LBF18303HP03 - Revision history

Editor at 00:00, 17 January 2014

2014-01-17T00:00:00Z

@@ Line 16: / Line 16: @@
 |Metabolism=
 |Biological Activity=Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously.[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485|{{RelationTable/GetFirstAuthor|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]]<!--8044--><!--8045-->[[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365|{{RelationTable/GetFirstAuthor|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]<!--8048--><!--8049-->. It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]].
 }}
 {{Lipid/Footer}}

Editor at 02:44, 14 May 2013

2013-05-14T02:44:07Z

← Older revision		Revision as of 11:44, 14 May 2013
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	\|LipidMaps=LMFA01040015		\|LipidMaps=LMFA01040015
	\|SysName=13-Hydroperoxy-9,11,15-octadecatrienoic acid		\|SysName=13-Hydroperoxy-9,11,15-octadecatrienoic acid
	\|Common Name=&&13-~~Hydroperoxy-9,11,15-octadecatrienoic acid~~&&		\|Common Name=&&13-HpOTrE&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm

Editor at 08:15, 26 May 2010

2010-05-26T08:15:56Z

← Older revision		Revision as of 17:15, 26 May 2010
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	\|LipidBank=DFA8052		\|LipidBank=DFA8052
	\|LipidMaps=LMFA01040015		\|LipidMaps=LMFA01040015
	\|SysName=13-Hydroperoxy-9,11,15-~~Octadecatrienoic Acid/13-Hydroperoxy-9,11,15-Octadecatrienoate~~		\|SysName=13-Hydroperoxy-9,11,15-octadecatrienoic acid
	\|Common Name=&&13-Hydroperoxy-9,11,15-~~Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate~~&&		\|Common Name=&&13-Hydroperoxy-9,11,15-octadecatrienoic acid&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm

Dbmanager at 21:00, 14 April 2010

2010-04-14T21:00:00Z

← Older revision		Revision as of 06:00, 15 April 2010
(No difference)

Dbmanager at 04:19, 17 March 2010

2010-03-17T04:19:59Z

← Older revision		Revision as of 13:19, 17 March 2010
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	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in ~~etoh~~)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm

Editor at 10:00, 25 February 2010

2010-02-25T10:00:10Z

← Older revision		Revision as of 19:00, 25 February 2010
Line 10:		Line 10:
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm
	\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25		\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25

Editor at 14:00, 19 February 2010

2010-02-19T14:00:10Z

← Older revision		Revision as of 23:00, 19 February 2010
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	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: ~~lambdamax~~=233nm, trans, trans, cis isomer: ~~lambdamax~~=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm

Editor at 14:00, 19 February 2010

2010-02-19T14:00:00Z

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: ~~<FONT FACE="Symbol">l</FONT>max~~=233nm, trans, trans, cis isomer: ~~<FONT FACE="Symbol">l</FONT>max~~=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambdamax=233nm, trans, trans, cis isomer: lambdamax=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm~~<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=~~-1~~>1</FONT></SUP>~~; trans, trans, cis isomer: 992-983cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1
	\|NMR Spectra=~~<SUP><FONT SIZE=-1>~~1~~</FONT></SUP>~~H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ~~<SUP><FONT SIZE=-~~1~~>1</FONT></SUP>~~H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm
	\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25		\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25
	\|Chemical Synthesis=		\|Chemical Synthesis=

Editor at 16:30, 26 January 2010

2010-01-26T16:30:00Z

← Older revision		Revision as of 01:30, 27 January 2010
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	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>; trans, trans, cis isomer: 992-983cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>; trans, trans, cis isomer: 992-983cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>
	\|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz <SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz <SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm
	\|Source=Auto oxidation of linoleate[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]][[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25		\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25
	\|Chemical Synthesis=		\|Chemical Synthesis=
	\|Metabolism=		\|Metabolism=
	\|Biological Activity=Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously.[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485\|{{RelationTable/GetFirstAuthor\|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]][[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365\|{{RelationTable/GetFirstAuthor\|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]. It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]].		\|Biological Activity=Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously.[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485\|{{RelationTable/GetFirstAuthor\|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]]<!--8044--><!--8045-->[[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365\|{{RelationTable/GetFirstAuthor\|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]<!--8048--><!--8049-->. It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]].
	}}		}}

	{{Lipid/Footer}}		{{Lipid/Footer}}

Editor at 21:00, 6 January 2010

2010-01-06T21:00:00Z

← Older revision		Revision as of 06:00, 7 January 2010
Line 15:		Line 15:
	\|Chemical Synthesis=		\|Chemical Synthesis=
	\|Metabolism=		\|Metabolism=
			\|Biological Activity=Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously.[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485\|{{RelationTable/GetFirstAuthor\|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]][[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365\|{{RelationTable/GetFirstAuthor\|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]. It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100\|{{RelationTable/GetFirstAuthor\|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]].
	}}		}}

	{{Lipid/Footer}}		{{Lipid/Footer}}

← Older revision		Revision as of 13:19, 17 March 2010
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	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in ~~etoh~~)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in ethanol)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm

← Older revision		Revision as of 19:00, 25 February 2010
Line 10:		Line 10:
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^{-1}; trans, trans, cis isomer: 992-983cm^{-1}, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^{-1}
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm
	\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25		\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: ~~lambdamax~~=233nm, trans, trans, cis isomer: ~~lambdamax~~=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambda max=233nm, trans, trans, cis isomer: lambda max=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1
	\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm

← Older revision		Revision as of 23:00, 19 February 2010
Line 9:		Line 9:
	\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&		\|Common Name=&&13-Hydroperoxy-9,11,15-Octadecatrienoic Acid&&13-Hydroperoxy-9,11,15-Octadecatrienoate&&
	\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]		\|Mass Spectra=EI-MS(Me-ester; after reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]][[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]]: m/e=243[O=CH(CH2)11C(=OH)OCH3]; 214[CH2(CH2)10C(=OH)OCH3]; 211[O=CH(CH2)11C=O], GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234\|{{RelationTable/GetFirstAuthor\|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]]: m/e=380[M]; 365[M-CH3]; 311[SMTO=CH-CH=CH-CH=CH-(CH2)7-COOCH3]
	\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: ~~<FONT FACE="Symbol">l</FONT>max~~=233nm, trans, trans, cis isomer: ~~<FONT FACE="Symbol">l</FONT>max~~=232nm		\|UV Spectra=(Me-ester; after reduction; in etoh)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]], cis, trans, cis isomer: lambdamax=233nm, trans, trans, cis isomer: lambdamax=232nm
	\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm~~<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=~~-1~~>1</FONT></SUP>~~; trans, trans, cis isomer: 992-983cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~, (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm~~<SUP><FONT SIZE=~~-1~~>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>~~		\|IR Spectra=(Me-ester; after reduction)[[Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Levett_G:,Lipids,1977,12,837}}]][[Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:Neff_WE:Rohwedder_WK:Khambay_BPS:Garwood_RF:Weedon_BCL:,Lipids,1977,12,1055}}]], cis, trans, cis isomer: 989-983 and 950-945cm^- ^1 ; trans, trans, cis isomer: 992-983cm^- ^1 , (Me-ester)[[Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84\|{{RelationTable/GetFirstAuthor\|Reference:Toyoda_I:Terao_J:Matsushita_S:,Lipids,1982,17,84}}]], OOH group: 3400cm^- ^1
	\|NMR Spectra=~~<SUP><FONT SIZE=-1>~~1~~</FONT></SUP>~~H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ~~<SUP><FONT SIZE=-~~1~~>1</FONT></SUP>~~H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm		\|NMR Spectra=^1 H-NMR(cis,trans,cis-isomer)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.95ppm; C11: 6.54ppm; C12: 5.54ppm; C13: 4.38ppm; J10-11=11Hz; J11-12=15Hz[C11-12: trans]; J12-13=8Hz ^1 H-NMR(cis,trans,cis-isomer; after reduction)[[Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191\|{{RelationTable/GetFirstAuthor\|Reference:Gardner_HW:Weisleder_D:,Lipids,1972,7,191}}]]: C10: 5.94ppm; C11: 6.49ppm; C12: 5.64ppm; C13: 4.20ppm
	\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25		\|Source=Auto oxidation of linoleate<!--8029--><!--8022--><!--8023--><!--8021-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->[[Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21\|{{RelationTable/GetFirstAuthor\|Reference:Chan_HWS:Coxon_DT:Peers_KE:Price_KR:,Food Chemistry,1982,9,21}}]]. Oxidation of linoleate by singlet oxygen<!--8022--><!--8023-->[[Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1980,19,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1983,22,1}}]][[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197\|{{RelationTable/GetFirstAuthor\|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8027--><!--8030-->. Reaction products between linoleate and soy bean lipoxygenase(pH:8.7,25
	\|Chemical Synthesis=		\|Chemical Synthesis=