https://lipidbank.jp/mediawiki/index.php?action=history&feed=atom&title=LBF16102PG01 2026-04-30T08:26:34Z Revision history for this page on the wiki MediaWiki 1.43.0 https://lipidbank.jp/mediawiki/index.php?title=LBF16102PG01&diff=46789&oldid=prev 2010-10-25T10:30:28Z

<p>New page: {{Lipid/Header}} {{Hierarchy|{{PAGENAME}}}} {{Metabolite |LipidBank=DFA8078 |LipidMaps=LMFA01050151 |SysName=Methyl-8- [ 2- (2-formylvinyl) -3-hydroxy-5-oxocyclopentyl ] octanic acid |Co...</p> <p><b>New page</b></p><div>{{Lipid/Header}}<br /> <br /> {{Hierarchy|{{PAGENAME}}}}<br /> <br /> {{Metabolite<br /> |LipidBank=DFA8078<br /> |LipidMaps=LMFA01050151<br /> |SysName=Methyl-8- [ 2- (2-formylvinyl) -3-hydroxy-5-oxocyclopentyl ] octanic acid<br /> |Common Name=&amp;&amp;Methyl-8- [ 2- (2-formylvinyl) -3-hydroxy-5-oxocyclopentyl ] octanic acid&amp;&amp;<br /> |Mass Spectra=GC-EI-MS(after reduction(NaBH4) and TMS-derivatization)[[Reference:Nakamura_T:,Lipids,1986,21,553|{{RelationTable/GetFirstAuthor|Reference:Nakamura_T:,Lipids,1986,21,553}}]]: m/e=530[M]; 515[M-CH3]; 440[M-HOTMS]; 425[440-CH3]; 399[515-SMTO=CHCH2]; 324[440-SMTO= CHCH2]; 311[M-SMTOC3H5OTMS]; 243[SMTOC5H5OTMS]; 217[EMTOC3H3OTMS]; 191[SMT OCHOTMS]; 167[C6H6OTMS]<br /> |IR Spectra=Keto carbonyl: 1740cm^{-1}[the peak corresponded with ester carbonyl] conjugated aldehyde: 1688cm^{-1} [[Reference:Nakamura_T:,Lipids,1986,21,553|{{RelationTable/GetFirstAuthor|Reference:Nakamura_T:,Lipids,1986,21,553}}]]<br /> |Source=It is prodused from 12-hydroperoxy isomer via PGG-like endoperoxide during autooxidation of linoleate[[Reference:Nakamura_T:,Lipids,1986,21,553|{{RelationTable/GetFirstAuthor|Reference:Nakamura_T:,Lipids,1986,21,553}}]].<br /> |Chemical Synthesis=<br /> |Metabolism=<br /> }}<br /> <br /> {{Lipid/Footer}}</div>

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