LBF20406LT01: Difference between revisions
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|SysName=5 (S) ,6 (S) -Epoxyeicosa-7 (E) ,9 (E) ,11 (Z) ,14 (Z) -tetraenoic acid | |SysName=5 (S) ,6 (S) -Epoxyeicosa-7 (E) ,9 (E) ,11 (Z) ,14 (Z) -tetraenoic acid | ||
|Common Name=&&LEUKOTRIENE A4&& | |Common Name=&&LEUKOTRIENE A4&& | ||
|Reflactive=[<FONT FACE="Symbol">a</FONT>]X<sub>D</sub><sup>25</sup>=-21.9°(C=0.32,CYCLOHEXANE) | |Reflactive=[<FONT FACE="Symbol">a</FONT>]X<sub>D</sub><sup>25</sup>=-21.9°(C=0.32,CYCLOHEXANE) [[Reference:Corey_EJ:Clark_DA:Goto_G:Marfat_A:Mioskowski_C:Samuelsson_B:Hammarstroem_S:,J. Am. Chem. Soc.,1980,102,1436|{{RelationTable/GetFirstAuthor|Reference:Corey_EJ:Clark_DA:Goto_G:Marfat_A:Mioskowski_C:Samuelsson_B:Hammarstroem_S:,J. Am. Chem. Soc.,1980,102,1436}}]] | ||
|Solubility=SOL. IN CYCLOHEXANE,METHANOL | |Solubility=SOL. IN CYCLOHEXANE,METHANOL[[Reference:Corey_EJ:Clark_DA:Goto_G:Marfat_A:Mioskowski_C:Samuelsson_B:Hammarstroem_S:,J. Am. Chem. Soc.,1980,102,1436|{{RelationTable/GetFirstAuthor|Reference:Corey_EJ:Clark_DA:Goto_G:Marfat_A:Mioskowski_C:Samuelsson_B:Hammarstroem_S:,J. Am. Chem. Soc.,1980,102,1436}}]]. STABILITIES : to decompose to 5,12-DIHYDROXY-6,8,10,14-EICOSATETRAENOIC ACID and 5,6-DIHYDROXY-7,9,11,14-EICOSATETRAENOIC ACID under neutral aqueous solution at 37°C with one minite of half-life[[Reference:Borgeat_P:Samuelsson_B:,Proc. Natl. Acad. Sci. U. S. A.,1979,76,3213|{{RelationTable/GetFirstAuthor|Reference:Borgeat_P:Samuelsson_B:,Proc. Natl. Acad. Sci. U. S. A.,1979,76,3213}}]]. | ||
|Mass Spectra=METHYL ESTER ; 332(M<SUP><FONT SIZE=-1>+</FONT></SUP>), 316, 300, 221, 189, 181, 129, 101 | |Mass Spectra=METHYL ESTER ; 332(M<SUP><FONT SIZE=-1>+</FONT></SUP>), 316, 300, 221, 189, 181, 129, 101 [[Reference:Mckay_SW:Mallen_DNB:Shrubasall_PR:Smith_JM:Baker_SR:Jamieson_WB:Ross_WJ:Morgan_SE:Rackham_DM:,J. Chromatogr. A,1981,214,249|{{RelationTable/GetFirstAuthor|Reference:Mckay_SW:Mallen_DNB:Shrubasall_PR:Smith_JM:Baker_SR:Jamieson_WB:Ross_WJ:Morgan_SE:Rackham_DM:,J. Chromatogr. A,1981,214,249}}]] | ||
|UV Spectra=METHYL ESTER ; <FONT FACE="Symbol">l</FONT> <SUP><FONT SIZE=-1>M</FONT></SUP><SUP><FONT SIZE=-1>e</FONT></SUP><SUP><FONT SIZE=-1>O</FONT></SUP><SUP><FONT SIZE=-1>H</FONT></SUP><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB> = 269(<FONT FACE="Symbol">e</FONT> 30,500), 278(<FONT FACE="Symbol">e</FONT> 40,000), 287(<FONT FACE="Symbol">e</FONT> 34,400) nm | |UV Spectra=METHYL ESTER ; <FONT FACE="Symbol">l</FONT> <SUP><FONT SIZE=-1>M</FONT></SUP><SUP><FONT SIZE=-1>e</FONT></SUP><SUP><FONT SIZE=-1>O</FONT></SUP><SUP><FONT SIZE=-1>H</FONT></SUP><SUB><FONT SIZE=-1>m</FONT></SUB><SUB><FONT SIZE=-1>a</FONT></SUB><SUB><FONT SIZE=-1>x</FONT></SUB> = 269(<FONT FACE="Symbol">e</FONT> 30,500), 278(<FONT FACE="Symbol">e</FONT> 40,000), 287(<FONT FACE="Symbol">e</FONT> 34,400) nm [[Reference:Corey_EJ:Arai_Y:Mioskowski_C:,J. Am. Chem. Soc.,1979,101,6748|{{RelationTable/GetFirstAuthor|Reference:Corey_EJ:Arai_Y:Mioskowski_C:,J. Am. Chem. Soc.,1979,101,6748}}]] | ||
}} | }} | ||
Revision as of 00:00, 12 December 2008
| IDs and Links | |
|---|---|
| LipidBank | XPR3001 |
| LipidMaps | LMFA03020023 |
| CAS | |
| KEGG | {{{KEGG}}} |
| KNApSAcK | {{{KNApSAcK}}} |
| mol | LBF20406LT01 |
| LEUKOTRIENE A4 | |
|---|---|
| |
| Structural Information | |
| 5 (S) ,6 (S) -Epoxyeicosa-7 (E) ,9 (E) ,11 (Z) ,14 (Z) -tetraenoic acid | |
| |
| Formula | C20H30O3 |
| Exact Mass | 318.21949482599996 |
| Average Mass | 318.4504 |
| SMILES | C(CC=CCC=CC=CC=C[C@@H](O1)[C@@H]1CCCC(O)=O)CCC |
| Physicochemical Information | |
| SOL. IN CYCLOHEXANE,METHANOL Corey_EJ et al.. STABILITIES : to decompose to 5,12-DIHYDROXY-6,8,10,14-EICOSATETRAENOIC ACID and 5,6-DIHYDROXY-7,9,11,14-EICOSATETRAENOIC ACID under neutral aqueous solution at 37°C with one minite of half-life BorgeatPet al.. | |
| Spectral Information | |
| Mass Spectra | METHYL ESTER ; 332(M+), 316, 300, 221, 189, 181, 129, 101 Mckay_SW et al. |
| UV Spectra | METHYL ESTER ; l MeOHmax = 269(e 30,500), 278(e 40,000), 287(e 34,400) nm Corey_EJ et al. |
| IR Spectra | |
| NMR Spectra | |
| Other Spectra | |
| Chromatograms | |
| Reported Metabolites, References | |||||||||||||||||||||||||||||||||||||||||||||
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