https://lipidbank.jp/mediawiki/index.php?action=history&feed=atom&title=LBF20406CV10 2026-04-30T20:09:49Z Revision history for this page on the wiki MediaWiki 1.43.0 https://lipidbank.jp/mediawiki/index.php?title=LBF20406CV10&diff=55199&oldid=prev 2010-10-21T06:01:35Z

<p></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Older revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 15:01, 21 October 2010</td> </tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l6">Line 6:</td> <td colspan="2" class="diff-lineno">Line 6:</td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidBank=XPR8006</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidBank=XPR8006</div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidMaps=LMFA03120006</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidMaps=LMFA03120006</div></td></tr> <tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>|SysName=Methyl-4R- (5-<del style="font-weight: bold; text-decoration: none;">trans,</del>7<del style="font-weight: bold; text-decoration: none;">-trans</del>) -4-acetoxy-7- [ 2S-acetoxy-2- <del style="font-weight: bold; text-decoration: none;">[</del>cis-7-acetoxy-2-octenyl<del style="font-weight: bold; text-decoration: none;">] </del>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>|SysName=Methyl-4R- (<ins style="font-weight: bold; text-decoration: none;">trans-</ins>5<ins style="font-weight: bold; text-decoration: none;">,trans</ins>-7) -4-acetoxy-7- [ 2S-acetoxy-2- <ins style="font-weight: bold; text-decoration: none;">(</ins>cis-7-acetoxy-2-octenyl<ins style="font-weight: bold; text-decoration: none;">) </ins>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td></tr> <tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>|Common Name=&amp;&amp;20-Acetoxyclavulone II&amp;&amp;Methyl-4R- (5E,7E) -4-acetoxy-7- [ 2S-acetoxy-2- <del style="font-weight: bold; text-decoration: none;">[</del>(<del style="font-weight: bold; text-decoration: none;">Z)-7</del>-acetoxy-2-octenyl<del style="font-weight: bold; text-decoration: none;">] </del>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>|Common Name=&amp;&amp;20-Acetoxyclavulone II&amp;&amp;Methyl-4R- (5E,7E) -4-acetoxy-7- [ 2S-acetoxy-2- (<ins style="font-weight: bold; text-decoration: none;">7Z</ins>-acetoxy-2-octenyl<ins style="font-weight: bold; text-decoration: none;">) </ins>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Optical=[ alpha ]_D  +3.7°(C 0.54, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Optical=[ alpha ]_D  +3.7°(C 0.54, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]</div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.</div></td></tr> </table>

Editor https://lipidbank.jp/mediawiki/index.php?title=LBF20406CV10&diff=55198&oldid=prev 2010-09-16T09:05:20Z

<p>New page: {{Lipid/Header}} {{Hierarchy|{{PAGENAME}}}} {{Metabolite |LipidBank=XPR8006 |LipidMaps=LMFA03120006 |SysName=Methyl-4R- (5-trans,7-trans) -4-acetoxy-7- [ 2S-acetoxy-2- [cis-7-acetoxy-2-o...</p> <p><b>New page</b></p><div>{{Lipid/Header}}<br /> <br /> {{Hierarchy|{{PAGENAME}}}}<br /> <br /> {{Metabolite<br /> |LipidBank=XPR8006<br /> |LipidMaps=LMFA03120006<br /> |SysName=Methyl-4R- (5-trans,7-trans) -4-acetoxy-7- [ 2S-acetoxy-2- [cis-7-acetoxy-2-octenyl] -5-oxo-3-cyclopentenylidene ] -5-heptenoic acid<br /> |Common Name=&amp;&amp;20-Acetoxyclavulone II&amp;&amp;Methyl-4R- (5E,7E) -4-acetoxy-7- [ 2S-acetoxy-2- [(Z)-7-acetoxy-2-octenyl] -5-oxo-3-cyclopentenylidene ] -5-heptenoic acid<br /> |Optical=[ alpha ]_D +3.7°(C 0.54, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.<br /> |UV Spectra= lambda _{max}(EtOH) 230 nm( epsilon 14200),292 nm( epsilon 18700)[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |IR Spectra= nu _{max}(film)1730,1700,1640,and 1235cm^{-1}[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |NMR Spectra=^1 H-NMR(270MHz,CDCl_3 ) delta ppm2.05(3H,s),2.07(3H,s),2.08(3H,s),2.38(2H,t,J=7.3Hz),2.69(1H,dd,J=7.6,16Hz),2.87(1H,dd,J=7.3,16Hz),3.68(3H,s),4.04(2H,t,J=6.9Hz),5.20(1H,m),5.41(1H,q,J=7Hz),5.51(1H,dt,J=11,7.3Hz),6.03(1H,dd,J=7,14.8Hz),6.41(1H,d,J=6.9Hz),6.74(1H,dd,J=12.2,14.8Hz),6.86(1H,d,J=12.2Hz),7.47(1H,d,J=5.9Hz).[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]^{13}C-NMR(67.8MHz,CDCl_3 ) delta ppm21.0(q,2C),21.2(q),25.6(t),27.3(t),28.5(t),29.2(t,2C),29.5(t),36.0(t),51.8(q),64.4(t),72.8(d),85.0(s),121.5(d),126.8(d),129.3(d),134.5(d),135.0(d),136.8(s),141.3(d),158.1(d),169.5(s),169.9(s),171.2(s),172.9(s),193.3(s).[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |NOTE Spectra=CD lambda _{ext}(EtOH)( Delta epsilon )nm 247(+2.6),295(-1.0).[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]][[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Source=20-Acetoxyclavulones were isolated from Japanese soft coral, Stolonifer Clavularia viridis Quoy and Gaimard.[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Chemical Synthesis=<br /> |Metabolism=<br /> |Biological Activity=20-Acetoxyclavulones showed a significant anti-inflammatory effect at 30 mu g/ml by the fertile egg test.[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]]<br /> |Other Spectra=CD lambda _{ext}(EtOH)( Delta epsilon )nm 247(+2.6),295(-1.0).[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]][[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> }}<br /> <br /> {{Lipid/Footer}}</div>

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