https://lipidbank.jp/mediawiki/index.php?action=history&feed=atom&title=LBF20406HP08 2026-05-30T17:44:05Z Revision history for this page on the wiki MediaWiki 1.43.0 https://lipidbank.jp/mediawiki/index.php?title=LBF20406HP08&diff=55645&oldid=prev 2010-10-27T06:45:56Z

<p>New page: {{Lipid/Header}} {{Hierarchy|{{PAGENAME}}}} {{Metabolite |LipidBank=DFA8087 |LipidMaps=LMFA03060046 |SysName=5,12-Dihydroperoxy-6,8,10,14-eicosatetraenoic acid |Common Name=&amp;&amp;5,12-Dihydr...</p> <p><b>New page</b></p><div>{{Lipid/Header}}<br /> <br /> {{Hierarchy|{{PAGENAME}}}}<br /> <br /> {{Metabolite<br /> |LipidBank=DFA8087<br /> |LipidMaps=LMFA03060046<br /> |SysName=5,12-Dihydroperoxy-6,8,10,14-eicosatetraenoic acid<br /> |Common Name=&amp;&amp;5,12-Dihydroperoxy-6,8,10,14-eicosatetraenoic acid&amp;&amp;<br /> |Mass Spectra=GC-EI-MS(Me-ester;after reduction, hydrogenation and TMS-derivatization)[[Reference:Yamagata_S:Murakami_H:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1983,47,2791|{{RelationTable/GetFirstAuthor|Reference:Yamagata_S:Murakami_H:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1983,47,2791}}]][[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]]: m/e=487[M-CH3]; 401[M-(CH2)3COOCH3]; 389[M-(CH2)7CH3]; 311[401- HOTMS]; 299[389-HOTMS]; 215[SMTO=CH(CH2)7CH3]; 203[SMTO=CH(CH2)3COOCH3]<br /> |UV Spectra=UV(Me-ester)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]] conjugated triene: 270nm and 281nm<br /> |IR Spectra=IR(Me-ester)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]] OOH group: 3400cm^{-1}<br /> |NMR Spectra=^1 H-NMR(Me-ester)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]]OOH: 8.3ppm<br /> |Source=Autooxidation of arachidonic acid[[Reference:Yamagata_S:Murakami_H:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1983,47,2791|{{RelationTable/GetFirstAuthor|Reference:Yamagata_S:Murakami_H:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1983,47,2791}}]]. In degradation products of 12-hydroperoxides of arachidonic acid in the presence of Fe(III)-ascorbic acid. Oxidation of arachidonic acid by singlet-oxygen[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]]. It is produced enzymatically from 5- or 12-HPETE in vivo(5,12-DHPETE)&lt;!--8103--&gt;&lt;!--8104--&gt;.<br /> |Chemical Synthesis=<br /> |Metabolism=<br /> }}<br /> <br /> {{Lipid/Footer}}</div>

Editor