LBF18206HP02: Difference between revisions
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|LipidBank=DFA8003 | |LipidBank=DFA8003 | ||
|LipidMaps=LMFA01040006 | |LipidMaps=LMFA01040006 | ||
|SysName=10-Hydroperoxy-8,12- | |SysName=10-Hydroperoxy-8,12-octadecadienoic acid | ||
|Common Name=&&10-Hydroperoxy-8,12- | |Common Name=&&10-Hydroperoxy-8,12-octadecadienoate&&10-Hydroperoxy-8,12-octadecadienoic acid&& | ||
|Mass Spectra=GC-EI-MS(after methanolysis, reduction and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961}}]]: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100|{{RelationTable/GetFirstAuthor|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]]:m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]] | |Mass Spectra=GC-EI-MS(after methanolysis, reduction and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961}}]]: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100|{{RelationTable/GetFirstAuthor|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]]:m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]] | ||
|IR Spectra=After methanolyzation and reduction[[Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544|{{RelationTable/GetFirstAuthor|Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544}}]][[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]]: isolated double bond (3013-3010, 972-971cm^{-1}) | |IR Spectra=After methanolyzation and reduction[[Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544|{{RelationTable/GetFirstAuthor|Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544}}]][[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]]: isolated double bond (3013-3010, 972-971cm^{-1}) |
Revision as of 06:29, 14 April 2010
LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
IDs and Links | |
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LipidBank | DFA8003 |
LipidMaps | LMFA01040006 |
CAS | |
KEGG | {{{KEGG}}} |
KNApSAcK | {{{KNApSAcK}}} |
mol | LBF18206HP02 |
10-Hydroperoxy-8,12-octadecadienoate | |
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Structural Information | |
10-Hydroperoxy-8,12-octadecadienoic acid | |
| |
Formula | C18H32O4 |
Exact Mass | 312.23005951199997 |
Average Mass | 312.44428 |
SMILES | CCCCCC=CCC(OO)C=CCCCCCCC(O)=O |
Physicochemical Information | |
Oxidation of methyl linoleate by singlet oxygen Logani_MK et al. Sevanian_A et al. Fujimoto_K . | |
Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously. Logani_MK et al. Sevanian_A et al. Fujimoto_K | |
Spectral Information | |
Mass Spectra | GC-EI-MS(after methanolysis, reduction and trimethylsilylation) TeraoJet al. Frankel_EN et al.: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation) Chan_HWS :m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation) TeraoJet al. |
UV Spectra | |
IR Spectra | After methanolyzation and reduction Thomas_MJ et al. TeraoJet al.: isolated double bond (3013-3010, 972-971cm-1) |
NMR Spectra | 1H-NMR(after methanolyzation and reduction) Thomas_MJ et al.: olefinic protons(5.55-5.59ppm), C10 (4.08-4.11ppm) |
Other Spectra | |
Chromatograms |
Reported Metabolites, References | ||||||||||||||||||||||||||||||||||||||||
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