 0156) |
C65H129O16P | 1197.684 | |
[Spectrum 0054] (Ref. 0156), [Spectrum 0051] (Ref. 0156), [Spectrum 0052] (Ref. 0156), [Spectrum 0053] (Ref. 0156) |
Aeropyrum pernix(Ref. 0156) |
|||||||||||||||||
| 143 |  |
C25,C25-archaetidylinositol(Ref. 0156) |
2,3-di-O-sesterterpanyl-sn-glycerol-1-phospho-myo-inositol(Ref. 0156) |
EEL0143 | Yosuke Koga |
AI(Ref. 0156) |
C59H119O11P | 1035.543 | |
Aeropyrum pernix(Ref. 0156) |
||||||||||||||||||
| 144 |  |
1-O-octadec-9-enylglycerol(Ref. 0157) |
EEL0144 | Yosuke Koga |
C21H42O3 | 342.556 | |
deep sea shark liver oil (Centrophorus squamosus) (Ref. 0157) |
||||||||||||||||||||
| 145 |  |
1-O-hexadec-9-enylglycerol(Ref. 0157) |
EEL0145 | Yosuke Koga |
C19H38O3 | 314.503 | |
deep sea shark liver oil (Centrophorus squamosus) (Ref. 0157) |
||||||||||||||||||||
| 146 |  |
EEL0146 | Yosuke Koga |
C98H192O19S | 1706.628 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 147 |  |
EEL0147 | Yosuke Koga |
C98H190O19S | 1704.612 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 148 |  |
EEL0148 | Yosuke Koga |
C98H188O19S | 1702.596 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 149 |  |
EEL0149 | Yosuke Koga |
C98H186O19S | 1700.580 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 150 |  |
EEL0150 | Yosuke Koga |
C98H184O19S | 1698.564 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 151 |  |
EEL0151 | Yosuke Koga |
C98H182O19S | 1696.548 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 152 |  |
EEL0152 | Yosuke Koga |
C98H180O19S | 1694.532 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 153 |  |
EEL0153 | Yosuke Koga |
C98H178O19S | 1692.517 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 154 |  |
EEL0154 | Yosuke Koga |
C98H176O19S | 1690.501 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 155 |  |
EEL0155 | Yosuke Koga |
C104H203O27PS | 1948.748 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 156 |  |
EEL0156 | Yosuke Koga |
C104H201O27PS | 1946.732 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 157 |  |
EEL0157 | Yosuke Koga |
C104H199O27PS | 1944.716 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 158 |  |
EEL0158 | Yosuke Koga |
C104H197O27PS | 1942.701 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 159 |  |
EEL0159 | Yosuke Koga |
C104H195O27PS | 1940.685 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 160 |  |
EEL0160 | Yosuke Koga |
C104H193O27PS | 1938.669 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 161 |  |
EEL0161 | Yosuke Koga |
C104H191O27PS | 1936.653 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 162 |  |
EEL0162 | Yosuke Koga |
C104H189O27PS | 1934.637 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 163 |  |
EEL0163 | Yosuke Koga |
C104H187O27PS | 1932.621 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 164 |  |
EEL0164 | Yosuke Koga |
C104H203O27PS | 1948.748 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 165 |  |
EEL0165 | Yosuke Koga |
C104H201O27PS | 1946.732 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 166 |  |
EEL0166 | Yosuke Koga |
C104H199O27PS | 1944.716 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 167 |  |
EEL0167 | Yosuke Koga |
C104H197O27PS | 1942.701 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 168 |  |
EEL0168 | Yosuke Koga |
C104H195O27PS | 1940.685 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 169 |  |
EEL0169 | Yosuke Koga |
C104H193O27PS | 1938.669 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 170 |  |
EEL0170 | Yosuke Koga |
C104H191O27PS | 1936.653 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 171 |  |
EEL0171 | Yosuke Koga |
C104H189O27PS | 1934.637 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 172 |  |
EEL0172 | Yosuke Koga |
C104H187O27PS | 1932.621 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 173 |  |
b-D-glucopyranosyl-diglycerol tetraether (Ref. 0159)/ b-D-Glcp-caldarchaeol |
EEL0173 | Yosuke Koga |
GL-IV(Ref. 0159) |
C92H178O11 | 1460.391 | |
molecular rotation +24 (20 C, in chloroform) |
103.6ppm indicates a b-glucosidic linkage |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||
| 174 |  |
b-D-glucopyranosyl-diglycerol tetraether (Ref. 0159)/ b-D-Glcp-caldarchaeol |
EEL0174 | Yosuke Koga |
GL-IV(Ref. 0159) |
C92H176O11 | 1458.375 | |
molecular rotation +24 (20 C, in chloroform) |
103.6ppm indicates a b-glucosidic linkage |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||
| 175 |  |
b-D-glucopyranosyl-diglycerol tetraether (Ref. 0159)/ b-D-Glcp-caldarchaeol |
EEL0175 | Yosuke Koga |
GL-IV(Ref. 0159) |
C92H174O11 | 1456.359 | |
molecular rotation +24 (20 C, in chloroform) |
103.6ppm indicates a b-glucosidic linkage |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||
| 176 |  |
Glcp-b1'-2'Glcp-b1'-1caldarchaeol/b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether/b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol(Ref. 0159) |
EEL0176 | Toshihiro Itoh |
GL-III(Ref. 0159) |
C98H192O16 | 1626.563 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 177 |  |
Glcp-b1'-2'Glcp-b1'-1caldarchaeol/b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether/b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol(Ref. 0159) |
EEL0177 | Toshihiro Itoh |
GL-III(Ref. 0159) |
C98H190O16 | 1624.548 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 178 |  |
Glcp-b1'-2'Glcp-b1'-1caldarchaeol/b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether/b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol(Ref. 0159) |
EEL0178 | Toshihiro Itoh |
GL-III(Ref. 0159) |
C98H188O16 | 1622.532 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 179 |  |
Glcp-b1'-2'Glcp-b1'-1caldarchaeol/b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether/b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol(Ref. 0159) |
EEL0179 | Toshihiro Itoh |
GL-III(Ref. 0159) |
C98H186O16 | 1620.516 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 180 |  |
Glcp-b1'-2'Glcp-b1'-1caldarchaeol/b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether/b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol(Ref. 0159) |
EEL0180 | Toshihiro Itoh |
GL-III(Ref. 0159) |
C98H184O16 | 1618.500 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 181 |  |
b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0159) / b-D-Glcp-(1,2)-b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol |
EEL0181 | Toshihiro Itoh |
GL-II(Ref. 0159) |
C104H202O21 | 1788.704 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 182 |  |
b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0159) / b-D-Glcp-(1,2)-b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol |
EEL0182 | Toshihiro Itoh |
GL-II(Ref. 0159) |
C104H200O21 | 1786.688 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 183 |  |
b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0159) / b-D-Glcp-(1,2)-b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol |
EEL0183 | Toshihiro Itoh |
GL-II(Ref. 0159) |
C104H198O21 | 1784.672 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 184 |  |
b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0159) / b-D-Glcp-(1,2)-b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol |
EEL0184 | Toshihiro Itoh |
GL-II(Ref. 0159) |
C104H196O21 | 1782.656 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 185 |  |
b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyl-(1,2)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0159) / b-D-Glcp-(1,2)-b-D-Glcp-(1,2)-b-D-Glcp-caldarchaeol |
EEL0185 | Toshihiro Itoh |
GL-II(Ref. 0159) |
C104H194O21 | 1780.641 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
|||||||||||||||||||
| 186 |  |
EEL0186 | Toshihiro Itoh |
GLP-I(Ref. 0159) |
C110H213O29P | 2030.825 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
||||||||||||||||||||
| 187 |  |
EEL0187 | Toshihiro Itoh |
GLP-I(Ref. 0159) |
C110H211O29P | 2028.809 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
||||||||||||||||||||
| 188 |  |
EEL0188 | Toshihiro Itoh |
GLP-I(Ref. 0159) |
C110H209O29P | 2026.793 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
||||||||||||||||||||
| 189 |  |
EEL0189 | Toshihiro Itoh |
GLP-I(Ref. 0159) |
C110H207O29P | 2024.777 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
||||||||||||||||||||
| 190 |  |
EEL0190 | Toshihiro Itoh |
GLP-I(Ref. 0159) |
C110H205O29P | 2022.761 | |
Pyrobaculum islandicum, Pyrobaculum organotrophucum(Ref. 0159) |
||||||||||||||||||||
| 191 |  |
unsaturated lysoarchaetidic acid |
(S)-3-O-geranylgeranylglycerylphosphate/3-geranylgeranyl-sn-glycerol-1-phosphate/3-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol-1-phosphate |
EEL0201 | Yosuke Koga |
LysoAA/LAA |
C23H41O6P | 444.542 | |
biosynthetic intermediate |
Methanothermobacter marburgensis enzymatic synthesis(Ref. 0174) |
biosynthesized from sn-G-1-P and GGPP by GGGPsynthase |
||||||||||||||||
| 192 |  |
unsaturated archaetidic acid |
2,3-di-O-geranylgeranyl-sn-glycerol-1-phosphate/2,3-di-O-geranylgeranyl-sn-glycerol-1-phosphate/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol-1-phosphate |
EEL0202 | Yosuke Koga |
unsaturated AA |
C43H73O6P | 717.010 | |
biosynthetic intermediate |
positive FAB-MS 740(M+Na+H)+, negative FAB-MS 715(M-H)-(Ref. 0166) |
biosynthesized from GGGP DGGGP synthase |
||||||||||||||||
| 193 |  |
CDP-archaeol |
cytidine-diphospho-(2,3-di-O-geranylgeranyl-sn-glycerol)/cytidine-diphospho-(2,3-di-O-3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0203 | Yosuke Koga |
C52H85O13N3P2 | 1022.191 | |
biosynthetic intermediate |
positive FAB-MS 739(M-CMP+Na+H)+, 1021(M)+, 1043(M-H+Na)+, 1065(M-2H+2Na)+(Ref. 0166) |
TLC Rf=0.37 chloroform-methanol-NH3 (60:35:8); Rf=0.40 chloroform-methanol-acetic acid-water(80:30:15:5)(Ref. 0166) |
Methanothermobacter thermautotrophicus(Ref. 0166) |
biosynthesized from unsaturated AA/CDP-archaeol synthase |
|||||||||||||||
| 194 |  |
unsaturated archaetidylserine |
2,3-di-O-geranylgeranyl-sn-glycerol-1-phospho-L-serine/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol-1-phospho-L-serine |
EEL0204 | Yosuke Koga |
AS |
C46H78O8NP | 804.087 | |
biosynthetic intermediate |
positive FAB-MS 803(M)+, 827(M+Na+H)+, 762(M-serine+Na+H)+, 784(M-serine+3Na)+(Ref. 0175) |
synthesized from CDP-archaeol and L-serine, AS synthase |
||||||||||||||||
| 195 |  |
a-monogeranylgeranylglycerol |
(R)-3-O-GGglycerol/3-geranylgeranyl-sn-glycerol/3-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0205 | Yosuke Koga |
C23H40O3 | 364.562 | |
(CCl4)3590, 3454 (Br), 2970, 2924, 2863, 1704, 1648, 1530, 1364, 1310, 1098, 1048, 1027, 809 (Ref. 0174) |
1H NMR (300MHz, CDCl3)1.5-1.7 (15H, d, 5 CH3), 1.9-2.1(12H, m, 6 CH2), 3.1(br, H, on hydroxyl), 3.49(2 H, m), 3.62(1 H, dd, J=4.3, 11.8Hz), 3.70(1 H, dd, J=4.3, 11.8Hz), 3.85(1 H, m), 4.0[2H, d, J=6.7Hz, H at C(1) on geranylgeranyl], 5.0-5.13[3H, m, H at C(6), C(10), and C(14) on geranylgeranyl], 5.30[1 H, t, J=6.7Hz, H at C(2) on geranylgeranyl]; 13C NMR (75MHz, CDCl3)16.0(q), 16.5(q), 17.7(q), 25.7(q), 26.3(t), 26.6(t), 26.8(t), 39.6(t), 39.68(t), 39.71(t), 64.2(t), 67.9(t), 70.5(d), 71.6(t), 120.3(d), 123.7(d), 124.2(d), 124.4(d), 131.3(s), 135.0(s), 135.4(s), 141.0(s) (Ref. 0174) |
(CI, methane) 69(100), 81(29.7), 95(12.9), 109(13.7), 121(15), 135(13.2), 149(7.2), 163(5.2), 175(3), 189(4.2), 211(4), 225(2.6), 253(2.6), 267(3.8), 273(6.1), 351(2.5), 365(M+1, 5.7) (Ref. 0174) |
silica gel flash chromatography (Rf=0.30, ethyl acetate-hexane(1:1))(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||
| 196 |  |
CDP-archaeol |
cytidine-diphospho-(2,3-di-O-phytanyl-sn-glycerol)/cytidine-diphospho-(2,3-di-O-3',7',11',15'-tetramethylhexadecyl)-sn-glycerol |
EEL0206 | Yosuke Koga |
C52H101O13N3P2 | 1038.318 | |
FAB-MS 731(M-CMP)-, 1036(M-H)(Ref. 0166) |
TLC Rf=0.37 chloroform-methanol-NH3(60:35:8); Rf=0.40 chloroform-methanol-acetic acid-water (80:30:15:5)(Ref. 0166) |
synthetic compound(Ref. 0166) |
|||||||||||||||||
| 197 |  |
b-monogeranylgeranylglycerol |
(R)-2-O-GGglycerol/2-geranylgeranyl-sn-glycerol/2-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0207 | Yosuke Koga |
C23H40O3 | 364.562 | |
IR(neat) 3450(br), 2965, 2925, 2875, 1710, 1670, 1445, 1380, 1110, 1050, 910, 730(Ref. 0174) |
1H NMR (300MHz,CDCl3)1.5-1.7(15H,5CH3), 1.9-2.1(12H,6CH2), 3.5(1H, m), 3.67(2H, dd, J=4.3, 11.6Hz, H of glyceryl methylene), 3.75(2H, dd, J=4.3Hz, 11.6Hz, H of glyceryl methylene), 4.13[2H, d, J=6.7Hz, H at C(1) on geranylgeranyl], 5.08[3H, m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.35[1H, t, J=6.7Hz H at C(2) on geranylgeranyl] 13C NMR(75MHz,CDCl3)16.1(q), 16.7(q), 17.8(q), 25.8(q), 26.3(t), 26.7(t), 26.8(t), 39.6(t), 39.7(t), 39.8(t), 62.4(t), 66.4(t), 78.7(d), 120.4(d), 123.6(d), 124.1(d), 124.3(d), 131.2(s), 134.9(s), 135.4(s), 141.0(s)(Ref. 0174) |
(EI 17eV)69(100), 81(99), 93(50), 107(25.8), 121(32.8), 135(37.5), 149(9.0), 161(6.6), 175(2.7), 189(3.4), 203(6.3), 215(1.4), 229(2.9), 243(1.1), 257(1.9), 272(2.5), 364(M+, 1.2)(Ref. 0174) |
TLC Rf=0.30, ethyl acetate-hexane(1:1)(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||
| 198 |  |
(S)-1,2-O-Isopropylidene-3-O-geranylgeranylglycerol |
EEL0208 | Yosuke Koga |
C25H41O3 | 389.591 | |
1H NMR (300MHz,CDCl3)1.33(3H, s, CH3), 1.42(3H, s, CH3), 1.55-1.65(15H, m, 5CH3 on geranylgeranyl), 1.9-2.1(12H, br m, 6CH2 on geranylgeranyl), 3.38-3.68(3H, br m), 4.0-4.1(3H, m), 4.23-4.3(1H, m), 5.08[3H, br m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.3[1H, t, J=6.8Hz H at C(2) on geranylgeranyl] 13C NMR(75MHz,CDCl3)16.1(q), 16.6(q), 17.8(q), 25.5(q), 25.8(q), 26.4(t), 26.7(t), 26.87(t), 26.93(q), 39.7(t), 39.81(t), 39.87(t), 67.1(t), 68.1(t), 71.1(t), 74.9(d), 109.5(s), 120.7(d), 123.9(d), 124.3(d), 124.5(d), 131.4(s), 135.1(s), 135.4(s), 140.6(s)(Ref. 0174) |
(EI 70eV)69(100), 93(22), 121(10.6), 135(15.9), 161(5.7), 175(2.9), 189(1.9), 203(2.9), 225(2.4), 272(3.9), 389(M-CH3, 2.1), 404(M+, 0.7)(Ref. 0174) |
silica gel flash chromatography (Rf=0.35, ethyl acetate-hexane(2:23) )(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||||
| 199 |  |
(S)-1-O-(tert-butyldimethylsilyl)-2-O-geranylgeranyl-3-O-benzylglycerol |
EEL0209 | Yosuke Koga |
C36H60O3Si | 568.945 | |
1H NMR (300MHz,CDCl3) 0.1(6H, s, 2CH3 on Si), 0.9(9H, s, 3CH3 on tert-butyl), 1.55-1.7(15H, m, 5CH3 on geranylgeranyl), 1.95-3.15(12H, br m, 6CH2 on geranylgeranyl), 3.45-3.70(5H, br m), 4.18[2H, d, J=6.7Hz H at C(1) on geranylgeranyl], 4.58(2H, s, CH2), 5.0-5.2[3H m, H at C(6), C(10) and C(14)], 5.4 [1H, t, J=6.7Hz H at C(2) on geranylgeranyl], 7.25(5H, br m) 13C NMR(75MHz, CDCl3)-5,2(q), 16.0(q), 16.5(q), 17.7(q), 18.2(q), 18.5(s), 25.2(q), 25.9(q), 26.37(t), 26.44(t), 27.8(t), 39.6(t), 39.7(t), 63.0(t), 66.9(t), 70.2(t), 73.5(t), 78.5(d), 121.2(d), 123.9(d), 124.2(d), 124.4(d), 127.46(d), 127.50(d), 128.3(d), 128.5(s), 132.0(s), 134.9(s), 135.2(s), 139.7(s)(Ref. 0174) |
(CI methane) 69(61.9), 81(40.9), 91(90.9), 109(15.5), 121(15.1), 137(18.9), 149(15.7), 163(7.4), 175(3.3), 189(8.6), 217(9.1), 239(11.4), 257(2.2), 273(19.4), 297(100), 568(M+1, 2.0)(Ref. 0174) |
chromatography on silica (Rf=0.57, ethyl acetate-hexane(2:23) )(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||||
| 200 |  |
(S)-1-O-(tert-butyldimethylsilyl)-2-O-geranylgeranylglycerol |
EEL0210 | Yosuke Koga |
C29H54O3Si | 478.823 | |
1H NMR (300MHz,CDCl3) 0.1(6H, s, 2CH3 on Si), 0.95(9H, s, 3CH3 on tert-butyl), 1.6-1.75(15H, m, 5CH3 on geranylgeranyl), 2.1-2.3(12H, br m, 6CH2 on geranylgeranyl), 3.5-3.85(5H, m), 4.15[1H, dd, J=5.9, 11.2Hz H at C(1) on geranylgeranyl], 4.24[1H, dd, J=5.9, 11.2Hz H at C(1) on geranylgeranyl], 5.12[3H, m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.45 [1H, t, J=5.9Hz, H at C(2) on geranylgeranyl], 13C NMR(75MHz, CDCl3)-5,2(q), 16.0(q), 16.5(q), 17.7(q), 18.2(q), 18.5(s), 25.7(q), 25.8(q), 26.3(t), 26.6(t), 26.7(t), 39.6(t), 39.67(t), 39.70(t), 63.0(t), 63.1(t), 66.6(t), 78.9(d), 120.7(d), 123.8(d), 124.1(d), 124.3(d), 131.3(s), 134.9(s), 135.4(s), 140.5(s)(Ref. 0174) |
(EI 70eV) 69(100), 81(99), 93(59.8), 107(39), 121(62.9), 137(99), 149(44), 161(10.8), 189(11.6), 203(31.5), 229(5.5), 257(3.1), 272(8.4), 478(M+, 1.6)(Ref. 0174) |
chromatography on silica (Rf= 0.36, ethyl acetate-hexane(15:85) )(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||||
| 201 |  |
(S)-1-O-(tert-butyldimethylsilyl)-2,3-di-O-geranylgeranylglycerol |
EEL0211 | Yosuke Koga |
C49H86O3Si | 751.291 | |
1H NMR (300MHz,CDCl3) 0.10(6H, s, 2CH3 on Si), 0.85(9H, s, 3CH3 on tert-butyl), 1.55-1.75(30H, m, 10CH3 on geranylgeranyl), 1.95-2.15(24H, br m, 12CH2 on geranylgeranyl), 3.44-3.65(5H, m), 3.95(2H, d, J=6.6Hz), 4.13(2H, d, J=6.8Hz), 5.05(6H, br m), 5.36(2H, m) 13C NMR(75MHz, CDCl3)-5,2(q), 16.1(q), 16.7(q), 17.8(q), 18.4(q), 25.8(q), 26.0(q), 26.5(t), 26.8(t), 26.9(t), 39.7(t), 38.8(t), 63.1(t), 67.0(t), 70.8(t), 73.4(t), 78.6(d), 121.3(d), 123.9(d), 124.1(d), 124.3(d), 127.4(d), 127.5(d), 128.2(d), 131.1(s), 134.8(s), 135.1(s), 138.4(s),139.6(s)(Ref. 0174) |
(CI, methane) 69(100), 81(68.4), 93(29.9), 107(13.8), 123(26.3), 135(13), 149(15.5), 161(7.5), 171(4.6), 189(11.3), 207(34.9), 217(11.1), 273(18.4), 477(18.8), 545(2.5), 750(M+1, 1.3)(Ref. 0174) |
TLC (Rf= 0.15 ethyl acetate-hexane(1:50))(Ref. 0174) |
synthetic compound(Ref. 0174) |
|||||||||||||||||
| 202 |  |
unsaturated benzylarchaeol |
2,3-di-O-geranylgeranyl-1-benzyl-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-1-benzyl-sn-glycerol |
EEL0212 | Yosuke Koga |
C50H78O3 | 727.153 | |
synthetic compound(Ref. 0166) |
|||||||||||||||||||
| 203 |  |
1,2-di-O-geranylgeranyl-3-benzyl-sn-glycerol/1,2-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-3-benzyl-sn-glycerol |
EEL0213 | Yosuke Koga |
C50H78O3 | 727.153 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 204 |  |
benzylarchaeol |
2,3-di-O-phytyl-1-benzyl-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2'-enyl)-1-benzyl-sn-glycerol |
EEL0214 | Yosuke Koga |
C50H90O3 | 739.248 | |
synthetic compound(Ref. 0166) |
|||||||||||||||||||
| 205 |  |
2,3-di-O-oleyl-1-benzyl-sn-glycerol/2,3-di-O-(9'-cis-octadecenyl)-sn-glycerol |
EEL0215 | Yosuke Koga |
C46H82O3 | 683.141 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 206 |  |
unsaturated archaeol |
(R)-2,3-di-O-geranylgeranylglycerol/2,3-di-O-geranylgeranyl-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethyl-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0216 | Yosuke Koga |
C43H72O3 | 637.030 | |
1H NMR (300MHz,CDCl3) 1.55-1.75(30H, m, 10CH3), 1.90-2.15(24H, br m, 12CH2), 3.43-3.55(4H, m), 3.67-3.76(1H, m), 3.98-4.01[2H, d, J=6.8Hz, H at C(1) of geranylgeranyl at glyceryl C(3)], 4.05-4.11[1H, dd, J=7.1, 12.8Hz, H at C(1) of geranylgeranyl at glyceryl C(2)], 4.14-4.20[1H, dd, J=7.1, 12.8Hz, H at C(1) of geranylgeranyl at glyceryl C(2)], 5.15(6H, m), 5.4(2H, m) 13C NMR(75MHz, CDCl3) 16.1(q), 16.60(q), 16.63(q), 17.8(q), 25.8(q), 26.4(q), 26.5(t), 26.7(t), 26.9(t), 29.8(t), 39.7(t), 39.76(t), 39.78(t), 63.2(t), 66.6(t), 68.0(t), 70.1(t), 77.5(d), 120.5(d), 120.8(d), 123.8(d), 124.2(d), 124.4(d), 131.2(s), 134.9(s), 135.30(s), 135.32(s), 140.5(s)(Ref. 0174) |
(EI 7eV) 69(100), 81(99), 93(89), 103(47.6), 107(55.5), 121(60.2), 135(65.6), 147(28.1), 161(25.4), 177(7.8), 191(4.7), 203(25.6), 229(3.1), 257(2.3), 272(25.8), 363(26.5), 636(M+, 0.5)(Ref. 0174) |
TLC Rf= 0.22 ethyl acetate-hexane (3:22) |
|||||||||||||||||
| 207 |  |
1,2-di-O-geranylgeranyl-sn-glycerol/1,2-di-O-(3',7',11',15'-tetramethyl-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0217 | Yosuke Koga |
C43H72O3 | 637.030 | |
[a]D= -9.7 (Ref. 0166) |
synthetic compound(Ref. 0166) |
|||||||||||||||||||
| 208 |  |
2,3-di-O-phytyl-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethyl-2'-hexadecyl)-sn-glycerol |
EEL0218 | Yosuke Koga |
C43H84O3 | 649.125 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 209 |  |
2,3-di-O-oleyl-sn-glycerol/2,3-di-O-(9'-cis-octadecenyl)-sn-glycerol |
EEL0219 | Yosuke Koga |
C39H76O3 | 593.019 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 210 |  |
2,3-di-O-geranylgeranyl-1-(dimethylphospho)-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-1-(dimethylphospho)-sn-glycerol |
EEL0220 | Yosuke Koga |
C45H77O6P | 745.063 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 211 |  |
1,2-di-O-geranylgeranyl-3-(dimethylphospho)-sn-glycerol/1,2-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-3-(dimethylphospho)-sn-glycerol |
EEL0221 | Yosuke Koga |
C45H77O6P | 745.063 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 212 |  |
2,3-di-O-phytyl-1-(dimethylphospho)-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2'-enyl)-1-(dimethylphospho)-sn-glycerol |
EEL0222 | Yosuke Koga |
C45H89O6P | 757.158 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 213 |  |
2,3-di-O-oleyl-1-(dimethylphospho)-sn-glycerol/2,3-di-O-(9'-cis-octadecenyl)-1-(dimethylphospho)-sn-glycerol |
EEL0223 | Yosuke Koga |
C41H81O6P | 701.052 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 214 |  |
1,2-di-O-geranylgeranyl-sn-glycerol-3-phosphate/1,2-di-O-(3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol-3-phosphate |
EEL0224 | Yosuke Koga |
C43H73O6P | 717.010 | |
positive FAB-MS 740(M+Na+H)+, negative FAB-MS 715(M-H)-(Ref. 0166) |
synthetic compound(Ref. 0166) |
|||||||||||||||||||
| 215 |  |
unsaturated archaetidic acid |
2,3-di-O-phytyl-sn-glycerol-1-phosphate/2,3-di-O-(3',7',11',15'-tetramethylhexadec-2'-enyl)-sn-glycerol-1-phosphate |
EEL0225 | Yosuke Koga |
C43H85O6P | 729.105 | |
FAB-MS 752(M+Na+H)+(Ref. 0166) |
synthetic compound(Ref. 0166) |
||||||||||||||||||
| 216 |  |
2,3-di-O-oleyl-sn-glycerol-1-phosphate/2,3-di-O-(9'-cis-octadecenyl)-sn-glycerol-1-phosphate |
EEL0226 | Yosuke Koga |
C39H77O6P | 672.999 | |
FAB-MS 695(M+Na)+(Ref. 0166) |
synthetic compound(Ref. 0166) |
|||||||||||||||||||
| 217 |  |
2,3-di-O-phytanyl-1-(diphenylphospho)-sn-glycerol/2,3-di-O-(3',7',11',15'-tetramethylhexadecyl)-1-sn-glycerol |
EEL0227 | Yosuke Koga |
C55H97O6P | 885.329 | |
synthetic compound(Ref. 0166) |
||||||||||||||||||||
| 218 |  |
CDP-digeranylgeranylglycerol |
cytidine-diphospho-(1,2-di-O-geranylgeranyl)-sn-glycerol/cytidine-diphospho-(1.2-di-O-3',7',11',15'-tetramethylhexadec-2',6',10',14'-tetraenyl)-sn-glycerol |
EEL0228 | Yosuke Koga |
C52H86O13N3P2 | 1023.199 | |
||||||||||||||||||||
| 219 |  |
CDP-1,2-dioleylglycerol |
cytidine-diphospho-(1,2-di-O-oleyl)-sn-glycerol/cytidine-diphospho-(1,2-di-O-9'-cis-octadecenyl-sn-glycerol) |
EEL0229 | Yosuke Koga |
C48H90O13N3P2 | 979.188 | |
synthetic compound(Ref. 0175) |
|||||||||||||||||||
| 220 |  |
archaetidylcholine (mixed hydrocarbon) |
2,3-di-O-alkyl-sn-glycerol-1-phosphocholine |
EEL0230 | Yosuke Koga |
|
TLC Rf=0.20 chloroform-methanol-acetone-acetic acid-water(6:2:8:2:1) (Ref. 0167) |
Methanopyrus kandleri(Ref. 0167) |
||||||||||||||||||||
| 221 |  |
archaetidylcholine |
2,3-di-O-phytanyl-sn-glycerol-1-phosphocholine/2,3-di-O-(3',7',11',15'-tetramethylhexadecanyl)-sn-glycerol-1-phosphocholine |
EEL0231 | Yosuke Koga |
C48H106O6NP | 824.332 | |
FAB-MS 818(M+H)+, 781(M+Na-N(CH3)3)+, 536(M-C20H41)+, 240(M+H-C20H41-OC20H41)+, 224(M+H-2(OC20H41))+, 840(M+Na)+(Ref. 0167) |
TLC Rf=0.20 chloroform-methanol-acetone-acetic acid-water(6:2:8:2:1) (Ref. 0167) |
Methanopyrus kandleri(Ref. 0167) |
|||||||||||||||||
| 222 |  |
b-D-gulosylcaldarchaeol |
EEL0232 | Yosuke Koga |
GL-1a |
C92H178O11 | 1460.391 | |
TLC Rf=0.52 chloroform-methanol-1M NH4OH (65:35:5): [Chromatogram 0025] (Ref. 0170) [Chromatogram 0026] (Ref. 0170) |
Thermoplasma acidophilum(Ref. 0170) |
||||||||||||||||||
| 223 |  |
a-D-glucosylcaldarchaeol |
EEL0233 | Yosuke Koga |
GL-1b |
C92H182O11 | 1464.423 | |
TLC Rf=0.76 chloroform-methanol-1M NH4OH (65:35:5): [Chromatogram 0025] (Ref. 0170) [Chromatogram 0026] (Ref. 0170) |
Thermoplasma acidophilum(Ref. 0170) |
||||||||||||||||||
| 224 |  |
1-(b-D-gulosyl)-1'-(b-D-gulosyl)-caldarchaeol |
EEL0234 | Yosuke Koga |
GL-2a |
C98H188O16 | 1622.532 | |
TLC Rf=0.17 chloroform-methanol-1M NH4OH (65:35:5): [Chromatogram 0025] (Ref. 0170) [Chromatogram 0026] (Ref. 0170) |
Thermoplasma acidophilum(Ref. 0170) |
||||||||||||||||||
| 225 |  |
1-(b-D-gulosyl)-1'-(a-D-glucosyl)-caldarchaeol |
EEL0235 | Yosuke Koga |
GL-2b |
C98H188O16 | 1622.532 | |
TLC Rf=0.33 chloroform-methanol-1M NH4OH (65:35:5): [Chromatogram 0025] (Ref. 0170) [Chromatogram 0026] (Ref. 0170) |
Thermoplasma acidophilum(Ref. 0170) |
||||||||||||||||||
| 226 |  |
1-(a-D-glucosyl)-1'-(a-D-glucosyl)-caldarchaeol |
EEL0236 | Yosuke Koga |
GL-2c |
C98H188O16 | 1622.532 | |
TLC Rf=0.56 chloroform-methanol-1M NH4OH (65:35:5): [Chromatogram 0025] (Ref. 0170) [Chromatogram 0026] (Ref. 0170) |
Thermoplasma acidophilum(Ref. 0170) |
||||||||||||||||||
| 227 |  |
a-D-glucosylcaldarchaetidylglycerol |
EEL0237 | Yosuke Koga |
GPL-K |
C95H187O16P | 1616.465 | |
1H NMR 13C NMR(Ref. 0171) |
FAB-MS 1614(M-H)-, 1452(M-hexose)-(Ref. 0171) |
boronic acid-impregnated silica gel HPTLC Rf= 0.26 chloroform-methanol-NH3(65:35:5): [Chromatogram 0027] (Ref. 0171) |
Thermoplasma acidophilum(Ref. 0171) |
||||||||||||||||
| 228 |  |
b-D-gulosylcaldarchaeol |
EEL0238 | Yosuke Koga |
U4 |
C92H182O11 | 1464.423 | |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||||
| 229 |  |
1-b-D-gulosyl-1'-b-D-gulosyl-caldarchaeol |
EEL0239 | Yosuke Koga |
A2 |
C98H184O16 | 1618.500 | |
SIMS 1616.9(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 230 |  |
b-D-gulosylcaldarchaetidylglycerol |
EEL0240 | Yosuke Koga |
A3 |
C95H189O16P | 1618.481 | |
SIMS 1616.9(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 231 |  |
b-D-gulosylcaldarchaetidylglycerol |
EEL0241 | Yosuke Koga |
A4-1 |
C95H183O16P | 1612.434 | |
SIMS 1609.9(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 232 |  |
a-mannosyl(1-3)-b-gulosylcaldarchaeol |
EEL0242 | Yosuke Koga |
A4-2 |
C98H188O16 | 1622.532 | |
SIMS 1620.7(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 233 |  |
1-a-mannosyl-(1-3)-b-gulosyl-1'-b-gulosylcaldarchaeol |
EEL0243 | Yosuke Koga |
A5 |
C104H196O21 | 1782.656 | |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
||||||||||||||||||
| 234 |  |
a-D-mannosyl-(1-3)-a-D-mannosyl-(1-3)-b-gulosyl-caldarchaeol |
EEL0244 | Yosuke Koga |
A6 |
C104H196O21 | 1782.656 | |
SIMS 1786.0(M-H)- (cyclopentane ring, 0)(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 235 |  |
trimannosyl-glucosylcaldarchaeol |
EEL0245 | Yosuke Koga |
A7 |
C110H212O26 | 1950.845 | |
SIMS 1946.3(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 236 |  |
a-D-mannosyl-(1-3)-b-D-gulosylcaldarchaetidylglycerol |
EEL0246 | Yosuke Koga |
C2 |
C101H193O21P | 1774.574 | |
SIMS 1771.3(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 237 |  |
a-D-mannosyl-(1-3)-a-D-mannosyl-(1-3)-b-D-gulosylcaldarchaetidylglycerol |
EEL0247 | Yosuke Koga |
C3 |
C107H205O26P | 1938.731 | |
SIMS 1933.7(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 238 |  |
a-D-mannosyl-(1-3)-a-D-mannosyl-(1-3)-a-D-mannosyl-(1-3)-b-D-gulosylcaldarchaetidylglycerol |
EEL0248 | Yosuke Koga |
C5 |
C113H217O31P | 2102.887 | |
SIMS 2098.9(M-H)-(Ref. 0168) |
HPLC-evaporative light-scattering detection: [Chromatogram 0029] (Ref. 0168) HPTLC: [Chromatogram 0028] (Ref. 0168) |
Thermoplasma acidophilum(Ref. 0168) |
|||||||||||||||||
| 239 |  |
2-(3'-sulfo-b-D-galactosyl-(1-6)-b-D-mannosyl)-6-archaetidyl-a-D-glucosylarchaeol/3-HSO3-Galp-b1,6Manp-a1,2Glcp-a1,1-[sn-2,3-di-O-phytanylglycerol]-6-[phospho-sn-2,3-di-O-phytanylglycerol |
EEL0249 | Yosuke Koga |
Lipid X |
C104H205O26PS | 1934.765 | |
Halobacterium salinarum L33 purple membrane(Ref. 0173) |
|||||||||||||||||||
| 240 |  |
1,3-diarchaetidylglycerol/diether analog of cardiolipin /sn-2,3-di-O-phytanyl-1-phosphoglycerol-3-phospho-sn-2,3-di-O-phytanylglycerol |
1,3-di-O-(2',3'-di-O-phytanyl-sn-glycerophosphoryl)-glycerol/1,3-di-O-(2',3'-di-O-(3'',7'',11'',15''-tetramethylhexadecyl)-sn-glycerophosphoryl)-glycerol |
EEL0250 | Yosuke Koga |
Lipid Y |
C89H182O13P2 | 1522.337 | |
Halobacterium salinarum L33 purple membrane(Ref. 0173) |
||||||||||||||||||
| 241 |  |
crenarchaeol |
EEL0251 | Yosuke Koga |
C86H162O6 | 1292.203 | |
13C and 1H-NMR(Ref. 0177) |
holocene sediments/ancient sediments(Ref. 0169) |
|||||||||||||||||||
| 242 |  |
tetraether lipid X |
EEL0252 | Yosuke Koga |
C66H132O6 | 1021.751 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 243 |  |
tetraether lipid XI |
EEL0253 | Yosuke Koga |
C67H134O6 | 1035.777 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 244 |  |
tetraether lipid XII |
EEL0254 | Yosuke Koga |
C68H136O6 | 1049.804 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 245 |  |
tetraether lipid XIII |
EEL0255 | Yosuke Koga |
C66H130O6 | 1019.735 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 246 |  |
tetraether lipid XIV |
EEL0256 | Yosuke Koga |
C66H128O6 | 1017.719 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 247 |  |
tetraether lipid XV |
EEL0257 | Yosuke Koga |
C78H156O6 | 1190.070 | |
holocene sediments/ancient sediments(Ref. 0169) |
||||||||||||||||||||
| 248 |  |
crenarchaeol : regioisomer |
EEL0258 | Yosuke Koga |
C86H162O6 | 1292.203 | |
|||||||||||||||||||||
| 249 |  |
EEL1001 | Toshihiro Itoh |
C98H190O16 | 1624.548 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 250 |  |
EEL1002 | Toshihiro Itoh |
C98H188O16 | 1622.532 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 251 |  |
EEL1003 | Toshihiro Itoh |
C98H186O16 | 1620.516 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 252 |  |
EEL1004 | Toshihiro Itoh |
C98H184O16 | 1618.500 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 253 |  |
EEL1005 | Toshihiro Itoh |
C98H182O16 | 1616.484 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 254 |  |
EEL1006 | Toshihiro Itoh |
C98H180O16 | 1614.468 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 255 |  |
EEL1007 | Toshihiro Itoh |
C98H178O16 | 1612.452 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 256 |  |
EEL1008 | Toshihiro Itoh |
C98H176O16 | 1610.436 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 257 |  |
EEL1009 | Toshihiro Itoh |
C104H201O24P | 1866.668 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 258 |  |
EEL1010 | Toshihiro Itoh |
C104H199O24P | 1864.652 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 259 |  |
EEL1011 | Toshihiro Itoh |
C104H197O24P | 1862.636 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 260 |  |
EEL1012 | Toshihiro Itoh |
C104H195O24P | 1860.620 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 261 |  |
EEL1013 | Toshihiro Itoh |
C104H193O24P | 1858.605 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 262 |  |
EEL1014 | Toshihiro Itoh |
C104H191O24P | 1856.589 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 263 |  |
EEL1015 | Toshihiro Itoh |
C104H189O24P | 1854.573 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 264 |  |
EEL1016 | Toshihiro Itoh |
C104H187O24P | 1852.557 | |
core lipid (Ref. 0134) |
|||||||||||||||||||||
| 265 |  |
EEL1017 | Toshihiro Itoh |
C98H190O16 | 1624.548 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 266 |  |
EEL1018 | Toshihiro Itoh |
C98H188O16 | 1622.532 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 267 |  |
EEL1019 | Toshihiro Itoh |
C98H186O16 | 1620.516 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 268 |  |
EEL1020 | Toshihiro Itoh |
C98H184O16 | 1618.500 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 269 |  |
EEL1021 | Toshihiro Itoh |
C98H182O16 | 1616.484 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 270 |  |
EEL1022 | Toshihiro Itoh |
C98H180O16 | 1614.468 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 271 |  |
EEL1023 | Toshihiro Itoh |
C98H178O16 | 1612.452 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 272 |  |
EEL1024 | Toshihiro Itoh |
C98H176O16 | 1610.436 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 273 |  |
EEL1025 | Toshihiro Itoh |
C104H201O24P | 1866.668 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 274 |  |
EEL1026 | Toshihiro Itoh |
C104H199O24P | 1864.652 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 275 |  |
EEL1027 | Toshihiro Itoh |
C104H197O24P | 1862.636 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 276 |  |
EEL1028 | Toshihiro Itoh |
C104H195O24P | 1860.620 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 277 |  |
EEL1029 | Toshihiro Itoh |
C104H193O24P | 1858.605 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 278 |  |
EEL1030 | Toshihiro Itoh |
C104H191O24P | 1856.589 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 279 |  |
EEL1031 | Toshihiro Itoh |
C104H189O24P | 1854.573 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 280 |  |
EEL1032 | Toshihiro Itoh |
C104H187O24P | 1852.557 | |
core lipid (Ref. 0126) |
|||||||||||||||||||||
| 281 |  |
EEL1033 | Toshihiro Itoh |
C98H190O19S | 1704.612 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 282 |  |
EEL1034 | Toshihiro Itoh |
C98H188O19S | 1702.596 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 283 |  |
EEL1035 | Toshihiro Itoh |
C98H186O19S | 1700.580 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 284 |  |
EEL1036 | Toshihiro Itoh |
C98H184O19S | 1698.564 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 285 |  |
EEL1037 | Toshihiro Itoh |
C98H182O19S | 1696.548 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 286 |  |
EEL1038 | Toshihiro Itoh |
C98H180O19S | 1694.532 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 287 |  |
EEL1039 | Toshihiro Itoh |
C98H178O19S | 1692.517 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 288 |  |
EEL1040 | Toshihiro Itoh |
C98H176O19S | 1690.501 | |
core lipid(Ref. 0126) |
|||||||||||||||||||||
| 289 |  |
EEL1041 | Toshihiro Itoh |
GL-1(Ref. 0145) |
C92H180O11 | 1462.407 | |
molecular rotation +24 (20 C, in chloroform) |
103.6ppm indicates a b-glucosidic linkage |
|||||||||||||||||||
| 290 |  |
EEL1042 | Toshihiro Itoh |
Gen-CAOH/GL-3(Ref. 0145) |
C98H190O16 | 1624.548 | |
4000-800 cm-1(Ref. 0086) |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 291 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL1043 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H200O21 | 1786.688 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 292 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL1044 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H198O21 | 1784.672 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 293 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL1045 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H198O21 | 1784.672 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 294 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL1046 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H196O21 | 1782.656 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 295 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL1047 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H194O21 | 1780.641 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 296 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL1048 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H191O19P | 1704.528 | |
||||||||||||||||||||
| 297 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL1049 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H189O19P | 1702.512 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 298 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL1050 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H189O19P | 1702.512 | |
||||||||||||||||||||
| 299 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL1051 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H187O19P | 1700.496 | |
||||||||||||||||||||
| 300 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL1052 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H185O19P | 1698.480 | |
||||||||||||||||||||
| 301 |  |
1-O-decylglycerol(Ref. 0040) |
EEL2001 | Keizo Waku |
10:0-Gro monoether |
C13H28O3 | 232.360 | 38.5 C |
TLC, THF-H2O (1:1) Rf 0.86 |
|||||||||||||||||||
| 302 |  |
1-O-dodecylglycerol(Ref. 0040) |
EEL2002 | Keizo Waku |
12:0-Gro monoether |
C15H32O3 | 260.413 | 49.5 C |
TLC, THF-H2O (1:1) Rf 0.70 |
|||||||||||||||||||
| 303 |  |
1-O-tetradecylglycerol(Ref. 0040) |
EEL2003 | Keizo Waku |
14:0-Gro monoether |
C17H36O3 | 288.466 | 58.5 C |
TLC, THF-H2O (1:1) Rf 0.55 |
|||||||||||||||||||
| 304 |  |
1-O-(cis,cis-9,12-octadecadienyl)glycerol(Ref. 0040) |
EEL2005 | Keizo Waku |
18:2-Gro monoether |
C21H40O3 | 340.541 | 8 C |
TLC, THF-H2O (1:1) Rf 0.49 |
|||||||||||||||||||
| 305 |  |
1-O-(cis,cis,cis-9,12,15-octadecatrienyl)glycerol(Ref. 0040) |
EEL2006 | Keizo Waku |
18:3-Gro monoether |
C21H38O3 | 338.525 | 13 C |
TLC, THF-H2O (1:1) Rf 0.58 |
|||||||||||||||||||
| 306 |  |
1,2-dihexadecylglycerol/dipalmitylglycerol |
1,2-di-O-hexadecyl-sn-glycerol(Ref. 0041) |
EEL2007 | Keizo Waku |
di-16:0-Gro diether |
C35H72O3 | 540.944 | synthesized by alkylation of L-a-O-benzyl glycerol with hexadecyl bromide and potassium hydroxide in boiling benzene, followed by removal of the benzyl group by hydrogenolysis with palladium catalyst. |
48.5-49.5 C |
[a]D = -7.5 , [M]D = -41 |
synthetic compound |
synthesized by alkylation of L-a-O-benzyl glycerol with hexadecyl bromide and potassium hydroxide in boiling benzene, followed by removal of the benzyl group by hydrogenolysis with palladium catalyst. |
|||||||||||||||
| 307 |  |
1,2-di-O-octadecylglycerol (Ref. 0041) |
EEL2008 | Keizo Waku |
di-18:0-Gro diether |
C39H80O3 | 597.051 | synthesized by alkylation of L-a-O-benzyl glycerol with octadecyl bromide and potassium hydroxide in boiling benzene, followed by removal of the benzyl group by hydrogenolysis with palladium catalyst. |
53.5-54.5 C |
[a]D = -6.9 , [M]D = -41 |
synthetic compound |
synthesized by alkylation of L-a-O-benzyl glycerol with octadecyl bromide and potassium hydroxide in boiling benzene, followed by removal of the benzyl group by hydrogenolysis with palladium catalyst. |
||||||||||||||||
| 308 |  |
1-O-octadecyl-2-O-(cis-9-octadecenyl)glycerol(Ref. 0043) |
EEL2009 | Keizo Waku |
18:0, 18:1-Gro diether |
C39H78O3 | 595.035 | 23-24 C |
||||||||||||||||||||
| 309 |  |
1,2,3-tri-O-octyl-sn-glycerol(Ref. 0044) |
EEL2010 | Keizo Waku |
tri-8:0-Gro triether |
C27H56O3 | 428.732 | |||||||||||||||||||||
| 310 |  |
EEL2011 | Keizo Waku |
12:0, di-10:0-Gro triether |
C35H72O3 | 540.944 | -5 C |
|||||||||||||||||||||
| 311 |  |
1,2,3-tri-O-hexadecyl-sn-glycerol(Ref. 0043) |
EEL2012 | Keizo Waku |
tri-16:0-Gro triether |
C51H104O3 | 765.370 | 47-48 C |
||||||||||||||||||||
| 312 |  |
1,2,3-tri-O-octadecyl-sn-glycerol(Ref. 0043) |
EEL2013 | Keizo Waku |
tri-18:0-Gro triether |
C57H116O3 | 849.529 | 57.5-58 C |
||||||||||||||||||||
| 313 |  |
1,2,3-tri-O-(cis-9-octadecenyl)-sn-glycerol(Ref. 0043) |
EEL2014 | Keizo Waku |
tri-18:1-Gro triether |
C57H110O3 | 843.482 | -11 C |
||||||||||||||||||||
| 314 |  |
2-O-cis-9'-octadecenylglycerol(Ref. 0047) |
EEL2015 | Keizo Waku |
18:1-Gro monoether |
C21H42O3 | 342.556 | GC-MS spectra C4-C7 monounsaturations at m/e 55,69,83,97 |
||||||||||||||||||||
| 315 |  |
1-palmitylglycerophosphate |
1-O-hexadecyl-sn-glycerol-3-phosphate(Ref. 0048) |
EEL2016 | Keizo Waku |
C16:0-GP/1Hx-GPA |
C19H41O6P | 396.499 | Prepared by hydrolysis of 1-O-HEXADECYL-GPC with phospholipase D |
synthetic product |
Prepared by hydrolysis of 1-O-HEXADECYL-GPC with phospholipase D |
|||||||||||||||||
| 316 |  |
Lyso PAF |
1-O-hexadecyl-sn-glycerophosphocholine(Ref. 0048) |
EEL2017 | Keizo Waku |
C16:0-GPC/1Hx-GPC |
C24H52O6PN | 481.647 | prepared by hydrolysis of 1(3)Hx-2Ac-GPC (racemic compound) with phospholipase A2 |
known as the PAF precursor |
prepared by hydrolysis of 1(3)Hx-2Ac-GPC (racemic compound) with phospholipase A2 |
|||||||||||||||||
| 317 |  |
1,2-di-O-cis-9'-octadecenyl-sn-glycero-3-phosphocholine(Ref. 0049) |
EEL2018 | Keizo Waku |
C44H88O6PN | 758.146 | 214-216 C |
[a]D = +1.4 (34mg/ml CHCl3:MeOH 1:1) |
||||||||||||||||||||
| 318 |  |
1-O-cis-9'-octadecenyl-3-O-octadecanoyl-sn-glycero-2-phosphoethanolamine(Ref. 0049) |
EEL2019 | Keizo Waku |
C41H84O6PN | 718.083 | |
192 C |
[a]  =-3.5 (28mg/ml CHCl3:MeOH 1:1) |
|||||||||||||||||||
| 319 |  |
1-O-cis-9'-octadecenyl-3-O-octadecanoyl-sn-glycero-2-phosphcholine(Ref. 0049) |
EEL2020 | Keizo Waku |
C44H90O6PN | 760.162 | |
225-226 C |
[a] =-3.8 |
cis double bond(300cm-1), -CH3,-CH2(2920,2850,1460,1370cm-1), ester C=O(1730cm-1), ether -C-O-C(1110cm-1 as a shoulder), P-O-C(950cm-1),P-O(-)(1070cm-1)P=O(1230cm-1), -OH(H2O)(3330cm-1) |
||||||||||||||||||
| 320 |  |
1-undecylglycerol(racemic compound)(Ref. 0050) |
EEL2021 | Keizo Waku |
C11:0-Gro monoether |
C14H30O3 | 246.386 | 37 C (Ref. 0050) |
CST(critical solution temperature with nitromethane) 61.5 C(Ref. 0050) |
synthetic product (racemic compound) |
||||||||||||||||||
| 321 |  |
1-tridecylglycerol(racemic compound)(Ref. 0050) |
EEL2022 | Keizo Waku |
C13:0-Gro monoether |
C16H34O3 | 274.439 | 47.5 C (Ref. 0050) |
CST=70.5 C(Ref. 0050) |
synthetic product (racemic compound) |
||||||||||||||||||
| 322 |  |
1-pentadecylglycerol(racemic compound)(Ref. 0050) |
EEL2023 | Keizo Waku |
C15:0-Gro monoether |
C18H38O3 | 302.493 | 58 C(Ref. 0050) |
CST=77.5 C(Ref. 0050) |
synthetic product (racemic compound) |
||||||||||||||||||
| 323 |  |
1-anteiso pentadecylglycerol |
1-(12'-methyltetradecyl)glycerol(racemic compound)(Ref. 0051) |
EEL2024 | Keizo Waku |
anteisoC15:0-Gro monoether |
C18H38O3 | 302.493 | 43-44.5 C |
synthetic product |
||||||||||||||||||
| 324 |  |
1-heptadecylglycerol(racemic compound)(Ref. 0050) |
EEL2025 | Keizo Waku |
C17:0-Gro monoether |
C20H42O3 | 330.546 | 64.5 C(Ref. 0050) |
CST = 84 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 325 |  |
1-anteiso heptadecylglycerol |
1-(14'-methylhexadecyl)glycerol(racemic compound)(Ref. 0051) |
EEL2026 | Keizo Waku |
anteisoC17:0-Gro monoether |
C20H42O3 | 330.546 | 48.5-50 C |
synthetic product |
||||||||||||||||||
| 326 |  |
1-nonadecylglycerol(racemic compound)(Ref. 0050) |
EEL2027 | Keizo Waku |
C19:0-Gro monoether |
C22H46O3 | 358.599 | 71.5 C(Ref. 0050) |
CST = 90.5 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 327 |  |
1-icosylglycerol(racemic compound)(Ref. 0040) |
EEL2028 | Keizo Waku |
C20:0-Gro monoether |
C23H48O3 | 372.625 | 76.5-77 C |
synthetic product |
|||||||||||||||||||
| 328 |  |
3-O-phytanyl-sn-glycerol/3-O-(3'R,7'R,11'R,15'-tetramethylhexadecyl)-sn-glycerol(Ref. 0052) |
EEL2029 | Keizo Waku |
C20:0-Gro monoether/phytanyl-Gro monoether |
C23H48O3 | 372.625 | 2.0 g/dl IN CHCl3 |
IR spectra |
synthetic product , Halobacterium cutirubrum |
||||||||||||||||||
| 329 |  |
1-(cis-9'-hexadecenyl)glycerol(racemic compound)(Ref. 0040) |
EEL2030 | Keizo Waku |
C16:0-Gro monoether |
C19H38O3 | 314.503 | 12.5 C |
CST = 68 C |
synthetic product (racemic compound) |
||||||||||||||||||
| 330 |  |
3-(trans-9'-octadecenyl)-sn-glycerol(Ref. 0040) |
EEL2031 | Keizo Waku |
C18:1-Gro monoether |
C21H42O3 | 342.556 | 49 C (Ref. 0040) |
||||||||||||||||||||
| 331 |  |
1-heneicosylglycerol(racemic compound)(Ref. 0040) |
EEL2032 | Keizo Waku |
C21:0-Gro monoether |
C24H50O3 | 386.652 | 12.5 C |
CST = 68 C |
synthetic product |
||||||||||||||||||
| 332 |  |
1,2-DIOCTYLGLYCEROL |
1,2-di-octyloxy-3-propanol(racemic compound)(Ref. 0044)/1,2-di-O-octylglycerol |
EEL2033 | Keizo Waku |
di-C8:0-Gro diether |
C19H40O3 | 316.519 | 150-155 C/0.2mmHg (Ref. 0044) |
synthetic product |
||||||||||||||||||
| 333 |  |
1,2-didodecylglycerol |
1,2-di-dodecyloxy-3-propanol(racemic compound)(Ref. 0044)/1,2-di-O-dodecylglycerol |
EEL2034 | Keizo Waku |
di-C12:0-Gro diether |
C27H56O3 | 428.732 | 38 C(Ref. 0044) |
synthetic product |
||||||||||||||||||
| 334 |  |
1-dodecyl-2-tetradecylglycerol/1-lauryl-2-myristylglycerol |
1-dodecyloxy-2-tetradecyloxy-3-propanol(racemic compound) (Ref. 0050)/1-O-dodecyl-2-O-tetradecylglycerol |
EEL2035 | Keizo Waku |
C12:0-C14:0-Gro diether |
C29H60O3 | 456.785 | 42-43 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 335 |  |
1-tetradecyl-2-dodecylglycerol/1-myristyl-2-laurylglycerol |
1-tetradecyloxy-2-dodecyloxy-3-propanol(racemic compound)(Ref. 0050)/1-O-tetradecyl-2-O-dodecylglycerol |
EEL2036 | Keizo Waku |
C14:0-C12:0-Gro diether |
C29H60O3 | 456.785 | 42 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 336 |  |
1,2-ditetradecylglycerol/1,2-myristylglycerol |
1,2-di-tetradecyloxy-3-propanol(racemic compound) (Ref. 0050)/1,2-di-O-tetradecylglycerol |
EEL2037 | Keizo Waku |
di-C14:0-Gro diether |
C31H64O3 | 484.838 | 51-52 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 337 |  |
1-hexadecyl-2-dodecylglycerol/1-palmityl-2-laurylglycerol |
1-hexadecyloxy-2-dodecyl-3-propanol(racemic compound)(Ref. 0050)/1-O-hexadecyl-2-O-dodecylglycerol |
EEL2038 | Keizo Waku |
C16:0-C12:0-Gro diether |
C31H64O3 | 484.838 | 43-44 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 338 |  |
1-dodecyl-2-octadecylglycerol/1-lauryl-2-stearylglycerol |
1-dodecyloxy-2-octadecyloxy-3-propanol(racemic compound)(Ref. 0050)/1-O-dodecyl-2-O-octadecylglycerol |
EEL2039 | Keizo Waku |
C12:0-C18:0-Gro diether |
C33H68O3 | 512.891 | 49-50 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 339 |  |
1-hexadecyl-2-tetradecylglycerol/1-palmityl-2-myristylglycerol |
1-hexadecyloxy-2-tetradecyloxy-3-propanol(racemic compound)(Ref. 0050)/1-O-hexadecyl-2-O-tetradecylglycerol |
EEL2040 | Keizo Waku |
C16:0-C14:0-Gro diether |
C33H68O3 | 512.891 | 54 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 340 |  |
1-tetradecyl-2-octadecylglycerol/1-myristyl-2-stearylglycerol |
1-tetradecyloxy-2-octadecyloxy-3-propanol(racemic compound)(Ref. 0050)/1-O-tetradecyl-2-O-octadecylglycerol |
EEL2041 | Keizo Waku |
C14:0-C18:0-Gro diether |
C35H72O3 | 540.944 | 55 C(Ref. 0050) |
synthetic product |
||||||||||||||||||
| 341 |  |
1-octadecyl-2-dodecylglycerol/1-stearyl-2-laurylglycerol |
1-octadecyloxy-2-dodecyloxy-3-propanol(racemic compound)(Ref. 0043)/1-O-octadecyl-2-O-dodecylglycerol |
EEL2042 | Keizo Waku |
C18:0-C12:0-Gro diether |
C33H68O3 | 512.891 | 41.5-42 C(Ref. 0043) |
CST = 123 C |
C-O frequency at 1120cm-1, C-O stretching absorption near 1048cm-1(Ref. 0043) |
synthetic product |
||||||||||||||||
| 342 |  |
1-octadecyl-2-tetradecylglycerol/1-stearyl-2-myristylglycerol |
1-Octadecyloxy-2-tetradecyloxy-3-propanol(racemic compound)(Ref. 0043)/1-O-octadecyl-2-O-tetradecylglycerol |
EEL2043 | Keizo Waku |
C18:0-C14:0-Gro diether |
C35H72O3 | 540.944 | 52.0-52.5 C(Ref. 0043) |
C-O frequency at 1120cm-1, C-O stretching at 1048cm-1(Ref. 0043) |
synthetic product |
|||||||||||||||||
| 343 |  |
1-hexadecyl-2-octadecylglycerol/1-palmityl-2-stearylglycerol |
1-hexadecyloxy-2-octadecyloxy-3-propanol(racemic compound) (Ref. 0043)/1-O-hexadecyl-2-O-octadecylglycerol |
EEL2044 | Keizo Waku |
C16:0-C18:0-Gro diether |
C37H76O3 | 568.998 | 61.5-62 C(Ref. 0043) |
C-O frequency at 1120cm-1, C-O stretching at 1048cm-1(Ref. 0043) |
||||||||||||||||||
| 344 |  |
1-octadecyl-2-hexadecylglycerol/1-stearyl-2-palmitylglycerol |
1-octadecyloxy-2-hexadecyloxy-3-propanol(racemic compound)(Ref. 0043)/1-O-octadecyl-2-O-hexadecylglycerol |
EEL2045 | Keizo Waku |
C18:0-C16:0-Gro diether |
C37H76O3 | 568.998 | 58.5-59 C |
CST = 139.5 C |
C-O frequency at 1120cm-1, C-O stretching at 1048cm-1(Ref. 0043) |
synthetic product |
||||||||||||||||
| 345 |  |
1-octadecyl-2-(5',8',11',14'-icosatetraenyl)glycerol/1-stearyl-2-(5',8',11',14'-icosatetraenyl)glycerol |
1-octadecyloxy-2-(5',8',11',14'-icosatetraenoxy)-3-propanol(racemic compound)(Ref. 0043)/1-O-octadecyl-2-O-(5',8',11',14'-icosatetraenyl)glycerol |
EEL2046 | Keizo Waku |
C18:0-C20:4-Gro diether |
C39H80O3 | 597.051 | 66.5-67 C(Ref. 0043) |
C-O frequency at 1120cm-1, C-O stretching at 1048cm-1, cis-C-H stretching at 2985cm-1 |
synthetic product |
|||||||||||||||||
| 346 |  |
1-octadecyl-2-(9'-octadecenyl)glycerol/1-stearyl-2-elaidylglycerol |
1-octadecyloxy-2-(9'-trans-octadecenyloxy-3-propanol(racemic compound)(Ref. 0043)/1-O-octadecyl-2-O-(9'-trans-octadecenyl)glycerol |
EEL2048 | Keizo Waku |
C18:0-C18:1-Gro diether |
C39H78O3 | 595.035 | 48-48.5 C(Ref. 0043) |
C-O frequency at1120cm-1, C-O stretching at1048cm-1(Ref. 0043) |
synthetic product |
|||||||||||||||||
| 347 |  |
2-cis-9'-octadecenyl-3-octadecyl-sn-glycerol(Ref. 0052) |
EEL2049 | Keizo Waku |
C18:1-C18:0-Gro diether |
C39H78O3 | 595.035 | OH:3420cm-1,CH2 and CH3:2910,284,1465,1380,720cm-1, ether C-O-C:1115cm-1, cis C=C:2980,1650,700cm-1 |
||||||||||||||||||||
| 348 |  |
1,2-di-cis-9'-octadecenyl-sn-glycerol(Ref. 0049) |
EEL2050 | Keizo Waku |
di-C18:1-Gro diether |
C39H76O3 | 593.019 | synthetic product |
||||||||||||||||||||
| 349 |  |
2-O-octadecyl-3-O-cis-9'-octadecenyl-sn-glycerol(Ref. 0050) |
EEL2051 | Keizo Waku |
C39H78O3 | 595.035 | 20 - 21 C(Ref. 0043) |
C-O stretching 1048cm-1, C-O frequency 1120cm-1 023); IR spectra (030); OH(3420cm-1), CH2 and CH3(2910, 2840, 1465, 720cm-1), C-O-C(1115cm-1), cis double bond (2980, 1650, 700cm-1) (Ref. 0052) |
synthetic product |
|||||||||||||||||||
| 350 |  |
2,3-di-O-cis-9'-octadecenyl-sn-glycerol(Ref. 0050) |
EEL2052 | Keizo Waku |
C39H76O3 | 593.019 | OH (3420cm-1), CH2 and CH3 (2910,2840,1465,1380,720cm-1), C-O-C(1115cm-1), cis double bond (2980,1650,700cm-1) (Ref. 0052) |
synthetic product |
||||||||||||||||||||
| 351 |  |
1,2,3-tridodecyloxypropane(Ref. 0044)/1,2,3-tridodecylglycerol |
EEL2053 | Keizo Waku |
C39H80O3 | 597.051 | synthetic product |
|||||||||||||||||||||
| 352 |  |
1-O-dodecyl-2,3-di-O-tetradecylglycerol(Ref. 0050) |
EEL2054 | Keizo Waku |
C43H88O3 | 653.157 | 17.5 - 18 C(Ref. 0050) |
synthetic product |
||||||||||||||||||||
| 353 |  |
1-hexadecyl-2,3-didodecylglycerol(Ref. 0054) |
EEL2055 | Keizo Waku |
C43H88O3 | 653.157 | 23 C(Ref. 0054) |
synthetic product |
||||||||||||||||||||
| 354 |  |
1-O-decyl-2,3-di-O-hexadecylglycerol(Ref. 0050) |
EEL2056 | Keizo Waku |
C47H96O3 | 709.263 | 36.5 - 37 C(Ref. 0050) |
synthetic product |
||||||||||||||||||||
| 355 |  |
1-O-dodecyl-2-O-hexadecyl-3-O-octadecylglycerol(Ref. 0043) |
EEL2057 | Keizo Waku |
C49H100O3 | 737.317 | 34 - 35 C(Ref. 0043) |
C-O frequency at 1120cm-1(Ref. 0043) |
synthetic product |
|||||||||||||||||||
| 356 |  |
1-O-dodecyl-2,3-dioctadecylglycerol(Ref. 0043) |
EEL2058 | Keizo Waku |
C51H104O3 | 765.370 | 43 - 44 C(Ref. 0043) |
C-O frequency at 1120cm-1 (Ref. 0043) |
synthetic product |
|||||||||||||||||||
| 357 |  |
1-O-tetradecyl-2-O-hexadecyl-3-O-octadecylglycerol(Ref. 0050) |
EEL2059 | Keizo Waku |
C51H104O3 | 765.370 | 43 C(Ref. 0050) |
synthetic product |
||||||||||||||||||||
| 358 |  |
1,2-di-O-octadecyl-3-O-cis-9-octadecenylglycerol(Ref. 0050) |
EEL2060 | Keizo Waku |
C57H114O3 | 847.513 | 23 - 25 C(Ref. 0050) |
synthetic product |
||||||||||||||||||||
| 359 |  |
1-O-octadecyl-2,3-di-O-cis-9-octadecenylglycerol(Ref. 0050) |
EEL2061 | Keizo Waku |
C57H112O3 | 845.497 | synthetic product |
|||||||||||||||||||||
| 360 |  |
3-O-tetradecylcholesterol(Ref. 0055) |
EEL2062 | Keizo Waku |
C29H50O | 414.707 | 50 C(Ref. 0055) |
synthetic product |
||||||||||||||||||||
| 361 |  |
3-O-hexadecylcholesterol(Ref. 0055) |
EEL2063 | Keizo Waku |
C31H54O | 442.760 | 57 C(Ref. 0055) |
synthetic product |
||||||||||||||||||||
| 362 |  |
3-O-(9-cis-octadecenyl)cholesterol(Ref. 0055) |
EEL2064 | Keizo Waku |
C33H52O | 464.765 | 35 C(Ref. 0055) |
synthetic product |
||||||||||||||||||||
| 363 |  |
ethyl-1-hexadecenylether(Ref. 0056) |
EEL2065 | Keizo Waku |
C18H36O | 268.478 | 123 - 128 C (0.01mmHg)(Ref. 0056) |
h  = 1.4480 (Ref. 0056) |
synthetic product |
|||||||||||||||||||
| 364 |  |
(rac)-1-(1'-ethoxyhexadecyloxy)-2,3-dipalmitoylglycerol(Ref. 0056) |
EEL2066 | Keizo Waku |
C53H104O6 | 837.389 | 56 - 57 C(Ref. 0056) |
synthetic product |
||||||||||||||||||||
| 365 |  |
(rac)-trans-1-(N-hexadec-1'-enyloxy)-2,3-dipalmitoylglycerol(Ref. 0056) |
EEL2067 | Keizo Waku |
C51H98O5 | 791.321 | 735cm-1weak absorption (Ref. 0056) |
synthetic product |
||||||||||||||||||||
| 366 |  |
(rac)-trans-1-(N-hexadec-1'-enyloxy)-2,3-dioleoylglycerol(Ref. 0056) |
EEL2068 | Keizo Waku |
C55H102O5 | 843.395 | 735cm-1 weak absorption (Ref. 0056) |
double at d=6.28ppm, (J=12.5cps), in acetylated compound (Ref. 0056) |
synthetic product |
|||||||||||||||||||
| 367 |  |
plasmenylcholine/choline plasmalogen |
(rac)-1-O-trans-hexadec-1'-enyl-2-O-oleoylglycerol-3-phosphocholine(Ref. 0056) |
EEL2069 | Keizo Waku |
C42H82O7PN | 744.077 | 229 - 231 C(Ref. 0056) |
IR spectrum (Ref. 0056) |
synthetic product |
||||||||||||||||||
| 368 |  |
(rac)-1-O-n-trans-hexadec-1'-enyl-2-O-oleoylglycerol(Ref. 0056) |
EEL2070 | Keizo Waku |
C37H66O3 | 558.918 | synthetic product |
|||||||||||||||||||||
| 369 |  |
1-O-(Z)-1'-alkenyl-2-oleoyl-sn-glycero-3-phosphoethanolamine(Ref. 0057) |
EEL2071 | Keizo Waku |
C39H76O7PN | 701.997 | synthetic product |
|||||||||||||||||||||
| 370 |  |
CHOLINE PLASMALOGEN/plasmenylcholine |
1-O-(Z)-1'-alkenyl-2-oleoyl-sn-glycero-3-phosphorylcholine(Ref. 0057) |
EEL2072 | Keizo Waku |
PlaC |
C42H82O7PN | 744.077 | 1H-NMR (90MHz,2CHCl3) a-enolether H+, -O-CH= 5.93ppm (as 1-alkenyl-2,3-diacyl-sn-glycerol) (Ref. 0057) |
synthetic product |
||||||||||||||||||
| 371 |  |
aldehydogenic ethanolamine phospholipid(Ref. 0058)/glycerol acetal of plasmenylethanolamine |
EEL2073 | Keizo Waku |
glycerol acetal of plaE |
Clostridium butyricum (Ref. 0039) |
||||||||||||||||||||||
| 372 |  |
N-acetyl-1-hexadecyl-2-acetyl-glycerophosphoethanolamine(Ref. 0059) |
EEL2074 | Keizo Waku |
C25H49O8PN | 522.632 | prepared by acetylation of 1-hexadecylglycerophosphoethanolamine with acetic anhydride |
acylester linkage:1720cm-1 strong absorption (Ref. 0059) |
synthetic product(Ref. 0059) |
prepared by acetylation of 1-HEXADECYL-GLYCEROPHOSPHOETHANOLAMINE with acetic anhydride |
||||||||||||||||||
| 373 |  |
N-hexadecanoyl-1-hexadecyl-2-hexadecanoyl-glycerophosphoethanolamine(Ref. 0059) |
EEL2075 | Keizo Waku |
C53H105O8PN | 915.377 | prepared by acylation of 1-hexadecyl glycerophosphoethanolamine with hexadecanoylchloride |
acylester linkage:1720cm-1 strong absorption (Ref. 0059) |
synthetic product(Ref. 0059) |
prepared by acylation of 1-HEXADECYL GLYCEROPHOSPHO ETHANOLAMINE with HEXADECANOYLCHLORIDE |
||||||||||||||||||
| 374 |  |
N-hexadecanoyl-1-octadecyl-2-octadecenoyl-glycerophosphoethanolamine(Ref. 0059) |
EEL2076 | Keizo Waku |
C57H111O8PN | 969.467 | acylester linkage:1720cm-1 strong absorption (Ref. 0059) |
bovine erythrocyte(Ref. 0059) |
||||||||||||||||||||
| 375 |  |
EEL2077 | Keizo Waku |
C31H58O6PN | 571.769 | synthetic product (Ref. 0060) |
||||||||||||||||||||||
| 376 |  |
EEL2078 | Keizo Waku |
C31H58O6PN | 571.769 | synthetic product(Ref. 0060) |
||||||||||||||||||||||
| 377 |  |
EEL2079 | Keizo Waku |
C24H52O5PN | 465.647 | synthetic product(Ref. 0062) |
||||||||||||||||||||||
| 378 |  |
1-O-tetradecylpropane-1,3-diol-3-phosphocholine(Ref. 0061) |
EEL2080 | Keizo Waku |
C22H48O5PN | 437.594 | synthetic product(Ref. 0061) |
|||||||||||||||||||||
| 379 |  |
1-O-dodecylpropane-1,3-diol-3-phosphocholine(Ref. 0061) |
EEL2081 | Keizo Waku |
C20H44O5PN | 409.541 | synthetic product (Ref. 0061) |
|||||||||||||||||||||
| 380 |  |
1,2-di-O-octylglycero-3-phosphocholine(Ref. 0061) |
EEL2082 | Keizo Waku |
C24H52O6PN | 481.647 | synthetic product(Ref. 0061) |
|||||||||||||||||||||
| 381 |  |
1,3-di-O-octylglycero-2-phosphocholine(Ref. 0061) |
EEL2083 | Keizo Waku |
C24H52O6PN | 481.647 | synthetic product (Ref. 0061) |
|||||||||||||||||||||
| 382 |  |
1-octadecanoyl-2-O-methylglycero-3-phosphocholine(Ref. 0063) |
EEL2084 | Keizo Waku |
C27H56O7PN | 537.710 | synthetic product (racemic compound) (Ref. 0063) |
|||||||||||||||||||||
| 383 |  |
1-nanonoyl-2-O-methylglycero-3-phosphocholine(Ref. 0063) |
EEL2085 | Keizo Waku |
C18H38O7PN | 411.471 | synthetic product (racemic compound) (Ref. 0063) |
|||||||||||||||||||||
| 384 |  |
2-hexadecyloxyethanol(Ref. 0064) |
EEL2086 | Keizo Waku |
C18H38O2 | 286.493 | 42.5-43 C(Ref. 0064) |
synthetic product(Ref. 0064) |
||||||||||||||||||||
| 385 |  |
cis,cis-9,12-octadecadienyloxyethanol(Ref. 0064) |
EEL2087 | Keizo Waku |
C20H38O2 | 310.515 | -18 C(Ref. 0064) |
synthetic product (Ref. 0064) |
||||||||||||||||||||
| 386 |  |
1,2-di-hexadecyloxyethane(Ref. 0064) |
EEL2088 | Keizo Waku |
C34H70O2 | 510.918 | 53.5-54 C(Ref. 0064) |
synthetic product (Ref. 0064) |
||||||||||||||||||||
| 387 |  |
1,2-di-cis-9-octadecenyloxyethane(Ref. 0064) |
EEL2089 | Keizo Waku |
C38H74O2 | 562.993 | 14 C(Ref. 0064) |
synthetic product(Ref. 0064) |
||||||||||||||||||||
| 388 |  |
1-hexadecanoyl-2-hexadecyloxyethanol(Ref. 0064) |
EEL2090 | Keizo Waku |
C34H68O3 | 524.902 | 54-55 C(Ref. 0064) |
synthetic product (Ref. 0064) |
||||||||||||||||||||
| 389 |  |
1-cis-9-octadecenoyl-2-cis-9-octadecenyloxyethanol(Ref. 0064) |
EEL2091 | Keizo Waku |
C38H72O3 | 576.976 | synthetic product (Ref. 0064) |
|||||||||||||||||||||
| 390 |  |
1-O-dodecyl-2-O-methylglycero-3-phosphocholine(Ref. 0062) |
EEL2092 | Keizo Waku |
C21H46O6PN | 439.567 | synthetic product (Ref. 0062) |
|||||||||||||||||||||
| 391 |  |
1-O-octadecyl-2-O-methylglycero-3-phosphocholine(Ref. 0062) |
EEL2093 | Keizo Waku |
C27H58O6PN | 523.726 | synthetic product (Ref. 0062) |
|||||||||||||||||||||
| 392 |  |
EEL2094 | Keizo Waku |
C53H100O22S | 1121.414 | S=O, strong absorption at 1240 cm-1; C-O-S, 820 cm-1(Ref. 0065) |
||||||||||||||||||||||
| 393 |  |
1-palmitoyl-2-O-hexadecyl-3-(6-O-surfoglcosyl(a1-6)glucosyl(a1-6)glucosyl)glycerol(Ref. 0065) |
EEL2095 | Keizo Waku |
C53H100O22S | 1121.414 | S=O, strong absorption at 1240 cm-1; C-O-S, 820 cm-1(Ref. 0065) |
human digestive fluid(Ref. 0065) |
||||||||||||||||||||
| 394 |  |
1-O-hexadecyl-2-docosanoyl-3-a-D-glucosyl-glycerol(Ref. 0066) |
EEL2096 | Keizo Waku |
C47H92O9 | 801.228 | HUMAN SALIVA(Ref. 0066) |
|||||||||||||||||||||
| 395 |  |
1-O-hexadecyl-2-O-docosanoyl-3-(glucosyl(a1-6)glucosyl)glycerol(Ref. 0066) |
EEL2097 | Keizo Waku |
C53H102O14 | 963.369 | human saliva(Ref. 0066) |
|||||||||||||||||||||
| 396 |  |
1-O-hexadecyl-2-docosanoyl-3-(glucosyl(6-1a)glucosyl(6-1a)glucosyl)glycerol(Ref. 0066) |
EEL2098 | Keizo Waku |
C59H112O19 | 1125.509 | human saliva(Ref. 0066) |
|||||||||||||||||||||
| 397 |  |
2-dodecyloxethanol(Ref. 0062) |
EEL2099 | Keizo Waku |
C14H30O2 | 230.387 | 16-17 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 398 |  |
2-tetradecyloxyethanol(Ref. 0062) |
EEL2100 | Keizo Waku |
C16H34O2 | 258.440 | 30.5-31.5 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 399 |  |
2-octadecyloxyethanol(Ref. 0062) |
EEL2101 | Keizo Waku |
C20H42O2 | 314.546 | 51.5-52 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 400 |  |
2-eicosyloxyethanol(Ref. 0062) |
EEL2102 | Keizo Waku |
C22H46O2 | 342.599 | 58-58.5 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 401 |  |
2-cis-9-octadecenyloxyethanol(Ref. 0062) |
EEL2103 | Keizo Waku |
C20H40O2 | 312.530 | 1-2 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 402 |  |
2-trans-9-octadecenyloxyethanol(Ref. 0062) |
EEL2104 | Keizo Waku |
C20H40O2 | 312.530 | 28 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 403 |  |
1-hexadecyloxy-2-octadecyloxyethane(Ref. 0062) |
EEL2105 | Keizo Waku |
C36H74O2 | 538.972 | 53-54 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 404 |  |
1,2-di-octadecyloxyethane(Ref. 0062) |
EEL2106 | Keizo Waku |
C38H78O2 | 567.025 | 60.5-61.5 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 405 |  |
1-octadecyloxy-2-cis-9-octadecenyloxyethane(Ref. 0062) |
EEL2107 | Keizo Waku |
C38H76O2 | 565.009 | 32-32.5 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 406 |  |
1-hexadecanoyl-2-tetradecyloxyethanol(Ref. 0062) |
EEL2108 | Keizo Waku |
C32H64O3 | 496.849 | 47-47.5 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 407 |  |
1-octadecanoyl-2-hexadecyloxyethanol(Ref. 0062) |
EEL2109 | Keizo Waku |
C36H72O3 | 552.955 | 50.5-51.5 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 408 |  |
1-hexadecanoyl-2-octadecyloxyethanol(Ref. 0062) |
EEL2110 | Keizo Waku |
C36H72O3 | 552.955 | 52.5-54 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 409 |  |
1-octadecanoyl-2-octadecyloxyethanol(Ref. 0062) |
EEL2111 | Keizo Waku |
C38H76O3 | 581.008 | 61.5-62 C(Ref. 0062) |
synthetic product (Ref. 0062) |
||||||||||||||||||||
| 410 |  |
1-cis-9-octadecenoyl-2-octadecyloxyethanol(Ref. 0062) |
EEL2112 | Keizo Waku |
C38H74O3 | 578.992 | 26-27 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 411 |  |
1-cis-octadecenoyl-2-cis-9-octadecenyloxyethanol(Ref. 0062) |
EEL2113 | Keizo Waku |
C38H74O3 | 578.992 | 30-30.5 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 412 |  |
1-octadecyloxy-3-trityloxypropane(Ref. 0062) |
EEL2114 | Keizo Waku |
C40H58O2 | 570.887 | 50-51 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 413 |  |
1-cis-9-octadecenyloxy-3-trityloxypropane(Ref. 0062) |
EEL2115 | Keizo Waku |
C40H56O2 | 568.871 | synthetic product(Ref. 0062) |
|||||||||||||||||||||
| 414 |  |
3-octadecyloxypropanol(Ref. 0062)/1-O-octadecylpropane-1,3-diol |
EEL2116 | Keizo Waku |
C21H44O2 | 328.573 | 48-49 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 415 |  |
3-cis-octadecenyloxypropanol(Ref. 0062)/3-cis-O-octadecylpropane-1,3-diol |
EEL2117 | Keizo Waku |
C21H42O2 | 326.557 | 5-6 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 416 |  |
1,3-dioctadecyloxypropane(Ref. 0062) |
EEL2118 | Keizo Waku |
C39H80O2 | 581.051 | 57-58 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 417 |  |
1-octadecyloxy-3-cis-9-octadecenyloxypropane(Ref. 0062) |
EEL2119 | Keizo Waku |
C39H80O2 | 581.051 | 30-31 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 418 |  |
1-O-octadecanoyl-3-octadecyloxypropanol(Ref. 0062)/1-O-octadecanoyl-3-O-octadecylpropane-1,3-diol |
EEL2120 | Keizo Waku |
C39H78O3 | 595.035 | 63 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 419 |  |
1-O-cis-9-octadecenoyl-3-octadecyloxypropanol(Ref. 0062)/1-O-cis-9-octadecenoyl-3-O-octadecylpropane-1,3-diol |
EEL2121 | Keizo Waku |
C39H76O3 | 593.019 | 27-28.5 C(Ref. 0062) |
synthetic product(Ref. 0062) |
||||||||||||||||||||
| 420 |  |
1,2-dioctadecanoyl-3-decylglycerol/1,2-distearoyl-3-decylglycerol |
D,L-1,2-dioctadecanoyl-3-decyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-decylglycerol |
EEL2122 | Keizo Waku |
C49H96O5 | 765.284 | 49-49.5 C (Ref. 0042) |
CST 146 C(CRITICAL SOLUTION TEMPERATURE WITH NITROMETHANE)(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 421 |  |
1,2-dioctadecanoyl-3-undecylglycerol/1,2-distearoyl-3-undecylglycerol |
D,L-1,2-dioctadecanoyl-3-undecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-undecylglycerol |
EEL2123 | Keizo Waku |
C50H98O5 | 779.310 | 47.5-49 C(Ref. 0042) |
CST 149 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 422 |  |
1,2-dioctadecanoyl-3-dodecylglycerol/1,2-distearoyl-3-laurylglycerol |
D,L-1,2-dioctadecanoyl-3-dodecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-dodecylglycerol |
EEL2124 | Keizo Waku |
C51H100O5 | 793.337 | 49.5-50.5 C(Ref. 0042) |
CST 152 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 423 |  |
1,2-dioctadecanoyl-3-tridecylglycerol/1,2-distearoyl-3-tridecylglycerol |
D,L-1,2-dioctadecanoyl-3-tridecyloxypropan-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-tridecylglycerol |
EEL2125 | Keizo Waku |
C52H102O5 | 807.363 | 49.5-50.5 C(Ref. 0042) |
CST 155 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 424 |  |
1,2-dioctadecanoyl-3-tetradecylglycerol/1,2-distearoyl-3-myristylglycerol |
D,L-1,2-dioctadecanoyl-3-tetradecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-tetradecylglycerol |
EEL2126 | Keizo Waku |
C53H104O5 | 821.390 | 59-59.5 C(Ref. 0042) |
CST 157.5 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 425 |  |
1,2-dioctadecanoyl-3-pentadecylglycerol/1,2-distearoyl-3-pentadecylglycerol |
D,L-1,2-dioctadecanoyl-3-pentadecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-pentadecylglycerol |
EEL2127 | Keizo Waku |
C54H106O5 | 835.416 | 55.5-56.5 C<0042>> |
CST 160 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 426 |  |
1,2-dioctadecanoyl-3-hexadecylglycerol/1,2-distearoyl-3-palmitylglycerol |
D,L-1,2-dioctadecanoyl-3-hexadecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-hexadecylglycerol |
EEL2128 | Keizo Waku |
C55H108O5 | 849.443 | 61-61.5 C(Ref. 0042) |
CST 162 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product |
|||||||||||||||||
| 427 |  |
1,2-dioctadecanoyl-3-heptadecylglycerol/1,2-distearoyl-3-heptadecylglycerol |
D,L-1,2-dioctadecanoyl-3-heptadecyloxypropane-1,2-diol(Ref. 0042)/1,2-O-dioctadecanoyl-3-heptadecylglycerol |
EEL2129 | Keizo Waku |
C56H110O5 | 863.470 | 60.5-61.5 C(Ref. 0042) |
CST=164 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product |
|||||||||||||||||
| 428 |  |
1,2-didodecanoyl-3-octadecylglycerol/1,2-dilauroyl-3-stearylglycerol |
D,L-1,2-didodecanoyl-3-octadecyloxypropane-1,2-diol(Ref. 0042)/1,2-O-didodecanoyl-3-O-octadecylglycerol |
EEL2130 | Keizo Waku |
C45H88O5 | 709.177 | 40-41 C(Ref. 0042) |
CST=135.5 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product |
|||||||||||||||||
| 429 |  |
1,2-ditetradecanoyl-3-octadecylglycerol/1,2-dimyristoyl-3-O-stearylglycerol |
D,L-1,2-ditetradecanoyl-3-octadecyloxypropane-1,2-diol(Ref. 0042)/1,2-O-ditetradecanoyl-3-O-octadecylglycerol |
EEL2131 | Keizo Waku |
C49H96O5 | 765.284 | 48-49 C(Ref. 0042) |
CST=146.5 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product |
|||||||||||||||||
| 430 |  |
1,2-dihexadecanoyl-3-octadecylglycerol/1,2-di-palmitoyl-3-stearylglycerol |
D,L-1,2-dihexadecanoyl-3-octadecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-hexadecanoyl-3-O-octadecylglycerol |
EEL2132 | Keizo Waku |
C53H104O5 | 821.390 | 53.5-54 C(Ref. 0042) |
CST=158 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product |
|||||||||||||||||
| 431 |  |
1,2-dioctadecanoyl-3-octadecylglycerol/1,2-disteroyl-3-stearylglycerol |
D,L-1,2-dioctadecanoyl-3-octadecyloxypropane-1,2-diol(Ref. 0042)/ 1,2-di-O-octadecanoyl-3-O-octadecylglycerol |
EEL2133 | Keizo Waku |
C57H112O5 | 877.496 | 61.5-62 C(Ref. 0042) |
CST=166.5 C<0042>> |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product |
|||||||||||||||||
| 432 |  |
1,2-di-(9'-cis-octadecenoyl)-3-octadecylglycerol/1,2-di-oleoyl-3-stearylglycerol |
D,L-1,2-DI-(9'-CIS-OCTADECENOYL)-3-OCTADECYLOXYPROPANE-1,2-DIOL(Ref. 0042)/ 1,2-di-O-(9'-cis-octadecenoyl)-3-O-octadecylglycerol |
EEL2134 | Keizo Waku |
C57H108O5 | 873.464 | -9 C(Ref. 0042) |
CST=151 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 433 |  |
1,2-diicosanoyl-3-octadecylglycerol/1,2-di-archidoyl-3-stearylglycerol |
D,L-1,2-diicosanoyl-3-octadecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-icosanoyl-3-O-octadecylglycerol |
EEL2135 | Keizo Waku |
C61H120O5 | 933.602 | 69-69.5 C(Ref. 0042) |
CST=175 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 434 |  |
1,2-dioctadecanoyl-3-(9'-cis-octadecyl)glycerol/1,2-distearoyl-3-O-oleylglycerol |
D,L-1,2-dioctadecanoyl-3-9'-cis-octadecenyloxypropane-1,2-diol(Ref. 0042)/ 1,2-di-O-octadecanoyl-3-O-(9'-cis-octadecyl)glycerol |
EEL2136 | Keizo Waku |
C57H110O5 | 875.480 | 31-32 C(Ref. 0042) |
CST=158.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 435 |  |
1,2-dioleoyl-3-oleylglycerol |
D,L-1,2-di-9'-cis-octadecenoyl-3-9'-cis-octadecenyloxypropane-1,2-diol(Ref. 0042)/ 1,2-di-O-(9'-octadecenoyl)-3-O-(9'-octadecyl)glycerol |
EEL2137 | Keizo Waku |
C57H106O5 | 871.449 | -20 C(Ref. 0042) |
CST=144 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 436 |  |
1,2-dioctadecanoyl-3-nonadecylglycerol/1,2-distearoyl-3-nonadecylglycerol |
1,2-dioctadecanoyl-3-nonadecyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-nonadecylglycerol |
EEL2138 | Keizo Waku |
C58H114O5 | 891.523 | 61-61.5 C(Ref. 0042) |
CST=168.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 437 |  |
1,2-dioctadecanoyl-3-icosanylglycerol/1,2-distearoyl-3-arachidylglycerol |
D,L-1,2-dioctadecanoyl-3-icosyloxypropane1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-icosanylglycerol |
EEL2139 | Keizo Waku |
C59H116O5 | 905.549 | 60-61 C(Ref. 0042) |
CST=170.5 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 438 |  |
1,2-dioctadecanoyl-3-heneicosylglycerol/1,2-distearoyl-3-heneicosylglycerol |
D,L-1,2-dioctadecanoyl-3-heneicosyloxypropane-1,2-diol(Ref. 0042)/1,2-di-O-octadecanoyl-3-O-heneicosylglycerol |
EEL2140 | Keizo Waku |
C60H118O5 | 919.576 | 61.5-62.5 C(Ref. 0042) |
CST=172.5 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 439 |  |
1-hexadecanoyl-2,3-dihexadecylglycerol/1-palmitoyl-2,3-dipalmitylglycerol |
D,L-1-hexadecanoyl-2,3-di-hexadecyloxypropanol(Ref. 0042)/1-O-hexadecanoyl-2,3-di-O-hexadecylglycerol |
EEL2141 | Keizo Waku |
C51H102O4 | 779.353 | 55-56 C(Ref. 0042) |
CST=168.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 440 |  |
1-octadecanoyl-2,3-dioctadecylglycerol/1-stearoyl-2,3-distearylglycerol |
D,L-1-octadecanoyl-2-octadecyloxy-3-hexadecyloxypropanol(Ref. 0042)/1-O-octadecanoyl-2,3-di-O-octadecylglycerol |
EEL2142 | Keizo Waku |
C55H110O4 | 835.460 | 55.5-56 C(Ref. 0042) |
CST=177 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 441 |  |
1-dodecanoyl-2-dodecyl-3-octadecylglycerol/1-lauroyl-2-lauryl-3-stearylglycerol |
D,L-1-dodecanoyl-2-dodecyloxy-3-octadecyloxypropanol(Ref. 0042)/1-O-dodecanoyl-2-O-dodecyl-3-O-octadecylglycerol |
EEL2143 | Keizo Waku |
C45H90O4 | 695.194 | 41-41.5 C(Ref. 0042) |
CST=153 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 442 |  |
1-octadecanoyl-2-dodecyl-3-octadecylglycerol/1-stearoyl-2-lauryl-3-stearylglycerol |
D,L-1-octadecanoyl-2-dodecyloxy-3-octadecyloxypropanol(Ref. 0042)/1-O-octadecanoyl-2-O-dodecyl-3-O-octadecylglycerol |
EEL2144 | Keizo Waku |
C51H102O4 | 779.353 | 42.5-43 C(Ref. 0042) |
CST=169 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 443 |  |
1-octadecanoyl-2-tetradecyl-3-octadecylglycerol/1-stearoyl-2-myristyl-3-stearylglycerol |
D,L-1-octadecanoyl-2-tetradecyloxy-3-octadecyloxypropanol(Ref. 0042)/1-O-octadecanoyl-2-O-tetradecyl-3-O-octadecylglycerol |
EEL2145 | Keizo Waku |
C53H106O4 | 807.406 | 46-47 C(Ref. 0042) |
CST=172.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 444 |  |
1-dodecanoyl-2-hexadecyl-3-octadecylglycerol/1-lauroyl-2-palmityl-3-stearylglycerol |
D,L-1-dodecanoyl-2-hexadecyloxy-3-octadecyloxypropanol(Ref. 0042)/1-O-dodecanoyl-2-O-hexadecyl-3-O-octadecylglycerol |
EEL2146 | Keizo Waku |
C49H98O4 | 751.300 | 39.5-40.5 C(Ref. 0042) |
CST=164 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 445 |  |
1-octadecanoyl-2-hexadecyl-3-octadecylglycerol/1-stearoyl-2-palmityl-3-stearylglycerol |
D,L-1-octadecanoyl-2-hexadecyloxy-3-octadecyloxypropanol(Ref. 0042)/1-O-octadecanoyl-2-O-hexadecyl-3-O-octadecylglycerol |
EEL2148 | Keizo Waku |
C55H110O4 | 835.460 | 55-55.5 C(Ref. 0042) |
CST=177 C (Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 446 |  |
1-dodecanoyl-2,3-dioctadecylglycerol/1-lauroyl-2,3-distearylglycerol |
D,L-1-dodecanoyl-2,3-dioctadecyloxypropanol(Ref. 0042)/1-O-dodecanoyl-2,3-di-O-octadecylglycerol |
EEL2149 | Keizo Waku |
C51H102O4 | 779.353 | 42.5-43 C(Ref. 0042) |
CST 170 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 447 |  |
1-octadecanoyl-2,3-dioctadecylglycerol/1-stearoyl-2,3-distearylglycerol |
D,L-1-octadecanoyl-2,3-dioctadecyloxypropanol(Ref. 0042)/1-O-octadecanoyl-2,3-di-O-octadecylglycerol |
EEL2150 | Keizo Waku |
C57H114O4 | 863.513 | 62.5-63 C(Ref. 0042) |
CST=181 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 448 |  |
1-(9'-cis-octadecenoyl)-2,3-dioctadecylglycerol/1-oleoyl-2,3-distearylglycerol |
D,L-1-9'-cis-octadecenoyl-2,3-dioctadecyloxypropanol(Ref. 0042)/1-O-(9'-cis-octadecenoyl)-2,3-di-O-octadecylglycerol |
EEL2151 | Keizo Waku |
C57H112O4 | 861.497 | CST=173.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
||||||||||||||||||
| 449 |  |
1-(9'-cis-octadecenoyl)-2-(9'-cis-octadecenyl)-3-octadecylglycerol/1-oleoyl-2-oleyl-3-stearylglycerol |
D,L-1-9'-cis-octadecenoyl-2-9'-cis-octadecenoyloxy-3-octadecyloxypropanol(Ref. 0042)/ 1-O-(9'-cis-octadecenoyl)-2-O-(9'-cis-octadecenyl)-3-O-octadecylglycerol |
EEL2152 | Keizo Waku |
C57H110O4 | 859.481 | 12.5-13.5 C(Ref. 0042) |
CST=166.5 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 450 |  |
1-(9'-cis-octadecenoyl)-2,3-di-(9''-octadecenyl)glycerol/1-oleoyl-2,3-dioleylglycerol |
D,L-1-9'-cis-octadecenoyl-2,3-9''-cis-octadecenyloxypropanol(Ref. 0042)/ 1-O-(9'-cis-octadecenoyl)-2,3-di-O-(9'-octadecenyl)glycerol |
EEL2153 | Keizo Waku |
C57H108O4 | 857.465 | CST=159 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers (Ref. 0042) |
synthetic product(Ref. 0042) |
||||||||||||||||||
| 451 |  |
1-octadecanoyl-2-icosyl-3-octadecylglycerol/1-stearoyl-2-arachidyl-3-stearylglycerol |
D,L-1-octadecanoyl-2-icosyloxy-3-octadecyloxypropanol(Ref. 0042)/ 1-O-octadecanoyl-2-O-icosyl-3-O-octadecylglycerol |
EEL2154 | Keizo Waku |
C59H118O4 | 891.566 | 58.5-59 C(Ref. 0042) |
CST 185 C(Ref. 0042) |
carbonyl band at 1745cm-1; C-O stretching at 1169cm-1; C-O stretching at 1120-1122cm-1; vibration of ethers(Ref. 0042) |
synthetic product(Ref. 0042) |
|||||||||||||||||
| 452 |  |
3-O-{[2-(dimethylamino)ethyl]carbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2155 | Keizo Waku |
C28H57O5N3 | 515.769 | 42-43 C(Ref. 0067) |
(KBr)3330, 1695cm-1(Ref. 0067) |
(CDCl3)d0.88(3H,brt,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.20(6H.s),2.39(2H,t,J=6Hz),3.02-3.34(4H,m),3.43(3H,s),3.58(1H,quint,J=5Hz),4.16(4H,brd,J=5Hz),5.00(1H,br)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 453 |  |
3-O-{[3-(dimethylamino)propyl]carbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2156 | Keizo Waku |
C29H59O5N3 | 529.796 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 454 |  |
3-O-{[2-(pyrrolidino)ethyl]carbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2157 | Keizo Waku |
C30H59O5N3 | 541.807 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 455 |  |
3-O-{[2-(N-morphoryl)ethyl]carbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2158 | Keizo Waku |
C30H59O6N3 | 557.806 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 456 |  |
3-O-[(2-pyridylmethyl)carbamoyl]-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2159 | Keizo Waku |
C30H53O5N3 | 535.759 | 66.5-67.0 C(Ref. 0067) |
(KBr)3320, 1695cm-1(Ref. 0067) |
(CDCl3)d0.86(3H,brt,J=7Hz),1.25(30H,s),1.4-1.7(2H,m),3.15(2H,q,J=6Hz),3.44(3H,s),3.59(1H,quint,J=5Hz),4.18(4H,m),4.50(2H,d,J=6Hz),4.80(1H,br),5.90(1H,br)7.10-7.40(2H,m),7.67(1H,dt,J=2.8Hz),8.56(1H,brd,J=5Hz) (Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 457 |  |
CV-3988 |
YAC-3-(N-n-octadecylcarbamoyloxy)-2-methoxypropyl-2-thiazolioethyl phosphate.(Ref. 0068) |
EEL2160 | Keizo Waku |
C28H53O7PN2S | 592.769 | (KBr)3400, 2920, 2851, 1701, 1558, 1246, 1065cm-1(Ref. 0068) |
(CDCl3)dppm 0.7-1.8(35H),3.46(3H,s,OCH3),2.9-4.8(9H,m),5.08(2H,broad),6.03(1H,CONH),8.55,8.88,10.93(Ref. 0068) |
synthetic product(Ref. 0068) |
||||||||||||||||||
| 458 |  |
3-N-octadecylcarbamoyl-2-methylglycerol(Ref. 0067) |
EEL2161 | Keizo Waku |
C23H47O4N | 401.624 | 55-56 C(Ref. 0068) |
MS m/l : 401(M+) (Ref. 0068) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 459 |  |
CV-6209 |
EEL2162 | Keizo Waku |
C34H60O6N3Cl | 642.310 | ||||||||||||||||||||||
| 460 |  |
2-O-acetyl-3-O-[N-acetyl-N-[2-(dimethylamino)ethyl]-carbamoyl]-1-O-octadecylglycerol(Ref. 0067) |
EEL2163 | Keizo Waku |
C30H58O6N2 | 542.791 | (VEAT)1745, 1710, 1234cm-1(Ref. 0067) |
(CDCl3)d 0.88(3H,brt,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.10(3H,s),2.23(6H,s),2.40(2H,t,J=7Hz),2.50(3H,s),3.46(2H,t,J=6Hz),3.58(2H,d,J=5Hz),3.85(2H,t,J=7Hz),4.42(2H,m),5.29(1H,m) (Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 461 |  |
3-O-{[2-(dimethylamino)ethyl]carbamoyl}-1-O-octadecylglycerol(Ref. 0067) |
EEL2164 | Keizo Waku |
C26H54O4N2 | 458.718 | (VEAT)3290, 1700, 1525, 1465cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,t,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.24(6H,s),2.40(2H,t,J=6Hz),2.99(1H,br),3.27(2H,q,J=6Hz),3.45(4H,m),3.97(1H,m),4.14(2H,m),5.48(1H,br)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 462 |  |
2-O-benzyl-3-O-{[2-(dimethylamino)ethyl]carbamoyl}-1-O-octadecylglycerol |
EEL2165 | Keizo Waku |
C33H60O4N2 | 548.841 | (VEAT)1725cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,brt,J=7Hz),1.28(30H,s),1.4-1.7(2H,m),2.20(6H,s),2.37(2H,t,J=6Hz),3.23(2H,q,J=6Hz),3.42(2H,t,J=6Hz),3,53(2H,d,J=5Hz),3.76(1H,quint,J=5Hz),4.20(2H,m),4.68(2H,s),5.28(1H,br),7.32(5H,s)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 463 |  |
2-{N-acetyl-N-{[2-acetoxy-3-(octadecyloxy)propoxy]carbonyl}amino}-N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2166 | Keizo Waku |
C33H61O6N2I | 708.752 | 73-76 C(Ref. 0067) |
(KBr)1740, 1680(br)cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,br,t,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.12(3H,s),2.52(3H,s),3.33-3.7(13H,m),3.80(2H,m),4.22(2H,br,t,J=7Hz),4.51(2H,m),5.42(1H,m)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 464 |  |
2-benzyl-3-O-[(2-hydroxyethyl)carbamoyl]-1-O-octadecylglycerol(Ref. 0067) |
EEL2167 | Keizo Waku |
C31H55O5N | 521.772 | 45-46 C(Ref. 0067) |
(KBr)3335, 1700cm-1(Ref. 0067) |
(CDCl3)d 0.89(3H,br,t,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.82(1H,brt,J=6Hz),3.15-3.91(9H,m),4.22(2H,m),4.68(2H,s),5.37(1H,brt,J=6Hz),7.33(5H,s)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 465 |  |
2-O-benzyl-3-O-[(2-bromoethyl)carbamoyl]-1-O-octadecylglycerol(Ref. 0067) |
EEL2168 | Keizo Waku |
C31H54O4NBr | 584.669 | 50-51 C(Ref. 0067) |
(VEAT)1720cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,m),1.26(30H,s),1.4-1.7(2H,m),2.41(3H,s),3.29-3.92(9H,m),4.22(2H,m),4.66(2H,s),5.06(1H,br),7.30(5H,s)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 466 |  |
2-{{[2-acetoxy-3-(octadecyloxy)propoxy]carbonyl}-amino}-N,N,N-trimethyl-1-ethaminium bromide(Ref. 0067) |
EEL2169 | Keizo Waku |
C29H59O5N2Br | 595.693 | 61-62 C(Ref. 0067) |
(KBr)1730, 1265, 1240cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,brt,J=7Hz),1.25(30H,s),1.4-1.7(2H,m),2.08(3H,s),3.32-3.97(17H,m),4.30(2H,m),5.20(1H,m),6.82(1H,m)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 467 |  |
2-O-methyl-1-O-(octadecylcarbamoyl)-3-O-(phenoxycarbonyl)glycerol(Ref. 0067) |
EEL2170 | Keizo Waku |
C30H51O6N | 521.729 | 59.5-60.5 C(Ref. 0067) |
(KBr)3330, 1762, 1695, 1275, 1250, 1205cm-1(Ref. 0067) |
(CDCl3)d 0.86(3H,brt,J=7Hz),1.26(30H,s),1.4-1.7(2H,m),3.15(2H,q,J=6Hz),3.48(3H.s),3.67(1H,m),4.22(2H,d,J=5Hz),4.33(2H,dd,J=3.5Hz),4.73(1H,br),7.10-7.53(5H,m)(Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 468 |  |
2-{[2-methoxy-3-(octadecylcarbamoyloxy)propoxy]carbonylamino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2171 | Keizo Waku |
C29H60O5N3I | 657.708 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 469 |  |
2-{[2-methoxy-3-(octadecylcarbamoyloxy)propoxy]carbonyl(N-methyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2172 | Keizo Waku |
C30H62O5N3I | 671.735 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 470 |  |
2-{[2-methoxy-3-(octadecylcarbamoyloxy)propoxy]carbonyl(N-acetyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2173 | Keizo Waku |
C31H62O6N3I | 699.745 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 471 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl(N-acetyl)amino}N,N,N-trimethyl-1-propaminium iodide(Ref. 0067) |
EEL2174 | Keizo Waku |
C32H64O6N3I | 713.772 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 472 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl(N-propionoyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2175 | Keizo Waku |
C32H64O6N3I | 713.772 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 473 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl(N-butanoyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2176 | Keizo Waku |
C33H66O6N3I | 727.798 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 474 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl(N-methoxycarbonyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2177 | Keizo Waku |
C31H62O7N3I | 715.744 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 475 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl(N-dimethylcarbamoyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2178 | Keizo Waku |
C37H65O6N4I | 788.840 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 476 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl-(N-pyrrolidinocarbonyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2179 | Keizo Waku |
C34H67O6N4I | 754.824 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 477 |  |
2-{[2-methoxy-3-(octadecylcarbamoyl)propoxy]carbonyl-(N-propylcarbamoyl)amino}N,N,N-trimethyl-1-ethaminium iodide(Ref. 0067) |
EEL2180 | Keizo Waku |
C33H67O6N4I | 742.813 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 478 |  |
3-O-{N-acetyl-N-[2-(dimethylamino)ethyl]carbamoyl}-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2181 | Keizo Waku |
C30H59O6N3 | 557.806 | (VEAT)1738, 1710, 1690cm-1(Ref. 0067) |
(CDCl3)d 0.89(3H,brt,J=7Hz),1.25(30H,s),1.4-1.7(2H,m),2.25(6H,s),2.43(2H,m),2.48(3H,s),3.13(2H,q,J=6Hz),3.43(3H,s),3.62(1H,br quint, J=5Hz), 3.86(2H,t,J=8Hz), 4.20(2H,d,J=5Hz), 4.30(2H,dd,J=2.5Hz), 5.61(1H,br)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 479 |  |
3-O-{N-[2-(dimethylamino)ethyl]-N-(methoxycarbonyl)carbamoyl}-2-O-methyl-1-o-(octadecylcarbamoyl)glycerol |
EEL2182 | Keizo Waku |
C31H60O8N4 | 616.830 | (VEAT)1790, 1750, 1725, 1705cm-1(Ref. 0067) |
(CDCl3)d 0.88(3H,m),1.25(32H,s),2.25(6H,s),2.48(2H,t,J=6Hz)3.10(2H,m),3.45(3H,s),3.67(1H,m),3.75(2H,t,J=6Hz),3.82(3H,s),4.20(2H,d,J=5Hz),4.30(2H,d,J=5Hz),5.03(1H,br)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 480 |  |
3-O-[N-acetyl-N-(2-pyridylmethyl)carbamoyl]-2-O-methyl-1-O-(octadecylcarbamoyl)glycerol(Ref. 0067) |
EEL2183 | Keizo Waku |
C32H55O6N3 | 577.796 | (KBr)3370, 1740, 1700cm-1(Ref. 0067) |
(CDCl3)d 0.86(3H,brt,J=7Hz),1.27(30H,s),1.4-1.7(2H,m),2.62(3H,s),3.12(2H,q,J=6Hz),3.30(3H,s),3.46(1H,quint,J=6Hz),3.99(2H,d,J=5Hz),4.23(2H,dd,J=2.5Hz),4.87(1H,br),5.09(2H,s),7.15(2H,m),7.64(2H,dt,J=2.8Hz),8.52(1H,m)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 481 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminoethyl]-1-methylpyrrolidinium iodide |
EEL2185 | Keizo Waku |
C33H64O6N3I | 725.782 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 482 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminoethyl]-1-methylpiperidinium iodide |
EEL2186 | Keizo Waku |
C34H66O6N3I | 739.809 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 483 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminoethyl]-1-methylmorpholinium iodide |
EEL2187 | Keizo Waku |
C33H64O7N3I | 741.782 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 484 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-methyl-1-ethyl-2-pyrrolidinium iodide(Ref. 0067) |
EEL2188 | Keizo Waku |
C34H66O6N3I | 739.809 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 485 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-methyl-2-pyridinium chloride(Ref. 0067) |
EEL2189 | Keizo Waku |
C33H58O6N3Cl | 628.283 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 486 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-propyl-2-pyridinium chloride(Ref. 0067) |
EEL2190 | Keizo Waku |
C35H62O6N3Cl | 656.336 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 487 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-butyl-2-pyridinium chloride(Ref. 0067) |
EEL2191 | Keizo Waku |
C36H64O6N3Cl | 670.363 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 488 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-methyl-2-thiazolium iodide(Ref. 0067) |
EEL2192 | Keizo Waku |
C31H56O6N3SI | 725.763 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 489 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-ethyl-2-thiazolium iodide(Ref. 0067) |
EEL2193 | Keizo Waku |
C32H58O6N3SI | 739.790 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 490 |  |
1-[N-acetyl-N-(2-methoxy-3-octadecylcarbamoyloxypropoxycarbonyl)aminomethyl]-1-methyl-4-thiazolium iodide(Ref. 0067) |
EEL2194 | Keizo Waku |
C31H56O6N3SI | 725.763 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 491 |  |
4-{[N-acetyL-N-{[2-methoxy-3-[(octadecylcarbamoyl)-oxy]propoxy]carbonyl}amino]methyl}-3-ethyl-thiazolium chloride(Ref. 0067) |
EEL2195 | Keizo Waku |
C32H58O6N3SCl | 648.338 | 55-56 C(Ref. 0067) |
(KBr) 1750, 1705cm-1(Ref. 0067) |
(CDCl3)d 0.87(3H,m),1.23(32H,s),1.72(3H,t,J=7Hz),2.60(3H,s),3.08(2H,m),3.45(3H,s),3.79(1H,m),4.14(2H,d,J=5Hz),4.42(2H,d,J=5Hz),4.87(2H,q,J=7Hz),5.07(1H,br),5.20(2H,s),8.25(1H,d,J=2Hz),10.80(1H,d,J=2Hz) (Ref. 0067) |
synthetic product(Ref. 0067) |
||||||||||||||||||
| 492 |  |
1-O-benzyl-2-O-methyl-3-O-trityl-Sn-glycerol(Ref. 0067) |
EEL2196 | Keizo Waku |
C30H30O3 | 438.557 | (VEAT)3060, 3025, 2930, 2870, 1495, 1450, 1210, 1090, 750, 700cm-1(Ref. 0067) |
(60MHz,CDCl3)d 3.25(2H,d,J=5Hz),3.42(3H,s),3.62(3H,m),4.53(2H,s),7.30(20H,m) (Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 493 |  |
1-O-benzyl-2-O-methyl-sn-glycerol(Ref. 0067) |
EEL2197 | Keizo Waku |
C11H16O3 | 196.243 | (VEAT)3450, 2940, 2870, 1450, 1360, 1080, 1030, 740, 700cm-1(Ref. 0067) |
d 2.08(1H,br),3.47(3H,s),3.5-3.8(5H,m),4.55(2H,s),7.33(5H,s)(Ref. 0067) |
synthetic product(Ref. 0067) |
|||||||||||||||||||
| 494 |  |
1-octadecyl-2-benzyl-sn-glycerol(Ref. 0067) |
EEL2198 | Keizo Waku |
C28H50O3 | 434.695 | synthetic product(Ref. 0067) |
|||||||||||||||||||||
| 495 |  |
archaeol |
EEL3001 | Toshihiro Itoh |
ArOH |
C43H88O3 | 653.157 | |||||||||||||||||||||
| 496 |  |
C20,C25-archaeol |
EEL3002 | Toshihiro Itoh |
C20,C25-ArOH |
C48H96O3 | 721.274 | |||||||||||||||||||||
| 497 |  |
C25,C25-archaeol |
EEL3003 | Toshihiro Itoh |
C25,C25-ArOH |
C53H106O3 | 791.407 | archaebacterial haloalkaliphile (Ref. 0080) |
||||||||||||||||||||
| 498 |  |
cyclic archaeol |
EEL3004 | Toshihiro Itoh |
cyc ArOH |
C43H84O3 | 649.125 | FD-MS (Ref. 0081) |
||||||||||||||||||||
| 499 |  |
caldarchaeol |
EEL3006 | Toshihiro Itoh |
C86H174O6 | 1304.298 | 600-4000 cm-1 (Ref. 0133) |
|||||||||||||||||||||
| 500 |  |
nonitolcaldarchaeol |
EEL3007 | Toshihiro Itoh |
C92H184O12 | 1482.438 | ||||||||||||||||||||||
| 501 |  |
archaetidylglycerol |
EEL3008 | Toshihiro Itoh |
AG/A1-2 |
C46H94O8P | 806.208 | SIMS 805.6 (M-H)- (Ref. 0168) |
||||||||||||||||||||
| 502 |  |
2,3-di-O-phytanyl-sn-glycerol-1-phosphoryl-1'-sn-glycerol (Ref. 0086) |
EEL3009 | Toshihiro Itoh |
C46H94O8P | 806.208 | chemically synthesized |
|||||||||||||||||||||
| 503 |  |
archaetidylglycerophosphate |
EEL3010 | Toshihiro Itoh |
AGP |
C46H95O11P2 | 886.187 | 31P-NMR (Ref. 0089) |
||||||||||||||||||||
| 504 |  |
archaetidylglycerosulfate |
EEL3011 | Toshihiro Itoh |
AGS |
C46H94O11PS | 886.272 | Halobacterium cutirubrum (Ref. 0141) |
||||||||||||||||||||
| 505 |  |
3'-HSO3-Galp-b1'-6'Manp-a1'-2'Glcp-a1'-1archaeol |
EEL3012 | Toshihiro Itoh |
S-TGA-1 |
C61H118O21S | 1219.643 | 800-4000 cm-1(Ref. 0095) |
MS of methylated compound(Ref. 0094) |
HALOBACTERIUM CUTIRUBRUM (Ref. 0095) |
||||||||||||||||||
| 506 |  |
Galp-b1'-6'Manp-a-1'-2'Glcp-a1'-1archaeol |
EEL3013 | Toshihiro Itoh |
TGA |
C61H118O18 | 1139.579 | Halobacterium cutirubrum (Ref. 0093) |
||||||||||||||||||||
| 507 |  |
3'-HSO3-Galp-b1'-6'-Manp-(3'-1'Galf-b)-a1'-2'-Glcp-a1'-1archaeol |
EEL3014 | Toshihiro Itoh |
S-TeGA |
C67H128O26S | 1381.784 | Halobacterium cutirubrum (Ref. 0093) |
||||||||||||||||||||
| 508 |  |
Galp-b1'-6'Manp-(3'-1'Galf-b)a1'-2'Glcp-a1'-1 archaeol |
EEL3015 | Toshihiro Itoh |
TeGA |
C67H128O23 | 1301.719 | Halobacterium cutirubrum(Ref. 0093) |
||||||||||||||||||||
| 509 |  |
Glcp-a1'-2'Galf-b1'-1archaeol |
EEL3019 | Toshihiro Itoh |
glucosyl galactosyl ArOH / DGD-I |
C55H108O13 | 977.438 | Methanospirillum hungatei(Ref. 0115) |
||||||||||||||||||||
| 510 |  |
Galf-b1'-6'-Galf-b1'-1archaeol |
EEL3020 | Toshihiro Itoh |
DGD-II |
C55H108O13 | 977.438 | Methanospirillum hungatei(Ref. 0115) |
||||||||||||||||||||
| 511 |  |
Galf-b1'-6'Galf-b1'-1caldarchaetidylglycerol |
EEL3021 | Toshihiro Itoh |
PGL-II |
C101H198O21P | 1779.614 | Methanospirillum hungatei(Ref. 0115) |
||||||||||||||||||||
| 512 |  |
EEL3022 | Toshihiro Itoh |
DGT-I |
C98H192O16 | 1626.563 | Methanospirillum hungatei(Ref. 0115) |
|||||||||||||||||||||
| 513 |  |
EEL3023 | Toshihiro Itoh |
DGT-II |
C98H192O16 | 1626.563 | Methanospirillum hungatei(Ref. 0115) |
|||||||||||||||||||||
| 514 |  |
Glcp-a1'-2'Galf-b1'-1caldarchaetidylglycerol |
EEL3024 | Toshihiro Itoh |
PGL-I |
C101H198O21P | 1779.614 | Methanospirillum hungatei(Ref. 0115) |
||||||||||||||||||||
| 515 |  |
archaetidylethanolamine |
EEL3025 | Toshihiro Itoh |
AE |
C45H92O6PN | 774.189 | 1H-NMR, 31P-NMR (Ref. 0103) |
||||||||||||||||||||
| 516 |  |
archaetidylserine |
EEL3026 | Toshihiro Itoh |
AS |
C46H92O8PN | 818.198 | |||||||||||||||||||||
| 517 |  |
archaetidylinositol |
EEL3027 | Toshihiro Itoh |
AI |
C49H99O11P | 895.278 | |||||||||||||||||||||
| 518 |  |
gentiobisylarchaeol |
EEL3028 | Toshihiro Itoh |
Gentiobiosyl ArOH |
C55H108O13 | 977.438 | |||||||||||||||||||||
| 519 |  |
EEL3029 | Toshihiro Itoh |
CE |
C88H178O9PN | 1425.330 | 4000-800cm-1 (Ref. 0086) |
""1H-NMR, 31P-NMR (Ref. 0103) |
Methanobacterium thermoautotrophicum(Ref. 0099) |
|||||||||||||||||||
| 520 |  |
EEL3030 | Toshihiro Itoh |
CS |
C89H178O11PN | 1469.340 | ||||||||||||||||||||||
| 521 |  |
EEL3031 | Toshihiro Itoh |
CI |
C92H183O14P | 1544.403 | ||||||||||||||||||||||
| 522 |  |
EEL3032 | Toshihiro Itoh |
Gen-CAOH/GL-3(Ref. 1005) |
C98H192O16 | 1626.563 | 4000-800 cm-1 (Ref. 0086) |
|||||||||||||||||||||
| 523 |  |
EEL3033 | Toshihiro Itoh |
gentiobiosyl CE |
C100H198O19PN | 1749.611 | 4000-800 cm-1(Ref. 0086) |
Methanobacterium thermoautotrophycum(Ref. 0099) |
||||||||||||||||||||
| 524 |  |
EEL3034 | Toshihiro Itoh |
gentiobiosyl CI |
C104H203O24P | 1868.684 | ||||||||||||||||||||||
| 525 |  |
EEL3035 | Toshihiro Itoh |
gentiobiosyl CS |
C101H198O21PN | 1793.621 | ||||||||||||||||||||||
| 526 |  |
EEL3036 | Toshihiro Itoh |
ATMAPT |
C51H105O9PN | 907.355 | Methanospirillum hungatei(Ref. 0105) |
|||||||||||||||||||||
| 527 |  |
EEL3037 | Toshihiro Itoh |
ADMAPT |
C50H102O9PN | 892.320 | Methanospirillum hungatei(Ref. 0105) |
|||||||||||||||||||||
| 528 |  |
archaetidyl-N-acetylglucosamine(Ref. 0002) |
2,3-di-O-(3',7',11',15'-tetramethyl)hexadecyl-sn-glycerol-1-phospho-(2''-acetoamido-2''-deoxy)-b-D-glucose/ 2,3-di-O-phytanyl-sn-glycerol-1-phospho-N-acetylglucosamine(Ref. 0002) |
EEL3038 | Toshihiro Itoh |
ArGlcNAc |
C51H101O11PN | 935.322 | P=O, P-O-C, 1240, 1040cm-1, C=O, 1740cm-1, -CH3, 2855, 2870cm-1, -CH2-, 2828-2960, 1460cm-1; -CH(CH3)2, 1360, 1380cm-1; -OH, 3265cm-1, amide stretch, 3210, 1550cm-1ether C-O-C, 1110 cm-1; (Ref. 0002) [Spectrum 0028] |
1H-NMR, 1.85 ppm13C-NMR, 69.02 (C-1 of sn-2 phytanyl), 70.17 (C-1 of sn-3 phytanyl), 65.68 (C-1 of glycerol), 78.49 (C-2 of glycerol), 71.23 (C-3 of glycerol), 94.54 (C-1 of sugar), 54.61 (C-2 of sugar), 71.69 (C-3 of sugar), 71.69 (C-4 of sugar), 74.19 (C-5 of sugar), 62.33 (C-6 of sugar)(Ref. 0002) [Spectrum 0029] |
Methanococcus voltae(Ref. 0002) |
|||||||||||||||||
| 529 |  |
EEL3040 | Toshihiro Itoh |
C98H192O16 | 1626.563 | core lipid (Ref. 0134) |
||||||||||||||||||||||
| 530 |  |
EEL3041 | Toshihiro Itoh |
C104H202O24P | 1867.676 | core lipid (Ref. 0134) |
||||||||||||||||||||||
| 531 |  |
EEL3042 | Toshihiro Itoh |
C98H194O17 | 1644.579 | core lipid(Ref. 0126) |
||||||||||||||||||||||
| 532 |  |
EEL3043 | Toshihiro Itoh |
C104H204O25P | 1885.691 | core lipid (Ref. 0126) |
||||||||||||||||||||||
| 533 |  |
EEL3044 | Toshihiro Itoh |
C98H193O20S | 1723.635 | core lipid(Ref. 0126) |
||||||||||||||||||||||
| 534 |  |
glucosyl calditocaldarchaeol(Ref. 0142) |
EEL3051 | Toshihiro Itoh |
C98H176192O16 | 179024.000 | |
dissolved in the solvent mixture of chloroform : methanol(2:1) |
13C-NMR of acetylated compound(in CDCl3),71.03(C-1 of calditol),77.66(C-2 of calditol),71.75(C-3 of calditol),64.13(C-1 of glycerol),76.66(C-2 of glycerol),70.03(C-3 of glycerol),84.48(C-1' of calditol),87.44(C-2' of calditol),72.64(C-3' of calditol),79.00(C-4' of calditol),80.68(C-5' of calditol),59.56(C-6 of calditol),100.50(C-1 of sugar),71.28(C-2 of sugar),72.69(C-3 of sugar),68.38(C-4 of sugar),71.92(C-5 of sugar),61.79(C-6 of sugar)(Ref. 0142) |
FABm/z1618(M+1)+ : a matrix of 3-nitorobenzyl alcohol(Ref. 0142) |
Sulfolobus acidocaldarius(Ref. 0142)/Sulfolobus solfataricus/Acidianus brierleyi/Metallosphaera sedula |
|||||||||||||||||
| 535 |  |
myo-inositolphosphoric-trialkylcaldarchaetidyl-myo-inositol(Ref. 0143) |
EEL3053 | Toshihiro Itoh |
PL-Z(Ref. 0143) |
C98H196O32P2 | 1948.533 | |
FABm/z1786(M-1)-: a matrix of glycerol(Ref. 0143) |
Sulfolobus acidocaldarius(Ref. 0143)/Sulfolobus solfataricus/Acidianus brierleyi/Metallosphaera sedula |
||||||||||||||||||
| 536 |  |
trialkylcaldarchaetidyl-myo-inositol(Ref. 0143) |
EEL3054 | Toshihiro Itoh |
PL-Y(Ref. 0143) |
C92H185O14P | 1546.419 | |
FABm/z1544(M-1)-: a matrix of glycerol(Ref. 0143) |
Sulfolobus acidocaldarius(Ref. 0143)/Sulfolobus solfataricus/Acidianus brierleyi/Metallosphaera sedula |
||||||||||||||||||
| 537 |  |
3-phosphoglucosyl archaeol |
2,3-di-O-phytanyl-sn-glycero-1-(a-D-glucopyranosyl-3-phosphate) (Ref. 0144) |
EEL3055 | Toshihiro Itoh |
PGD(Ref. 0144) |
C49H99O11P | 895.278 | |
hydroxyl(3350cm-1),methylene(1460,2925 and 2926cm-1),methyl(2860cm-1), isopropyl (1365-1375cm-1),phosphate(1255 and 1060cm-1), C-O-C(1085cm-1)(Ref. 0144) |
FABm/z916(M+Na)+ : glycerol matrix adding 0.1%sodium acetate, FABm/z893(M-1)- : a glycerol matrix(Ref. 0144) |
[a] =+34(CHCl3) |
TLC, Rf=0.35(CHCl3/MeOH/H2O=65:25:4)(Ref. 0144) |
Pyrococcus woesei (Ref. 0144) |
||||||||||||||
| 538 |  |
b-D-glucopyranosyl-diglycerol tetraether (Ref. 0145)/ b-D-Glcp-caldarchaeol |
EEL3056 | Toshihiro Itoh |
GL-1(Ref. 0145) |
C92H182O11 | 1464.423 | |
molecular rotation +24 (20 C, in chloroform) |
103.6ppm indicates a b-glucosidic linkage |
||||||||||||||||||
| 539 |  |
b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyldiglycerol tetraether(Ref. 0145) / b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl-(1,6)-b-D-glucopyranosyl caldarchaeol |
EEL3058 | Toshihiro Itoh |
GL-4(Ref. 0145) |
C104H202O21 | 1788.704 | |
Thermoproteus tenax(Ref. 0145) |
|||||||||||||||||||
| 540 |  |
b-D-glucopyranosyl-caldarchaetidyl -myo-inositol(Ref. 0145) |
EEL3059 | Toshihiro Itoh |
PL-3(Ref. 0145) |
C98H193O19P | 1706.543 | |
||||||||||||||||||||
| 541 |  |
a-D-glucopyranosyl-(1,4)-b-D-galactopyranosyl-caldarchaeol |
EEL3060 | Toshihiro Itoh |
C98H192O16 | 1626.563 | |
13C-NMR of compound in [CDCl3/CD3OH/D2O(65:25:4)] ; ppm isopranoid chains : 69.0T(C-1), 69.5T(C-1'), 36.8T(C-2), 37.1T(C-2'), 30.8D(C-3), 31.4D(C-3'), 37.4T(C-4,6,8,10,12,14), 24.7T(C-5), 32.8D(C-7,11), 33.0D(C-15), 24.5T(C-9,13), 33.3T(C-16), 19.5Q(C-17), 19.8Q(C-18,19,20) glycerol : 62.3T(C-1a), 71.1T(C-1b), 78.4D(C-2), 70.2T(C-3) galactosyl : 104.3T(C-1), 70.4T(C-2), 70.8T(C-3), 77.2(C-4), 74.2T(C-5), 61.2D(C-6) glucosyl : 98.6T(C-1), 71.7T(C-2), 73.4T(C-3), 70.1T(C-4), 71.9(C-5), 61.9D(C-6) |
FABm/z1646(M+Na)+ : glycerol matrix adding 0.1%sodium acetate, FABm/z1622(M-H)-, m/z1490[(M-H)-132]-, m/z1328[(M-H)-132-162]-: glycerol matrix |
Desulfurococcus mobilis(Ref. 0146) |
||||||||||||||||||
| 542 |  |
b-D-galactopyranosyl-caldarchaetidyl-myo-inositol |
EEL3061 | Toshihiro Itoh |
C98H192O19P | 1705.535 | |
13C-NMR in [CDCl3/CD3OH/D2O(65:25:4)] ; ppm isopranoid chains : 69.0T(C-1), 69.4T(C-1'), 36.7T(C-2), 37.1T(C-2'), 30.8D(C-3), 31.3D(C-3'), 37.4T(C-4,6,8,10,12,14), 24.6T(C-5), 32.8D(C-7,11), 33.0D(C-15), 24.5T(C-9,13), 33.2T(C-16), 19.6Q(C-17), 19.9Q(C-18,19,20)(Ref. 0146) glycerol : 65.3T(C-1a), 71.0T(C-1b), 78.5D(C-2), 70.1T(C-3) galactosyl : 104.3T(C-1), 70.6T(C-2), 72.2T(C-3), 68.2(C-4), 75.2T(C-5), 61.0D(C-6) P-myo-inositol : 72.6T, 73.4T, 71.4T, 71.4T, 70.2T, 69.8T(Ref. 0146) |
FABm/z1762(M+Na)+ : glycerol matrix adding 0.1%sodium acetate,(Ref. 0146) |
Desulfurococcus mobilis(Ref. 0146) |
||||||||||||||||||
| 543 |  |
a-D-glucopyranosyl-(1,4)-b-D-galactopyranosyl-caldarchaetidyl-myo-inositol |
EEL3062 | Toshihiro Itoh |
C104H202O24P | 1867.676 | |
13C-NMR in [CDCl3/CD3OH/D2O(65:25:4)] ; ppm isopranoid chains : 69.0T(C-1), 69.4T(C-1'), 36.8T(C-2), 37.0T(C-2'), 30.9D(C-3), 31.1D(C-3'), 37.5T(C-4,6,8,10,12,14), 24.6T(C-5), 32.8D(C-7,11), 33.0D(C-15), 24.5T(C-9,13), 33.2T(C-16), 19.6Q(C-17), 19.9Q(C-18,19,20)(Ref. 0146) glycerol : 65.3T(C-1a), 71.0T(C-1b), 78.4D(C-2), 70.2T(C-3) galactosyl : 104.3T(C-1), 70.4T(C-2), 70.9T(C-3), 77.4(C-4), 74.0T(C-5), 61.3D(C-6) glucosyl : 98.8T(C-1), 71.8T(C-2), 73.4T(C-3), 70.1T(C-4), 71.8(C-5), 61.7D(C-6) P-myo-inositol : 72.5T, 73.4T, 71.3T, 71.3T, 70.2T, 69.9T(Ref. 0146) |
FABm/z1888(M+Na)+ : glycerol matrix adding 0.1%sodium acetate,(Ref. 0146) |
Desulfurococcus mobilis(Ref. 0146) |
||||||||||||||||||
| 544 |  |
b-L-gulopyranosyl-caldarchaetidyl-glycerol |
EEL3063 | Toshihiro Itoh |
MPL(Ref. 0147) |
C95H189O16P | 1618.481 | |
MPL(2rings), +161.4 in CHCl3 |
13C-NMR in [benzen-d6 / CD3OD(7:1)] ; ppm sugar moiety : 102.25(C-1),69.18(C-2), 72.18(C-3), 70.67(C-4), 73.86(C-5), 62.40(C-6) 1H-NMR, 4.864(H-1), 4.056(H-2), 4.337(H-3), 4.091(H-4), 4.17(H-5), 4.001(H-6,6')(Ref. 0147) |
FABm/z1612.6(1606.7-1619.8)[M-H]- : triethanolamine matrix(Ref. 0147) |
Thermoplasma acidophilum / Thermoplasma volcanium(Ref. 0147) |
||||||||||||||||
| 545 | No image | EEL3064 | Toshihiro Itoh |
C98H192O16 | 1626.563 | core lipid (Ref. 0134) |
||||||||||||||||||||||
| 546 |  |
[Manp-(a1,2)-Manp-(a1,4)-Manp-(a1,3)]8-Glcp-(a1,1)-dibiphytanyldiglycerol tetraether/ [Manp-(a1,2)-Manp-(a1,4)-Manp-(a1,3)]8-Glcp-(a1,1)-caldarchaeol |
EEL3065 | Toshihiro Itoh |
C236H424O131 | 5357.813 | |
Thermoplasma acidophilum(Ref. 0160) |
||||||||||||||||||||
| 547 |  |
isocaldarchaeol(Ref. 0161) |
EEL3066 | Toshihiro Itoh |
C86H174O6 | 1304.298 | |
Methanobacterium thermoautotrophicum, Sulfolobus solfataricus, thermoplasma acidophilum(Ref. 0161) |
||||||||||||||||||||
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