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{{Huge|Fatty acyl (脂肪酸アシル)}}
{{Huge|{{Bilingual|脂肪酸アシル|Fat acyl}}}}
{{LB/Header}}
{{Hierarchy|{{PAGENAME}}}}
{{Hierarchy|{{PAGENAME}}}}
 
{| style="float:right"
| __TOC__
|}
==Class Overview==
==Class Overview==


{{Twocolumn|
{{Twocolumn|
The fatty acyl category includes fatty acids and acyl derivatives of length more than 7.  Fatty acids with aliphatic tails of 8--14 are called medium chain fatty acids (MCFA), and those of more than 14 are called long chain fatty acids (LCFA).
The fat acyl category includes fatty acids and acyl derivatives of length more than 7.  Fatty acids with aliphatic tails of 8--14 are called medium chain fatty acids (MCFA), and those of more than 14 are called long chain fatty acids (LCFA).
For shorter ones (SCFA), please go to the [[:Category:BM|Basic Metabolites (BM)]] category.<br>
For shorter ones (SCFA), please go to the [http://metabolomics.jp/wiki/Category:BM Basic Metabolites (BM)] category.<br>


Higher fatty acids refer to those of 10 or more carbons. For definition, see [http://www.chem.qmul.ac.uk/iupac/lipid/appABC.html#appB IUPAC page].
Higher fatty acids refer to those of 10 or more carbons. For definition, see [http://www.chem.qmul.ac.uk/iupac/lipid/appABC.html#appB IUPAC page].
|
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脂肪族アシルカテゴリーは長さが8以上の脂肪酸やアシル誘導体を含んでいます。長さが8~14のものを中鎖脂肪酸(MCFA)、長さが15以上のものを長鎖脂肪酸(LCFA)といいます。
脂肪族アシルカテゴリーは長さが8以上の脂肪酸やアシル誘導体を含んでいます。長さが8~14のものを中鎖脂肪酸(MCFA)、長さが15以上のものを長鎖脂肪酸(LCFA)といいます。
短いもの(SCFA)は[[:Category:BM|基礎代謝物(BM)]]カテゴリーに登録されています。<br>
短いもの(SCFA)は[http://metabolomics.jp/wiki/Category:BM 基礎代謝物(BM)]カテゴリーに登録されています。<br>


炭素長が10以上のものは高級脂肪酸とも呼ばれます。定義は[http://www.chem.qmul.ac.uk/iupac/lipid/appABC.html#appB IUPAC]を参照してください。
炭素長が10以上のものは高級脂肪酸とも呼ばれます。定義は[http://www.chem.qmul.ac.uk/iupac/lipid/appABC.html#appB IUPAC]を参照してください。
}}
}}


===Common Abbreviations <small>よく使う略称</small>===
==={{Bilingual|よく使う略称|Abbreviations}}===
{|
{|  
|-
{{#repeatnum:LBS/AbbrevRow|1|
| SCFA || short chain fatty acids || 短鎖脂肪酸 ||: 1-7 carbons  
SCFA && short chain fatty acids && 短鎖脂肪酸 : 1-7 carbons  
|-
MCFA && medium chain fatty acids && 中鎖脂肪酸 : 8-14 carbons
| MCFA || medium chain fatty acids || 中鎖脂肪酸 ||: 8-14 carbons
LCFA && long chain fatty acids && 長鎖脂肪酸 : 15< carbons
|-
SFA  && Saturated fatty acids && 飽和脂肪酸 : no double bond
| LCFA || long chain fatty acids || 長鎖脂肪酸 ||: 15< carbons
UFA  && Unsaturated fatty acids && 不飽和脂肪酸 : with double bond(s)
|-
MUFA && monounsaturated fatty acids && 一価不飽和脂肪酸 : 1 double bond
| SFA  || Saturated fatty acids || 飽和脂肪酸 ||: no double bond
PUFA && polyunsaturated fatty acids && 多価不飽和脂肪酸 : 1< double bonds
|-
}}
| UFA  || Unsaturated fatty acids || 不飽和脂肪酸 ||: with double bond(s)
|-
| MUFA || monounsaturated fatty acids || 一価不飽和脂肪酸 ||: 1 double bond
|-
| PUFA || polyunsaturated fatty acids || 多価不飽和脂肪酸 ||: 1< double bonds
|}
|}




==Classification by Chain Length <small>鎖長による分類</small>==
=={{Bilingual|ID番号 (ページ名) の設計|Design of Fat acyl Page Titles}}==
{{Twocolumn|
Each page title contains chain-length, degree of unsaturation, position of double bonds, and backbone structure (branches, peroxidation, or prostanoids etc.).
|
各分子のページタイトルに鎖長、不飽和度、二重結合の位置、骨格タイプ(分岐や過酸化、プロスタノイドなど)がコード化されています。
}}
<center>
12-DIGIT
<table border=1>
<tr>
<td style="background-color:yellowgreen;" width=15px align="center"><big>L</big>
<td style="background-color:yellowgreen;" width=15px align="center"><big>B</big>
<td style="background-color:darkseagreen;" width=15px align="center"><big>F</big>
<td style="background-color:tomato; color:white" width=15px align="center"><big>''x''</big>
<td style="background-color:tomato; color:white" width=15px align="center"><big>''x''</big>
<td style="background-color:purple; color:white" width=15px align="center"><big>''y''</big>
<td style="background-color:firebrick; color:white" width=15px align="center"><big>''z''</big>
<td style="background-color:firebrick; color:white" width=15px align="center"><big>''z''</big>
<td style="background-color:green; color:white;" width=15px align="center"><big>''w''</big>
<td style="background-color:green; color:white" width=15px align="center"><big>''w''</big>
<td style="background-color:white;" width=15px align="center"><big>''c''</big>
<td style="background-color:white;" width=15px align="center"><big>''c''</big>
</tr>
</table>
</center>
{{Twocolumn|
* ''x'' ... carbon chain length ([[#By_Chain_Length_.E9.8E.96.E9.95.B7|See Table]])
* ''y'' ... degree of unsaturation ([[#Other_Classification_Charts_.E3.81.9D.E3.81.AE.E4.BB.96.E3.81.AE.E5.88.86.E9.A1.9E.E3.83.81.E3.83.A3.E3.83.BC.E3.83.88|See Table]])
* ''z'' ... position of n-''z'' (n minus z; also ω-z or omega-z) nomenclature ([[#Other_Classification_Charts_.E3.81.9D.E3.81.AE.E4.BB.96.E3.81.AE.E5.88.86.E9.A1.9E.E3.83.81.E3.83.A3.E3.83.BC.E3.83.88|See Table]])
* ''w'' ... structure type ([[#By_Structure_.E9.AA.A8.E6.A0.BC|See Table]])
* ''c'' ... serial number
|
* ''x'' ... 炭素鎖長 ([[#By_Chain_Length_.E9.8E.96.E9.95.B7|分類表]])
* ''y'' ... 不飽和度([[#Other_Classification_Charts_.E3.81.9D.E3.81.AE.E4.BB.96.E3.81.AE.E5.88.86.E9.A1.9E.E3.83.81.E3.83.A3.E3.83.BC.E3.83.88|分類表]])
* ''z'' ... n-''z'' (またはω-''z''やomega-''z'') における数([[#Other_Classification_Charts_.E3.81.9D.E3.81.AE.E4.BB.96.E3.81.AE.E5.88.86.E9.A1.9E.E3.83.81.E3.83.A3.E3.83.BC.E3.83.88|分類表]])
* ''w'' ... 骨格のタイプ ([[#By_Structure_.E9.AA.A8.E6.A0.BC|分類表]])
* ''c'' ... 通し番号
}}
 
==Classification <small>分類</small>==
===By Chain Length <small>鎖長</small>===
{{Twocolumn|
{{Twocolumn|
Fatty acids are extended by polymerization of malonyl CoA, and have even chain length in general.
Fatty acids are extended by polymerization of malonyl CoA, and have even chain length by default.
|
|
脂肪酸はマロニルCoAの重合によって伸張し、通常は炭素数が偶数です。長いものほど融点が高くなります。
脂肪酸はマロニルCoAの重合によって伸張し、通常は炭素数が偶数です。長いものほど融点が高くなります。
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<center>
<center>
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
|+ Table 1. Classification by Chain Length [[Image:LBF.png|120px]]  
|+ Classification by Chain Length [[Image:LBF.png|100px]]  
|- valign="top"
|- valign="top"
|align="center"|Chain length =<8<br>[[:Category:BM|BMFY: Short-chain]]<br>短鎖<br><br><br>N.A.
|align="center"|Chain length =<7<br>[[:Category:BM|BMFY: Short-chain]]<br>短鎖<br><br><br>N.A.
|align="center"|Chain length =8<br>[[Volatile:ListMol|LBF08|LBF08: Octanoid]]<br>オクタノイド {{LBF digit910Table|08}}
|align="center"|Chain length =8<br>{{#volatile:ListMol|LBF08: Octanoid|LBF08}}<br>オクタノイド <br>[[Image:LBF08.png|70px]]{{LBF digit910Table|08}}
|align="center"|Chain length =9<br>[[Volatile:ListMol|LBF09|LBF09: Nonanoid]]<br>ノナノイド {{LBF digit910Table|09}}
|align="center"|Chain length =9<br>{{#volatile:ListMol|LBF09: Nonanoid|LBF09}}<br>ノナノイド <br>[[Image:LBF09.png|70px]]{{LBF digit910Table|09}}
|align="center"|Chain length =10<br>[[Volatile:ListMol|LBF10|LBF10: Decanoid]]<br>デカノイド {{LBF digit910Table|10}}
|align="center"|Chain length =10<br>{{#volatile:ListMol|LBF10: Decanoid|LBF10}}<br>デカノイド <br>[[Image:LBF10.png|70px]]{{LBF digit910Table|10}}


|- valign="top"
|- valign="top"
|align="center"|Chain length =12<br>[[Volatile:ListMol|LBF12|LBF12: Dodecanoid]]<br>ドデカノイド {{LBF digit910Table|12}}
|align="center"|Chain length =11<br>{{#volatile:ListMol|LBF11: Undecanoid|LBF11}}<br>アンデカノイド <br>[[Image:LBF11.png|70px]]{{LBF digit910Table|11}}
|align="center"|Chain length =14<br>[[Volatile:ListMol|LBF14|LBF14: Tetradecanoid]]<br>テトラデカノイド {{LBF digit910Table|14}}
|align="center"|Chain length =12<br>{{#volatile:ListMol|LBF12: Dodecanoid|LBF12}}<br>ドデカノイド <br>[[Image:LBF12.png|70px]]{{LBF digit910Table|12}}
|align="center"|Chain length =16<br>[[Volatile:ListMol|LBF16|LBF16: Hexadecanoid]]<br>ヘキサデカノイド {{LBF digit910Table|16}}
|align="center"|Chain length =13<br>{{#volatile:ListMol|LBF13: Tridecanoid|LBF13}}<br>トリデカノイド <br>[[Image:LBF13.png|70px]]{{LBF digit910Table|13}}
|align="center"|Chain length =14<br>{{#volatile:ListMol|LBF14: Tetradecanoid|LBF14}}<br>テトラデカノイド <br>[[Image:LBF14.png|70px]]{{LBF digit910Table|14}}


|- valign="top"
|- valign="top"
|align="center"|Chain length =18<br>[[Volatile:ListMol|LBF18|LBF18: Octadecanoid]]<br>オクタデカノイド {{LBF digit910Table|18}}
|align="center"|Chain length =15<br>{{#volatile:ListMol|LBF15: Pentadecanoid|LBF15}}<br>ペンタデカノイド <br>[[Image:LBF15.png|70px]]{{LBF digit910Table|15}}
|align="center"|Chain length =20<br>[[Volatile:ListMol|LBF20|LBF20: Eicosanoid]]<br>エイコサノイド {{LBF digit910Table|20}}
|align="center"|Chain length =16<br>{{#volatile:ListMol|LBF16: Hexadecanoid|LBF16}}<br>ヘキサデカノイド <br>[[Image:LBF16.png|70px]]{{LBF digit910Table|16}}
|align="center"|Chain length =22<br>[[Volatile:ListMol|LBF22|LBF22: Docosanoid]]<br>ドコサノイド {{LBF digit910Table|22}}
|align="center"|Chain length =17<br>{{#volatile:ListMol|LBF17: Heptadecanoid|LBF17}}<br>ヘプタデカノイド <br>[[Image:LBF17.png|70px]]{{LBF digit910Table|17}}
|align="center"|Chain length =18<br>{{#volatile:ListMol|LBF18: Octadecanoid|LBF18}}<br>オクタデカノイド <br>[[Image:LBF18.png|70px]]{{LBF digit910Table|18}}


|- valign="top"
|- valign="top"
|align="center"|Chain length =24<br>[[Volatile:ListMol|LBF24|LBF24: Tetracosanoid]]<br>テトラコサノイド {{LBF digit910Table|24}}
|align="center"|Chain length =19<br>{{#volatile:ListMol|LBF19: Nonadecanoid|LBF19}}<br>ノナデカノイド <br>[[Image:LBF19.png|70px]]{{LBF digit910Table|19}}
|align="center"|Chain length >= 26<br>[[Volatile:ListMol|LBF26|LBF26: > 26]]<br>長さ26以上 {{LBF digit910Table|26}}
|align="center"|Chain length =20<br>{{#volatile:ListMol|LBF20: Eicosanoid|LBF20}}<br>エイコサノイド <br>[[Image:LBF20.png|70px]]{{LBF digit910Table|20}}
|align="center"|Chain length =2n+1<br>[[Volatile:ListMol|LBF.%5b13579%5d|F**: odd numbers]]<br>長さが奇数 {{LBF digit910Table|13579}}
|align="center"|Chain length =21<br>{{#volatile:ListMol|LBF21: Uncosanoid|LBF21}}<br>アンコサノイド <br>[[Image:LBF21.png|70px]]{{LBF digit910Table|21}}
|align="center"|Chain length =22<br>{{#volatile:ListMol|LBF22: Docosanoid|LBF22}}<br>ドコサノイド <br>[[Image:LBF22.png|70px]]{{LBF digit910Table|22}}
 
|- valign="top"
|align="center"|Chain length =23<br>{{#volatile:ListMol|LBF23: Tricosaoid|LBF23}}<br>トリコサノイド <br>[[Image:LBF23.png|70px]]{{LBF digit910Table|23}}
|align="center"|Chain length =24<br>{{#volatile:ListMol|LBF24: Tetracosanoid|LBF24}}<br>テトラコサノイド <br>[[Image:LB24.png|70px]]{{LBF digit910Table|24}}
|align="center"|Chain length =25<br>{{#volatile:ListMol|LBF25: Pentacosanoid|LBF25}}<br>ペンタコサノイド <br>[[Image:LBF25.png|70px]]{{LBF digit910Table|25}}
|align="center"|Chain length =26<br>{{#volatile:ListMol|LBF26: Hexacosanoid|LBF26}}<br>ヘキサコサノイド <br>[[Image:LBF26.png|70px]]{{LBF digit910Table|26}}
 
|- valign="top"
|align="center"|Chain length =27<br>{{#volatile:ListMol|LBF27: Heptacosanoid|LBF27}}<br>ヘプタコサノイド <br>[[Image:LBF27.png|70px]]{{LBF digit910Table|27}}
|align="center"|Chain length =28<br>{{#volatile:ListMol|LBF28: Octacosanoid|LBF28}}<br>オクタコサノイド <br>[[Image:LBF28.png|70px]]{{LBF digit910Table|28}}
|align="center"|Chain length =29<br>{{#volatile:ListMol|LBF29: Nonacosanoid|LBF29}}<br>ノナコサノイド <br>[[Image:LBF29.png|70px]]{{LBF digit910Table|29}}
|align="center"|Chain length =30<br>{{#volatile:ListMol|LBF30: Triacontanoid|LBF30}}<br>トリアコンタノイド <br>[[Image:LBF30.png|70px]]{{LBF digit910Table|30}}
 
|- valign="top"
|align="center"|Chain length =31<br>{{#volatile:ListMol|LBF31: Hentriacontanoid|LBF31}}<br>ヘントリアコンタノイド <br>[[Image:LBF31.png|70px]]{{LBF digit910Table|31}}
|align="center"|Chain length =32<br>{{#volatile:ListMol|LBF32: Dotriacontanoid|LBF32}}<br>ドトリアコンタノイド <br>[[Image:LBF32.png|70px]]{{LBF digit910Table|32}}
|align="center"|Chain length =33<br>{{#volatile:ListMol|LBF33: Tritriacontanoid|LBF33}}<br>トリトリアコンタノイド <br>[[Image:LBF33.png|70px]]{{LBF digit910Table|33}}
|align="center"|Chain length =34<br>{{#volatile:ListMol|LBF34: Tetratriacontanoid|LBF34}}<br>テトラトリアコンタノイド <br>[[Image:LBF34.png|70px]]{{LBF digit910Table|34}}
 
|- valign="top"
|align="center"|Chain length =35<br>{{#volatile:ListMol|LBF35: Pentatriacontanoid|LBF35}}<br>ペンタトリアコンタノイド <br>[[Image:LBF35.png|70px]]{{LBF digit910Table|35}}
|align="center"|Chain length =36<br>{{#volatile:ListMol|LBF36: Hexatriacontanoid|LBF36}}<br>ヘキサトリアコンタノイド <br>[[Image:LBF36.png|70px]]{{LBF digit910Table|36}}
|align="center"|Chain length =37<br>{{#volatile:ListMol|LBF37: Heptatriacontanoid|LBF37}}<br>ヘプタトリアコンタノイド <br>[[Image:LBF37.png|70px]]{{LBF digit910Table|37}}
|align="center"|Chain length =38<br>{{#volatile:ListMol|LBF38: Octatriacontanoid|LBF38}}<br>オクタトリアコンタノイド <br>[[Image:LBF38.png|70px]]{{LBF digit910Table|38}}
 
|- valign="top"
|align="center"|Chain length =46<br>{{#volatile:ListMol|LBF46: HexaTetracontanoid|LBF46}}<br>ヘキサテトラコンタノイド <br>[[Image:LBF46.png|70px]]{{LBF digit910Table|46}}
|align="center"|
|align="center"|
|align="center"|
|}
|}
</center>
</center>


==Classification by Structure <small>骨格による分類</small>==
===By Structure <small>骨格</small>===
{{Twocolumn|
{{Twocolumn|


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<center>
<center>
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
|+ Table 2. Classification by Structure
|+ Classification by Structure
|- valign="top"
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....SC|LBF.....SC: <br>straight chain<br>直鎖<br>}}</span><br>[[Image:LBF-----SC.png|80px]]
|align="center"| [[:Category:LBF-----BC|LBF.....BC:<br/>branched chain<br>分岐鎖<br>]]<br>[[Image:LBF-----BC.png|80px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....HP|LBF.....HP: <br>hydroperoxy<br>過酸化<br>}}</span><br>[[Image:LBF-----HP.png|90px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....HO|LBF.....HO: <br>hydroxy or<br>fatty alcohol<br>}}</span><br>[[Image:LBF-----HO.png|80px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....SC|SC: straight chain<br>}}<br><br>[[Image:LBF-----SC.png|110px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....OX|LBF.....OX: <br>oxo<br>オキソ<br>}}</span><br>[[Image:LBF-----OX.png|80px]]
|align="center"| {{MapLink|ListMol|LBF.....BC|BC: branched chain<br>}}<br><br>[[Image:LBF-----BC.png|110px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....EO|LBF.....EO: <br>epoxy<br>エポキシ<br>}}</span><br>[[Image:LBF-----EO.png|100px]]
|align="center"| {{MapLink|ListMol|LBF.....HP|HP: hydroperoxy<br>}}<br>[[Image:LBF-----HP.png|130px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....MO|LBF.....MO: <br>methoxy<br>メトキシ<br>}}</span><br>[[Image:LBF-----MO.png|80px]]
|align="center"| {{MapLink|ListMol|LBF.....HO|HO: hydroxy or<br>fatty alcohol<br>}}<br>[[Image:LBF-----HO.png|110px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....CA|LBF.....CA: <br>carboxylic<br>カルボキシル<br>}}</span><br>[[Image:LBF-----CA.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....OX|OX: oxo<br>}} <br><br>[[Image:LBF-----OX.png|110px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....EO|EO: epoxy<br>}}<br><br>[[Image:LBF-----EO.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....AL|LBF.....AL: <br>aldehyde<br>アルデヒド<br>}}</span><br>[[Image:LBF-----AL.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....MO|MO: methoxy<br>}}<br>[[Image:LBF-----MO.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....KT|LBF.....KT: <br>ketone<br>ケトン<br>}}</span><br>[[Image:LBF-----KT.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....CA|CA: carboxylic<br>}}<br><br>[[Image:LBF-----CA.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....ES|LBF.....ES: <br>ester<br>エステル<br>}}</span><br>[[Image:LBF-----ES.png|100px]]
|align="center"| {{MapLink|ListMol|LBF.....AL|AL: aldehyde<br>}}<br>[[Image:LBF-----AL.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....ET|LBF.....ET: <br>ether<br>エーテル<br>}}</span><br>[[Image:LBF-----ET.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....KT|KT: ketone<br>}}<br>[[Image:LBF-----KT.png|120px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....ES|ES: ester<br>}}<br>[[Image:LBF-----ES.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....SF|LBF.....SF: <br>sulfur containing<br>含硫<br>}}</span><br>[[Image:LBF-----SF.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....ET|ET: ether<br>}}<br>[[Image:LBF-----ET.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....PH|LBF.....PH: <br>phosphate<br>燐酸<br>}}</span><br>[[Image:LBF-----PH.png|110px]]
|align="center"| {{MapLink|ListMol|LBF.....SF|SF: sulfur<br>containing<br>}}<br>[[Image:LBF-----SF.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....AN|LBF.....AN: <br>nitrogen containing<br>含窒素<br>}}</span><br>[[Image:LBF-----AN.png|90px]]
|align="center"| {{MapLink|ListMol|LBF.....PH|PH: phosphate<br>}}<br>[[Image:LBF-----PH.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....AM|LBF.....AM: <br>amide<br>アミド<br>}}</span><br>[[Image:LBF-----AM.png|110px]]
|align="center"| {{MapLink|ListMol|LBF.....AN|AN: nitrogen containing<br>}}<br>[[Image:LBF-----AN.png|120px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....AM|AM: amide<br>}}<br>[[Image:LBF-----AM.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....JA|LBF.....JA: <br>jasmonic acid related<br>ジャスモン酸関係<br>}}</span><br>[[Image:LBF-----OP.png|120px]]
|align="center"| {{MapLink|ListMol|LBF.....OP|OP: 12-oxo<br>-phytodienoic acid <br>}}<br>[[Image:LBF-----OP.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....PG|LBF.....PG: <br>prostaglandin<br>プロスタグランジン<br>}}</span><br>[[Image:LBF-----PG.png|140px]]
|align="center"| {{MapLink|ListMol|LBF.....JA|JA: jasmonic<br>acid related<br>}}<br>[[Image:LBF-----JA.png|125px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....LT|LBF.....LT: <br>leukotriene<br>ロイコトリエン<br>}}</span><br>[[Image:LBF-----LT.png|135px]]
|align="center"| {{MapLink|ListMol|LBF.....PG|PG: prostaglandin<br>}}<br>[[Image:LBF-----PG.png|130px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....TX|LBF.....TX: <br>thromboxane<br>トロンボキサン<br>}}</span><br>[[Image:LBF-----TX.png|140px]]
|align="center"| {{MapLink|ListMol|LBF.....LT|LT: leucotriene<br>}}<br>[[Image:LBF-----LT.png|140px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....TX|TX: thromboxane<br>}}<br>[[Image:LBF-----TX.png|140px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....LX|LBF.....LX: <br>lipoxin<br>リポキシン<br>}}</span><br>[[Image:LBF-----LX.png|140px]]
|align="center"| {{MapLink|ListMol|LBF.....LX|LX: lipoxin<br>}}<br>[[Image:LBF-----LX.png|130px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....HX|LBF.....HX: <br>hepoxilin<br>ヘポキシリン<br>}}</span><br>[[Image:LBF-----HX.png|120px]]
|align="center"| {{MapLink|ListMol|LBF.....HX|HX: hepoxilin<br>}}<br>[[Image:LBF-----HX.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....LG|LBF.....LG: <br>levuglandin<br>レブグランジン<br>}}</span><br>[[Image:LBF-----LG.png|140px]]
|align="center"| {{MapLink|ListMol|LBF.....LG|LG: levugladin<br>}}<br>[[Image:LBF-----LG.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....CV|LBF.....CV: <br>clavulone<br>クラヴロン<br>}}</span><br>[[Image:LBF-----CV.png|130px]]
|align="center"| {{MapLink|ListMol|LBF.....CV|CV: clavulone<br>}}<br>[[Image:LBF-----CV.png|120px]]


|- valign="top"
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF.....XX|XX: others<br>}}<br>[[Image:LBF-----XX.png|120px]]
|align="center"| <span class="plainlinks">{{MapLink|ListMol|LBF.....XX|LBF.....XX: <br>others<br>その他<br>}}</span><br>[[Image:LBF-----XX.png|120px]]
|align="center"|
|align="center"|
|align="center"|
|align="center"|
|align="center"|
|}
</center>
===Other Classification Charts <small>その他の分類チャート</small>===
* {{#volatile:ClassMatrix|Number of Carbons v.s. Degree of Unsaturation (炭素鎖長 対 不飽和度)|LBF.........|4|5|6|6|Number_of_Carbons|Degree_of_Unsaturation}}
* {{#volatile:ClassMatrix|Number of Carbons v.s. (n-z) Position (炭素鎖長 対 ω数)|LBF.........|4|5|7|8|Number_of_Carbons|(n-z)_Position}}
* {{#volatile:ClassMatrix|Number of Carbons v.s. Structure Type (炭素鎖長 対 骨格タイプ)|LBF.........|4|5|9|10|Number_of_Carbons|Structure_Type}}
* {{#volatile:ClassMatrix|Degree of Unsaturation v.s. (n-z) Position (不飽和度 対 ω数)|LBF.........|6|6|7|8|Degree_of_Unsaturation|(n-z)_Position}}
* {{#volatile:ClassMatrix|Degree of Unsaturation v.s. Structure Type (不飽和度 対 骨格タイプ)|LBF.........|6|6|9|10|Degree_of_Unsaturation|Structure_Type}}
* {{#volatile:ClassMatrix|(n-z) Position v.s. Structure Type (ω数 対 骨格タイプ)|LBF.........|7|8|9|10|(n-z)_Position|Structure_Type}}
<!-----
===By Degree of Unsaturation <small>不飽和度</small>===
{{Twocolumn|
The degree of unsaturation means the number of double bounds.
|
不飽和度とは二重結合の数を意味しています。
}}
<center>
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
|+ Classification by Degree of Unsaturation
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF..0|LBF..0: degree 0<br>不飽和度0<br>}}<br>例)Stearic acid
[[Image:LBF--0.png|70px]]
|align="center"| {{MapLink|ListMol|LBF..1|LBF..1: degree 1<br>不飽和度1<br>}}<br>例)Oleic acid
[[Image:LBF--1.png|120px]]
|align="center"| {{MapLink|ListMol|LBF..2|LBF..2: degree 2<br>不飽和度2<br>}}<br>例)Linoleic acid
[[Image:LBF--2.png|160px]]
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF..3|LBF..3: degree 3<br>不飽和度3<br>}}<br>例)α-linolenic acid
[[Image:LBF--3.png|160px]]
|align="center"| {{MapLink|ListMol|LBF..4|LBF..4: degree 4<br>不飽和度4<br>}}<br>例)Stearidonic acid
[[Image:LBF--4.png|160px]]
|align="center"| {{MapLink|ListMol|LBF..5|LBF..5: degree 5<br>不飽和度5<br>}}<br>例)Eicosapentanoic acid
[[Image:LBF--5.png|160px]]
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF..6|LBF..6: degree 6<br>不飽和度6<br>}}<br>例)DHA
[[Image:LBF--6.png|160px]]
|align="center"|
|align="center"|
|align="center"|
|align="center"|
Line 124: Line 241:
</center>
</center>


==Design of Fatty acyl ID numbers <small>ID番号の設計</small>==
 
===By Position of n-z Nomenclature <small>二重結合の位置(n-z)</small>===
<center>
<center>
12-DIGIT
{| class="wikitable" border="1" cellpadding="2" cellspacing="1" margin: 1em 1em 1em 1em"
<table border=1>
|+ Table 3. Classification by Position of n-z Nomenclature
<tr>
 
<td style="background-color:yellowgreen;" width=15px align="center"><big>L</big>
|- valign="top"
<td style="background-color:yellowgreen;" width=15px align="center"><big>B</big>
|align="center"| {{MapLink|ListMol|LBF...00|LBF...00: <br>(n-0) <br>}}<br>[[Image:LBF---00.png|70px]]
<td style="background-color:darkseagreen;" width=15px align="center"><big>F</big>
|align="center"| {{MapLink|ListMol|LBF...01|LBF...01: <br>(n-1) <br>}}<br>[[Image:LBF---01.png|90px]]
<td style="background-color:tomato; color:white" width=15px align="center"><big>''x''</big>
|align="center"| {{MapLink|ListMol|LBF...02|LBF...02: <br>(n-2) <br>}}<br>[[Image:LBF---02.png|110px]]
<td style="background-color:tomato; color:white" width=15px align="center"><big>''x''</big>
|align="center"| {{MapLink|ListMol|LBF...03|LBF...03: <br>(n-3) <br>}}<br>[[Image:LBF---03.png|120px]]
<td style="background-color:purple; color:white" width=15px align="center"><big>''y''</big>
 
<td style="background-color:firebrick; color:white" width=15px align="center"><big>''z''</big>
|- valign="top"
<td style="background-color:firebrick; color:white" width=15px align="center"><big>''z''</big>
|align="center"| {{MapLink|ListMol|LBF...04|LBF...04: <br>(n-4) <br>}}<br>[[Image:LBF---04.png|120px]]
<td style="background-color:green; color:white;" width=15px align="center"><big>''w''</big>
|align="center"| {{MapLink|ListMol|LBF...05|LBF...05: <br>(n-5) <br>}}<br>[[Image:LBF---05.png|120px]]
<td style="background-color:green; color:white" width=15px align="center"><big>''w''</big>
|align="center"| {{MapLink|ListMol|LBF...06|LBF...06: <br>(n-6) <br>}}<br>[[Image:LBF---06.png|120px]]
<td style="background-color:white;" width=15px align="center"><big>''c''</big>
|align="center"| {{MapLink|ListMol|LBF...07|LBF...07: <br>(n-7) <br>}}<br>[[Image:LBF---07.png|120px]]
<td style="background-color:white;" width=15px align="center"><big>''c''</big>
 
</tr>
|- valign="top"
</table>
|align="center"| {{MapLink|ListMol|LBF...08|LBF...08: <br>(n-8) <br>}}<br>[[Image:LBF---08.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...09|LBF...09: <br>(n-9) <br>}}<br>[[Image:LBF---09.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...10|LBF...10: <br>(n-10) <br>}}<br>[[Image:LBF---10.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...11|LBF...11: <br>(n-11) <br>}}<br>[[Image:LBF---11.png|120px]]
 
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF...12|LBF...12: <br>(n-12) <br>}}<br>[[Image:LBF---12.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...13|LBF...13: <br>(n-13) <br>}}<br>[[Image:LBF---13.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...14|LBF...14: <br>(n-14) <br>}}<br>[[Image:LBF---14.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...15|LBF...15: <br>(n-15) <br>}}<br>[[Image:LBF---15.png|120px]]
 
|- valign="top"
|align="center"| {{MapLink|ListMol|LBF...16|LBF...16: <br>(n-16) <br>}}<br>[[Image:LBF---16.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...17|LBF...17: <br>(n-17) <br>}}<br>[[Image:LBF---17.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...18|LBF...18: <br>(n-18) <br>}}<br>[[Image:LBF---18.png|120px]]
|align="center"| {{MapLink|ListMol|LBF...22|LBF...22: <br>(n-22) <br>}}<br>[[Image:LBF---22.png|120px]]
|}
</center>
</center>
{{Twocolumn|
----->
* ''x'' ... carbon chain length
* ''y'' ... degree of unsaturation
* ''z'' ... position of n-''z'' (n minus z; also ω-z or omega-z) nomenclature
* ''w'' ... structure type as in Table 2 above
* ''c'' ... serial number
|
* ''x'' ... 炭素鎖長
* ''y'' ... 不飽和度
* ''z'' ... n-''z'' (またはω-zやomega-z) における数
* ''w'' ... 上記Table 2にある構造タイプ
* ''c'' ... 通し番号
}}

Latest revision as of 01:11, 30 January 2023

Fat acyl


Upper classes: LB

Class Overview

The fat acyl category includes fatty acids and acyl derivatives of length more than 7. Fatty acids with aliphatic tails of 8--14 are called medium chain fatty acids (MCFA), and those of more than 14 are called long chain fatty acids (LCFA). For shorter ones (SCFA), please go to the Basic Metabolites (BM) category.

Higher fatty acids refer to those of 10 or more carbons. For definition, see IUPAC page.

脂肪族アシルカテゴリーは長さが8以上の脂肪酸やアシル誘導体を含んでいます。長さが8~14のものを中鎖脂肪酸(MCFA)、長さが15以上のものを長鎖脂肪酸(LCFA)といいます。 短いもの(SCFA)は基礎代謝物(BM)カテゴリーに登録されています。

炭素長が10以上のものは高級脂肪酸とも呼ばれます。定義はIUPACを参照してください。

Abbreviations

SCFA short chain fatty acids 短鎖脂肪酸 : 1-7 carbons
MCFA medium chain fatty acids 中鎖脂肪酸 : 8-14 carbons
LCFA long chain fatty acids 長鎖脂肪酸 : 15< carbons
SFA Saturated fatty acids 飽和脂肪酸 : no double bond
UFA Unsaturated fatty acids 不飽和脂肪酸 : with double bond(s)
MUFA monounsaturated fatty acids 一価不飽和脂肪酸 : 1 double bond
PUFA polyunsaturated fatty acids 多価不飽和脂肪酸 : 1< double bonds


Design of Fat acyl Page Titles

Each page title contains chain-length, degree of unsaturation, position of double bonds, and backbone structure (branches, peroxidation, or prostanoids etc.).

各分子のページタイトルに鎖長、不飽和度、二重結合の位置、骨格タイプ(分岐や過酸化、プロスタノイドなど)がコード化されています。

12-DIGIT

L B F x x y z z w w c c

  • x ... carbon chain length (See Table)
  • y ... degree of unsaturation (See Table)
  • z ... position of n-z (n minus z; also ω-z or omega-z) nomenclature (See Table)
  • w ... structure type (See Table)
  • c ... serial number

  • x ... 炭素鎖長 (分類表)
  • y ... 不飽和度(分類表)
  • z ... n-z (またはω-zやomega-z) における数(分類表)
  • w ... 骨格のタイプ (分類表)
  • c ... 通し番号

Classification 分類

By Chain Length 鎖長

Fatty acids are extended by polymerization of malonyl CoA, and have even chain length by default.

脂肪酸はマロニルCoAの重合によって伸張し、通常は炭素数が偶数です。長いものほど融点が高くなります。

Classification by Chain Length LBF.png
Chain length =<7
BMFY: Short-chain
短鎖


N.A.
Chain length =8

オクタノイド
LBF08.png


Chain length =9

ノナノイド
LBF09.png


Chain length =10

デカノイド
LBF10.png


Chain length =11

アンデカノイド
LBF11.png


Chain length =12

ドデカノイド
LBF12.png


Chain length =13

トリデカノイド
LBF13.png


Chain length =14

テトラデカノイド
LBF14.png


Chain length =15

ペンタデカノイド
LBF15.png


Chain length =16

ヘキサデカノイド
LBF16.png


Chain length =17

ヘプタデカノイド
LBF17.png


Chain length =18

オクタデカノイド
LBF18.png


Chain length =19

ノナデカノイド
LBF19.png


Chain length =20

エイコサノイド
LBF20.png


Chain length =21

アンコサノイド
LBF21.png


Chain length =22

ドコサノイド
LBF22.png


Chain length =23

トリコサノイド
LBF23.png


Chain length =24

テトラコサノイド
LB24.png


Chain length =25

ペンタコサノイド
LBF25.png


Chain length =26

ヘキサコサノイド
LBF26.png


Chain length =27

ヘプタコサノイド
LBF27.png


Chain length =28

オクタコサノイド
LBF28.png


Chain length =29

ノナコサノイド
LBF29.png


Chain length =30

トリアコンタノイド
LBF30.png


Chain length =31

ヘントリアコンタノイド
LBF31.png


Chain length =32

ドトリアコンタノイド
LBF32.png


Chain length =33

トリトリアコンタノイド
LBF33.png


Chain length =34

テトラトリアコンタノイド
LBF34.png


Chain length =35

ペンタトリアコンタノイド
LBF35.png


Chain length =36

ヘキサトリアコンタノイド
LBF36.png


Chain length =37

ヘプタトリアコンタノイド
LBF37.png


Chain length =38

オクタトリアコンタノイド
LBF38.png


Chain length =46

ヘキサテトラコンタノイド
LBF46.png


By Structure 骨格

Classification by Structure
 
(200 pages)

LBF-----SC.png
LBF.....BC:
branched chain
分岐鎖

LBF-----BC.png
 
(62 pages)

LBF-----HP.png
 
(170 pages)

LBF-----HO.png
 
(60 pages)

LBF-----OX.png
 
(16 pages)

LBF-----EO.png
 
(6 pages)

LBF-----MO.png
 
(2 pages)

LBF-----CA.png
 
(0 pages)

LBF-----AL.png
 
(0 pages)

LBF-----KT.png
 
(0 pages)

LBF-----ES.png
 
(0 pages)

LBF-----ET.png
 
(0 pages)

LBF-----SF.png
 
(1 pages)

LBF-----PH.png
 
(0 pages)

LBF-----AN.png
 
(54 pages)

LBF-----AM.png
 
(2 pages)

LBF-----OP.png
 
(128 pages)

LBF-----PG.png
 
(22 pages)

LBF-----LT.png
 
(6 pages)

LBF-----TX.png
 
(2 pages)

LBF-----LX.png
 
(4 pages)

LBF-----HX.png
 
(0 pages)

LBF-----LG.png
 
(23 pages)

LBF-----CV.png
 
(8 pages)

LBF-----XX.png


Other Classification Charts その他の分類チャート


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