LBG01gcc:g:R:R: Difference between revisions

Latest revision as of 21:00, 14 April 2010

Seminolipid

Structural Information
	1 [ (S3) Galb1 ] -2Ak-3Ay-sn-Gro
	Seminolipid sulfogalactoglycerolipid

Formula	C10H27O7R1R2S
Exact Mass	383.13104890799997
Average Mass	383.36648
SMILES	`O`
Physicochemical Information





	Sol in pyridine insol in diethylether sol in hot methanol but precipitates on cooling to ambient temperature <<0058>> Behavior in the Folch partition <<0027>>.






Spectral Information
Mass Spectra	Galactosyl-alkylGro <<0065>> , SI-MS <<0036>>,
UV Spectra
IR Spectra	1735cm^-1 ester carbonyl <<0058>> 1240cm^-1 C-O-S <<0058>> ,820cm^-1 equatorial C-O-S <<0058>> 875cm^-1 type 2b ( β ) <<0058>> , diacyl species: 1720cm^-1 is larger <<0061>>
NMR Spectra	CDCl3/CD3OD, 2:1(v/v) 35 OR 60,
Other Spectra
Chromatograms	Silicagel TLC <<>>,

Reported Metabolites, References

Biospecies	ID	Compound Name	Reference
n.a.	LBG01gcc:g:R:R	See above.	Burkart_T et al. 1983
n.a.	LBG01gcc:g:R:R	See above.	Burkart_T et al. 1983
n.a.	LBG01gcc:g:R:R	See above.	Farooqui_AA 1987
n.a.	LBG01gcc:g:R:R	See above.	Farooqui_AA 1983
n.a.	LBG01gcc:g:R:R	See above.	Flynn_TJ et al. 1975
n.a.	LBG01gcc:g:R:R	See above.	Ishizuka_I 1998
n.a.	LBG01gcc:g:R:R	See above.	Ishizuka_I et al. 1979
n.a.	LBG01gcc:g:R:R	See above.	Ishizuka_I et al. 1978
n.a.	LBG01gcc:g:R:R	See above.	Ishizuka_I et al. 1973
n.a.	LBG01gcc:g:R:R	See above.	Kornblatt_MJ et al. 1974
n.a.	LBG01gcc:g:R:R	See above.	Levine_M et al. 1975
n.a.	LBG01gcc:g:R:R	See above.	Levy_RJ et al. 1968
n.a.	LBG01gcc:g:R:R	See above.	Lingwood_C et al. 1981
n.a.	LBG01gcc:g:R:R	See above.	Lingwood_CA 1985
n.a.	LBG01gcc:g:R:R	See above.	Selivonchick_DP et al. 1980
n.a.	LBG01gcc:g:R:R	See above.	Suzuki_A et al. 1977
n.a.	LBG01gcc:g:R:R	See above.	Suzuki_A et al. 1973
n.a.	LBG01gcc:g:R:R	See above.	Tadano-Aritomi_K et al. 1983
n.a.	LBG01gcc:g:R:R	See above.	Tamai_Y et al. 1993

@@ Line 4: / Line 4: @@
 |LipidBank=GGG0091
 |SysName=1 [  (S3) Galb1 ] -2Ak-3Ay-sn-Gro
-|Common Name=&&Seminolipid&&sulfogalactoglycerolipid &&1 [  (S3) Galb1 ] -2Ak-3Ay-sn-Gro&&
+|Common Name=&&Seminolipid&&sulfogalactoglycerolipid&&
-|Reflactive=[alpha]23/D = +2.78(C=1.44 IN C/M 1:1),[alpha]/D =0 (C=,0.39 IN C/M 1:1) <<0059>>.
+|Reflactive=[ alpha ]23/D = +2.78(C=1.44 IN C/M 1:1),[ alpha ]/D =0 (C=,0.39 IN C/M 1:1) <<0059>>.
 |Solubility=Sol in pyridine insol in diethylether sol in hot methanol but precipitates on cooling to ambient temperature <<0058>> Behavior in the Folch partition <<0027>>.
 |Mass Spectra=Galactosyl-alkylGro <<0065>> , SI-MS <<0036>>,
-|IR Spectra=1735cm^- ^1  ester carbonyl <<0058>> 1240cm^- ^1  C-O-S <<0058>> ,820cm^- ^1  equatorial C-O-S <<0058>> 875cm^- ^1  type 2b (beta) <<0058>> , diacyl species: 1720cm^- ^1  is larger <<0061>>
+|IR Spectra=1735cm^{-1} ester carbonyl <<0058>> 1240cm^{-1} C-O-S <<0058>> ,820cm^{-1} equatorial C-O-S <<0058>> 875cm^{-1} type 2b ( beta ) <<0058>> , diacyl species: 1720cm^{-1} is larger <<0061>>
 |NMR Spectra=CDCl3/CD3OD, 2:1(v/v) 35 OR 60,
 |NOTE Spectra=The visual color absorption of the Azure A complex <<0027>>,