LBF18207OX01 - Revision history

Editor at 00:00, 17 January 2014

2014-01-17T00:00:00Z

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 |Metabolism=
 |Biological Activity=It showed a slightly lower toxicity than linoleate monohydroxyperoxide<!--8045-->[[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]].
 }}
 {{Lipid/Footer}}

Editor at 02:43, 14 May 2013

2013-05-14T02:43:28Z

← Older revision		Revision as of 11:43, 14 May 2013
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	\|LipidMaps=LMFA01060072		\|LipidMaps=LMFA01060072
	\|SysName=13-Oxo-9,11-octadecadienoic acid		\|SysName=13-Oxo-9,11-octadecadienoic acid
	\|Common Name=&&13-~~Oxo-9,11-octadecadienoic acid~~&&		\|Common Name=&&13-KODE&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]

Editor at 07:58, 26 May 2010

2010-05-26T07:58:13Z

← Older revision		Revision as of 16:58, 26 May 2010
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	\|LipidBank=DFA8047		\|LipidBank=DFA8047
	\|LipidMaps=LMFA01060072		\|LipidMaps=LMFA01060072
	\|SysName=13-Oxo-9,11-~~Octadecadienoic Acid/13-Oxo-9,11-Octadecadienoate~~		\|SysName=13-Oxo-9,11-octadecadienoic acid
	\|Common Name=&&13-Oxo-9,11-~~Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate~~&&		\|Common Name=&&13-Oxo-9,11-octadecadienoic acid&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]

Editor at 21:00, 14 April 2010

2010-04-14T21:00:00Z

← Older revision	Revision as of 06:00, 15 April 2010
(No difference)

Editor at 10:00, 25 February 2010

2010-02-25T10:00:10Z

← Older revision		Revision as of 19:00, 25 February 2010
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	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^{-1}), cis, trans unsaturations(960-955cm^{-1}), unsaturated ketone(1695-1600cm^{-1})[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)
	\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].		\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].

Editor at 14:00, 19 February 2010

2010-02-19T14:00:10Z

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&		\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra=~~lambdaMeOH~~/max=277-278nm(epsilon=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], ~~lambdamax~~=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: ~~lambdaCHCl3~~/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)

Editor at 14:00, 19 February 2010

2010-02-19T14:00:00Z

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&		\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra=~~<FONT FACE="Symbol">l</FONT>MeOH~~/max=277-278nm(~~<FONT FACE="Symbol">e</FONT>~~=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), ~~<FONT FACE="Symbol">l</FONT>~~ EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], ~~<FONT FACE="Symbol">l</FONT>max~~=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: ~~<FONT FACE="Symbol">l</FONT>CHCl3~~/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra=lambdaMeOH/max=277-278nm(epsilon=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambdamax=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambdaCHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~), cis, trans unsaturations(960-955cm~~<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=~~-1~~>1</FONT></SUP>~~), unsaturated ketone(1695-1600cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=~~<SUP><FONT SIZE=-~~1~~>1</FONT></SUP>~~H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)
	\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].		\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].
	\|Chemical Synthesis=		\|Chemical Synthesis=

Editor at 16:30, 26 January 2010

2010-01-26T16:30:00Z

← Older revision		Revision as of 01:30, 27 January 2010
Line 15:		Line 15:
	\|Chemical Synthesis=		\|Chemical Synthesis=
	\|Metabolism=		\|Metabolism=
	\|Biological Activity=It showed a slightly lower toxicity than linoleate monohydroxyperoxide[[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]].		\|Biological Activity=It showed a slightly lower toxicity than linoleate monohydroxyperoxide<!--8045-->[[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]].
	}}		}}

	{{Lipid/Footer}}		{{Lipid/Footer}}

Editor at 21:00, 6 January 2010

2010-01-06T21:00:00Z

← Older revision		Revision as of 06:00, 7 January 2010
Line 15:		Line 15:
	\|Chemical Synthesis=		\|Chemical Synthesis=
	\|Metabolism=		\|Metabolism=
			\|Biological Activity=It showed a slightly lower toxicity than linoleate monohydroxyperoxide[[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]].
	}}		}}

	{{Lipid/Footer}}		{{Lipid/Footer}}

Editor at 11:55, 25 November 2009

2009-11-25T11:55:00Z

← Older revision		Revision as of 20:55, 25 November 2009
Line 12:		Line 12:
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), cis, trans unsaturations(960-955cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), unsaturated ketone(1695-1600cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), cis, trans unsaturations(960-955cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), unsaturated ketone(1695-1600cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)
	\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]];>. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]];>.		\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].
	\|Chemical Synthesis=		\|Chemical Synthesis=
	\|Metabolism=		\|Metabolism=

← Older revision		Revision as of 19:00, 25 February 2010
Line 10:		Line 10:
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^{-1}), cis, trans unsaturations(960-955cm^{-1}), unsaturated ketone(1695-1600cm^{-1})[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)
	\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].		\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&		\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra=~~lambdaMeOH~~/max=277-278nm(epsilon=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], ~~lambdamax~~=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: ~~lambdaCHCl3~~/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra= lambda MeOH/max=277-278nm( epsilon =20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambda max=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambda CHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&		\|Common Name=&&13-Oxo-9,11-Octadecadienoic Acid&&13-Oxo-9,11-Octadecadienoate&&
	\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA		\|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Hamberg_M:,Lipids,1975,10,87\|{{RelationTable/GetFirstAuthor\|Reference:Hamberg_M:,Lipids,1975,10,87}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BP:Garwood_RF:Weedon_BC:,Lipids,1977,12,908}}]][[Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Nelson_EC:Tjarks_LW:England_RE:,Chem. Phys. Lipids,1984,35,87}}]]: m/e=308[M], 277[M-OCH3], 252[M-CH2=C H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3], GC-EI-MS(TMS)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]: m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS], 166[M-(CH2)6C(=O)OTMS]; REARRA
	\|UV Spectra=~~<FONT FACE="Symbol">l</FONT>MeOH~~/max=277-278nm(~~<FONT FACE="Symbol">e</FONT>~~=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), ~~<FONT FACE="Symbol">l</FONT>~~ EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], ~~<FONT FACE="Symbol">l</FONT>max~~=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: ~~<FONT FACE="Symbol">l</FONT>CHCl3~~/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]		\|UV Spectra=lambdaMeOH/max=277-278nm(epsilon=20300)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]](038/078/075), lambda EtOH /max=278nm[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]], lambdamax=267nm(cyclohexane)[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]], DNP hydrazone: lambdaCHCl3/max=388, 304, 265nm[[Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327\|{{RelationTable/GetFirstAuthor\|Reference:Garssen_GJ:Vliegenthart_JF:Boldingh_J:,Biochem. J.,1971,122,327}}]]
	\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~), cis, trans unsaturations(960-955cm~~<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=~~-1~~>1</FONT></SUP>~~), unsaturated ketone(1695-1600cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]		\|IR Spectra=Trans, trans unsaturations(strong absorption at 1000-990cm^- ^1 ), cis, trans unsaturations(960-955cm^- ^1 ), unsaturated ketone(1695-1600cm^- ^1 )[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847\|{{RelationTable/GetFirstAuthor\|Reference:Streckert_G:Stan_HJ:,Lipids,1975,10,847}}]][[Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448\|{{RelationTable/GetFirstAuthor\|Reference:Schieberle_P:Tsoukalas_B:Grosch_W:,Z. Lebensm. Unters. Forsch.,1979,168,448}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
	\|NMR Spectra=~~<SUP><FONT SIZE=-~~1~~>1</FONT></SUP>~~H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)		\|NMR Spectra=^1 H-NMR[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613\|{{RelationTable/GetFirstAuthor\|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]: C8(2.20-2.23ppm), C9, 10, 12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)
	\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].		\|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[trans, trans; or trans, cis][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A degradation product of hydroperoxymethyllinoleate in the presence of di-t-butyl diperoxyoxalate or Co(II)[[Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177\|{{RelationTable/GetFirstAuthor\|Reference:Yamamoto_Y:Saeki_N:Haga_S:Niki_E:_Kamiya_Y:,Bull. Chem. Soc. Jpn.,1984,57,3177}}]].
	\|Chemical Synthesis=		\|Chemical Synthesis=