https://lipidbank.jp/mediawiki/index.php?action=history&feed=atom&title=LBF20406CV11 2026-04-30T20:09:49Z Revision history for this page on the wiki MediaWiki 1.43.0 https://lipidbank.jp/mediawiki/index.php?title=LBF20406CV11&diff=55201&oldid=prev 2010-10-21T06:02:04Z

<p></p> <table style="background-color: #fff; color: #202122;" data-mw="interface"> <col class="diff-marker" /> <col class="diff-content" /> <col class="diff-marker" /> <col class="diff-content" /> <tr class="diff-title" lang="en"> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Older revision</td> <td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revision as of 15:02, 21 October 2010</td> </tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l6">Line 6:</td> <td colspan="2" class="diff-lineno">Line 6:</td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidBank=XPR8007</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidBank=XPR8007</div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidMaps=LMFA03120007</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|LipidMaps=LMFA03120007</div></td></tr> <tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>|SysName=Methyl-4R- (5-<del style="font-weight: bold; text-decoration: none;">trans,</del>7<del style="font-weight: bold; text-decoration: none;">-cis</del>) -4-acetoxy-7- [ 2S-acetoxy-2- <del style="font-weight: bold; text-decoration: none;">[</del>cis-7-acetoxy-2-octenyl<del style="font-weight: bold; text-decoration: none;">] </del>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>|SysName=Methyl-4R- (<ins style="font-weight: bold; text-decoration: none;">trans-</ins>5<ins style="font-weight: bold; text-decoration: none;">,cis</ins>-7) -4-acetoxy-7- [ 2S-acetoxy-2- <ins style="font-weight: bold; text-decoration: none;"> (</ins>cis-7-acetoxy-2-octenyl<ins style="font-weight: bold; text-decoration: none;">) </ins>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td></tr> <tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>|Common Name=&amp;&amp;20-Acetoxyclavulone III&amp;&amp;Methyl-4R- (5E,7Z) -4-acetoxy-7- [ 2S-acetoxy-2- <del style="font-weight: bold; text-decoration: none;">[</del>(<del style="font-weight: bold; text-decoration: none;">Z)-7</del>-acetoxy-2-octenyl<del style="font-weight: bold; text-decoration: none;">] </del>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>|Common Name=&amp;&amp;20-Acetoxyclavulone III&amp;&amp;Methyl-4R- (5E,7Z) -4-acetoxy-7- [ 2S-acetoxy-2- (<ins style="font-weight: bold; text-decoration: none;">7Z</ins>-acetoxy-2-octenyl<ins style="font-weight: bold; text-decoration: none;">) </ins>-5-oxo-3-cyclopentenylidene ] -5-heptenoic acid<ins style="font-weight: bold; text-decoration: none;">&amp;&amp;</ins></div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Optical=[ alpha ]_D  +26.4°(C 0.86, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Optical=[ alpha ]_D  +26.4°(C 0.86, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]</div></td></tr> <tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>|Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.</div></td></tr> </table>

Editor https://lipidbank.jp/mediawiki/index.php?title=LBF20406CV11&diff=55200&oldid=prev 2010-09-16T09:06:35Z

<p>New page: {{Lipid/Header}} {{Hierarchy|{{PAGENAME}}}} {{Metabolite |LipidBank=XPR8007 |LipidMaps=LMFA03120007 |SysName=Methyl-4R- (5-trans,7-cis) -4-acetoxy-7- [ 2S-acetoxy-2- [cis-7-acetoxy-2-oct...</p> <p><b>New page</b></p><div>{{Lipid/Header}}<br /> <br /> {{Hierarchy|{{PAGENAME}}}}<br /> <br /> {{Metabolite<br /> |LipidBank=XPR8007<br /> |LipidMaps=LMFA03120007<br /> |SysName=Methyl-4R- (5-trans,7-cis) -4-acetoxy-7- [ 2S-acetoxy-2- [cis-7-acetoxy-2-octenyl] -5-oxo-3-cyclopentenylidene ] -5-heptenoic acid<br /> |Common Name=&amp;&amp;20-Acetoxyclavulone III&amp;&amp;Methyl-4R- (5E,7Z) -4-acetoxy-7- [ 2S-acetoxy-2- [(Z)-7-acetoxy-2-octenyl] -5-oxo-3-cyclopentenylidene ] -5-heptenoic acid<br /> |Optical=[ alpha ]_D +26.4°(C 0.86, CHCl_3 )[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Solubility=20-Acetoxyclavulones are soluble in MeOH, EtOH, CHCl_3 , or hexane.<br /> |UV Spectra= lambda _{max}(EtOH) 230 nm( epsilon 12400),295 nm( epsilon 12100)[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |IR Spectra= nu _{max}(film)1730,1695,1640,and 1235cm^{-1}[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |NMR Spectra=^1 H-NMR(270MHz,CDCl_3 ) delta ppm2.02(3H,s),2.05(3H,s),2.10(3H,s),2.39(2H,t,J=7.6Hz),2.62(1H,dd,J=7.6,14.2Hz),2.87(1H,dd,J=7.3,14.2Hz),3.68(3H,s),4.04(2H,t,J=6.9Hz),5.21(1H,m),5.44(1H,q,J=5.9Hz),5.51(1H,m),6.03(1H,dd,J=5.9,15.5Hz),6.36(1H,d,J=6.3Hz),6.52(1H,d,J=11.2Hz),7.50(1H,d,J=6.3Hz),7.47(1H,dd,J=11.2,15.5Hz).[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]^{13}C-NMR(67.8MHz,CDCl_3 ) delta ppm21.0(q,2C),21.7(q),25.6(t),27.3(t),28.5(t),29.0(t),29.2(t),29.8(t),35.6(t),51.7(q),64.4(t),72.5(d),85.2(s),121.8(d),126.4(d),133.5(d),134.2(d),135.6(s),136.9(d),141.1(d),156.0(d),169.9(s),170.1(s),171.2(s),173.1(s),194.0(s).[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |NOTE Spectra=CD lambda _{ext}(EtOH)( Delta epsilon )nm 243(+2.5),291(-0.6).[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]][[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Source=20-Acetoxyclavulones were isolated from Japanese soft coral, Stolonifer Clavularia viridis Quoy and Gaimard.[[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> |Chemical Synthesis=<br /> |Metabolism=<br /> |Biological Activity=20-Acetoxyclavulones showed a significant anti-inflammatory effect at 30 mu g/ml by the fertile egg test.[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]]<br /> |Other Spectra=CD lambda _{ext}(EtOH)( Delta epsilon )nm 243(+2.5),291(-0.6).[[Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220|{{RelationTable/GetFirstAuthor|Reference:Kikuchi_H:Tsukitani_Y:Iguchi_K:Yamada_Y:,Tennen Yuki Kagoubutsu Toronkai Koen Yoshishu 26th,1983,26,220}}]][[Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433|{{RelationTable/GetFirstAuthor|Reference:Iguchi_K:Yamada_Y:Kikuchi_H:Tsukitani_Y:,Tetrahedron Lett.,1983,24,4433}}]]<br /> }}<br /> <br /> {{Lipid/Footer}}</div>

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