LBF21503HO04: Difference between revisions
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|Note=Isomerization of hydroperoxides generated from icosapentaenoete by autooxidation: the proportion of 5-, 18-isomer (outer hydroperoxides) is higher than that of other isomer (8-,9-,11-,12-,14-,15-isomer[inner hydroperoxides])<!--8110-->. | |||
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Revision as of 17:00, 27 January 2010
| LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
| IDs and Links | |
|---|---|
| LipidBank | DFA8100 |
| LipidMaps | LMFA03070017 |
| CAS | |
| KEGG | {{{KEGG}}} |
| KNApSAcK | {{{KNApSAcK}}} |
| mol | LBF21503HO04 |
| Methyl 11-Hydroperoxy-5,8,12,14,17-Icosapentaenoate | |
|---|---|
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| Structural Information | |
| Methyl 11-Hydroperoxy-5,8,12,14,17-Icosapentaenoate | |
| |
| Formula | |
| Exact Mass | |
| Average Mass | |
| SMILES | |
| Physicochemical Information | |
| Autooxidation of icosapentaenoate Yamauchi_R et al.. Oxidation of icosapentaenoate by singlet-oxygen Yamauchi_R et al.. Oxidation of icosapentaenoate in the presence of myoglobin. | |
| Isomerization of hydroperoxides generated from icosapentaenoete by autooxidation: the proportion of 5-, 18-isomer (outer hydroperoxides) is higher than that of other isomer (8-,9-,11-,12-,14-,15-isomer[inner hydroperoxides]). | |
| Spectral Information | |
| Mass Spectra | GC-EI-MS(after reduction and TMS-derivatization) YamauchiRet al.: m/e=404[M]; 389[M-CH3] 314[M-HOTMS], GC-EI-MS(Me-ester: after reduction, hydrogenation and TMS-derivatization) YamauchiRet al.: m/e=399[M-CH3]; 383[M-OCH3]; 367[399-CH3OH] |
| UV Spectra | conjugated diene: lmax=235.5nm YamauchiRet al. |
| IR Spectra | OOH group: 3400cm-1 YamauchiRet al. |
| NMR Spectra | 1H-NMR YamauchiRet al.: OOH proton: 8.5ppm |
| Other Spectra | |
| Chromatograms | |
