LBF20406HO22: Difference between revisions
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|NMR Spectra=8(S)-ISOMER METHYL ESTER ; <SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>) : <FONT FACE=""Symbol"">d</FONT> 6.56(dd, J=14.5, 11.1Hz, 1H, 10-CH), 6.00(brt, J=11.1, 9.7Hz, 1H, 11-CH), 5.72(dd, J=7.3, 14.5Hz, 1H, 9-CH), 5.59-5.16(m, 5H), 4.23(q, 1H,8-CH), 3.71(s, 3H,OCH<SUB><FONT SIZE=-1>3</FONT></SUB>), 2.95(t, 2H,13-CH), 2.35(t, 4H, 4,7-CH), 2.11(sextet, 4H), 1.73(pentet, 2H, 3-CH), 1.56(brs, S, 1H, OH), 1.32(m, 6H), 0.91(t, 3H, 20-CH) [[Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039|{{RelationTable/GetFirstAuthor|Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039}}]] | |NMR Spectra=8(S)-ISOMER METHYL ESTER ; <SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>) : <FONT FACE=""Symbol"">d</FONT> 6.56(dd, J=14.5, 11.1Hz, 1H, 10-CH), 6.00(brt, J=11.1, 9.7Hz, 1H, 11-CH), 5.72(dd, J=7.3, 14.5Hz, 1H, 9-CH), 5.59-5.16(m, 5H), 4.23(q, 1H,8-CH), 3.71(s, 3H,OCH<SUB><FONT SIZE=-1>3</FONT></SUB>), 2.95(t, 2H,13-CH), 2.35(t, 4H, 4,7-CH), 2.11(sextet, 4H), 1.73(pentet, 2H, 3-CH), 1.56(brs, S, 1H, OH), 1.32(m, 6H), 0.91(t, 3H, 20-CH) [[Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039|{{RelationTable/GetFirstAuthor|Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039}}]] | ||
|Source= | |Source= | ||
|Chemical Synthesis=[[Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039|{{RelationTable/GetFirstAuthor|Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039}}]];> {{Image200| | |Chemical Synthesis=[[Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039|{{RelationTable/GetFirstAuthor|Reference:Yadagiri_P:Lumin_S:Mosset_P:Capdevila_J:Falck_JR:,Tetrah. Lett.,1986,27,6039}}]];> {{Image200|LBF20406HO22FT0001.gif}} | ||
|Metabolism= | |Metabolism= | ||
}} | }} | ||
{{Lipid/Footer}} | {{Lipid/Footer}} | ||
Revision as of 10:00, 25 November 2009
| LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
| IDs and Links | |
|---|---|
| LipidBank | XPR6114 |
| LipidMaps | LMFA03060021 |
| CAS | |
| KEGG | {{{KEGG}}} |
| KNApSAcK | {{{KNApSAcK}}} |
| mol | LBF20406HO22 |
| (R) , (Z,E,Z,Z) -8-Hydroxy-5,9,11,14-eicosatetraenoic acid | |
|---|---|
| |
| Structural Information | |
| (R) , (Z,E,Z,Z) -8-Hydroxy-5,9,11,14-eicosatetraenoic acid | |
| |
| Formula | C20H32O3 |
| Exact Mass | 320.23514489 |
| Average Mass | 320.46628 |
| SMILES | C(CC=CCC=CC=C[C@H](CC=CCCCC(O)=O)O)CCC |
| Physicochemical Information | |
| ETHYL ACETATE Bundy_GL et al. | |
Yadagiri_P et al.;>  | |
| Spectral Information | |
| Mass Spectra | METHYL ESTER, TMS ETHER ; m/e 265 Bundy_GL et al.. 8(S)-ISOMER METHYL ESTER TMS ETHER ; m/e 406, 391, 316, 265, 243 YadagiriPet al. |
| UV Spectra | METHYL ESTER ; l max = 235.8nm (e 28,000) Bundy_GL et al. |
| IR Spectra | |
| NMR Spectra | 8(S)-ISOMER METHYL ESTER ; 1H-NMR(CDCl3) : d 6.56(dd, J=14.5, 11.1Hz, 1H, 10-CH), 6.00(brt, J=11.1, 9.7Hz, 1H, 11-CH), 5.72(dd, J=7.3, 14.5Hz, 1H, 9-CH), 5.59-5.16(m, 5H), 4.23(q, 1H,8-CH), 3.71(s, 3H,OCH3), 2.95(t, 2H,13-CH), 2.35(t, 4H, 4,7-CH), 2.11(sextet, 4H), 1.73(pentet, 2H, 3-CH), 1.56(brs, S, 1H, OH), 1.32(m, 6H), 0.91(t, 3H, 20-CH) YadagiriPet al. |
| Other Spectra | |
| Chromatograms | |
| Reported Metabolites, References | ||||||||||||||||||||
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