LBGPEccp:R:R:YB2ANe001: Difference between revisions

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|LipidBank=PGP2401
|LipidBank=PGP2401
|SysName=1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine
|SysName=1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine
|Common Name=phosphatidyl-N-methylethanolamine N-methylphosphatidylethanolaminephosphatidyl-N-monomethylethanolamine1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine
|Common Name=&&phosphatidyl-N-methylethanolamine&& N-methylphosphatidylethanolamine&&phosphatidyl-N-monomethylethanolamine&&1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine&&
|Melting Point=1,2-distearoyl-L-N-methylphosphatidylethanolamine, 178-180°C 2412; 1,2-distearoyl-DL-N-methylphosphatidylethanolamine, 171-172°C 2412; 1,2-dipalmitoyl-L-N-methylphosphatidylethanolamine, 177-178°C 2412, 184-186°C (from CHClSUBFONT SIZE=-13/FONT/SUB-MeOH at 4°C 2413; 1,2-dipalmitoyl-DL-N-methylphosphatidylethanolamine, 170-171°C 2412, 182°C 2413
|Melting Point=1,2-distearoyl-L-N-methylphosphatidylethanolamine, 178-180°C <<2412>>; 1,2-distearoyl-DL-N-methylphosphatidylethanolamine, 171-172°C <<2412>>; 1,2-dipalmitoyl-L-N-methylphosphatidylethanolamine, 177-178°C <<2412>>, 184-186°C (from CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>-MeOH at 4°C <<2413>>; 1,2-dipalmitoyl-DL-N-methylphosphatidylethanolamine, 170-171°C <<2412>>, 182°C <<2413>>
|Reflactive=1,2-distearoyl-L-N-methylphosphatidylethanolamine, [FONT FACE=Symbola/FONT]subD/subsup25/sup +7.1° 2412; 1,2-dipalmitoyl-L-N-methylphosphatidylethanolamine, [FONT FACE=Symbola/FONT]subD/subsup25/sup +8.0° 2412, [FONT FACE=Symbola/FONT]subD/subsup23/sup +8.0° (in CHClSUBFONT SIZE=-13/FONT/SUB) 2413
|Reflactive=1,2-distearoyl-L-N-methylphosphatidylethanolamine, [<FONT FACE="Symbol">a</FONT>]<sub>D</sub><sup>25</sup> +7.1° <<2412>>; 1,2-dipalmitoyl-L-N-methylphosphatidylethanolamine, [<FONT FACE="Symbol">a</FONT>]<sub>D</sub><sup>25</sup> +8.0° <<2412>>, [<FONT FACE="Symbol">a</FONT>]<sub>D</sub><sup>23</sup> +8.0° (in CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>) <<2413>>
|NMR Spectra=SUPFONT SIZE=-12/FONT/SUPH-NMR spectra of PC, PDME, PMME, and PE fully hydrated with DSUBFONT SIZE=-12/FONT/SUBO at the indicated temperatures {{Image200|LBGPEccp:R:R:YB2ANe001SP0001.gif}} 2410.,  
|NMR Spectra=<SUP><FONT SIZE=-1>2</FONT></SUP>H-NMR spectra of PC, PDME, PMME, and PE fully hydrated with D<SUB><FONT SIZE=-1>2</FONT></SUB>O at the indicated temperatures {{Image200|LBGPEccp:R:R:YB2ANe001SP0001.gif}} <<2410>>.,  
|Chromatograms=HPLC, FONT FACE=Symbolm/FONTBondapak NHSUBFONT SIZE=-12/FONT/SUB, acetonitril-methanol-water (13:7:1, v/v), elution rate 1.6 ml/min, detection ODSUBFONT SIZE=-12/FONT/SUBSUBFONT SIZE=-10/FONT/SUBSUBFONT SIZE=-13/FONT/SUB nm, Peaks: SF = solvent front, PC = phosphatidylcholine, SPH = sphingomyelin, LPC = lysophosphatidylcholine, PMME = phosphatidylmonomethylethanolamine, PE = phosphatidylethanolamine, PDME = phosphatidyldimethylethanolamine, LPE = lysophosphatidylethanolamine, {{Image200|LBGPEccp:R:R:YB2ANe001CH0001.gif}} 2401/BRTLC, plate: Silica gel 60 (Merck, 20 X 20 cm, 0.25 mm thick), solvent: 1st dim. chloroform - methanol - water (65:25:4, v/v), 2nd dim. n-butanol - acetic acid - water (6:2:2, v/v) 2402,  
|Chromatograms=HPLC, <FONT FACE="Symbol">m</FONT>Bondapak NH<SUB><FONT SIZE=-1>2</FONT></SUB>, acetonitril-methanol-water (13:7:1, v/v), elution rate 1.6 ml/min, detection OD<SUB><FONT SIZE=-1>2</FONT></SUB><SUB><FONT SIZE=-1>0</FONT></SUB><SUB><FONT SIZE=-1>3</FONT></SUB> nm, Peaks: SF = solvent front, PC = phosphatidylcholine, SPH = sphingomyelin, LPC = lysophosphatidylcholine, PMME = phosphatidylmonomethylethanolamine, PE = phosphatidylethanolamine, PDME = phosphatidyldimethylethanolamine, LPE = lysophosphatidylethanolamine, {{Image200|LBGPEccp:R:R:YB2ANe001CH0001.gif}} <<2401>>/<BR>TLC, plate: Silica gel 60 (Merck, 20 X 20 cm, 0.25 mm thick), solvent: 1st dim. chloroform - methanol - water (65:25:4, v/v), 2nd dim. n-butanol - acetic acid - water (6:2:2, v/v) <<2402>>,  
}}
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Revision as of 15:00, 18 February 2010

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phosphatidyl-N-methylethanolamine
LBGPEccp:R:R:YB2ANe001.png
Structural Information
1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine
  • phosphatidyl-N-methylethanolamine
  • N-methylphosphatidylethanolamine
  • phosphatidyl-N-monomethylethanolamine
  • 1,2-di-acyl-sn-glycero- (3) -phospho-N-methylethanolamine
Formula
Exact Mass
Average Mass
SMILES
Physicochemical Information
1,2-distearoyl-L-N-methylphosphatidylethanolamine, 178-180°C <<2412>>; 1,2-distearoyl-DL-N-methylphosphatidylethanolamine, 171-172°C <<2412>>; 1,2-dipalmitoyl-L-N-methylphosphatidylethanolamine, 177-178°C <<2412>>, 184-186°C (from CHCl3-MeOH at 4°C <<2413>>; 1,2-dipalmitoyl-DL-N-methylphosphatidylethanolamine, 170-171°C <<2412>>, 182°C <<2413>>
Spectral Information
Mass Spectra
UV Spectra
IR Spectra
NMR Spectra 2H-NMR spectra of PC, PDME, PMME, and PE fully hydrated with D2O at the indicated temperatures
LBGPEccp:R:R:YB2ANe001SP0001.gif
<<2410>>.,
Other Spectra
Chromatograms HPLC, mBondapak NH2, acetonitril-methanol-water (13:7:1, v/v), elution rate 1.6 ml/min, detection OD203 nm, Peaks: SF = solvent front, PC = phosphatidylcholine, SPH = sphingomyelin, LPC = lysophosphatidylcholine, PMME = phosphatidylmonomethylethanolamine, PE = phosphatidylethanolamine, PDME = phosphatidyldimethylethanolamine, LPE = lysophosphatidylethanolamine,
LBGPEccp:R:R:YB2ANe001CH0001.gif
<<2401>>/
TLC, plate: Silica gel 60 (Merck, 20 X 20 cm, 0.25 mm thick), solvent: 1st dim. chloroform - methanol - water (65:25:4, v/v), 2nd dim. n-butanol - acetic acid - water (6:2:2, v/v) <<2402>>,
Reported Metabolites, References
Biospecies ID Compound Name Reference Comment
n.a. LBGPEccp:R:R:YB2ANe001 See above. Baumann_NA et al. 1965
n.a. LBGPEccp:R:R:YB2ANe001 See above. Billimoria_JD et al. 1968
n.a. LBGPEccp:R:R:YB2ANe001 See above. Bremer_J et al. 1959
n.a. LBGPEccp:R:R:YB2ANe001 See above. Chen_SS et al. 1982
n.a. LBGPEccp:R:R:YB2ANe001:01 Chen_SS et al. 1982
n.a. LBGPEccp:R:R:YB2ANe001 See above. Cui_Z et al. 1993
n.a. LBGPEccp:R:R:YB2ANe001 See above. Hall_MO et al. 1961
n.a. LBGPEccp:R:R:YB2ANe001 See above. Hsieh_CH et al. 1995
n.a. LBGPEccp:R:R:YB2ANe001 See above. Kodaki_T et al. 1987
n.a. LBGPEccp:R:R:YB2ANe001 See above. Lester_RL et al. 1967
n.a. LBGPEccp:R:R:YB2ANe001 See above. Shapiro_D et al. 1964
n.a. LBGPEccp:R:R:YB2ANe001 See above. Slotboom_AJ et al. 1970
n.a. LBGPEccp:R:R:YB2ANe001 See above. Tanaka_Y et al. 1979
n.a. LBGPEccp:R:R:YB2ANe001 See above. Vance_DE et al. 1981