LBF18104HP01: Difference between revisions
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{{Lipid/Header}} | |||
{{Hierarchy|{{PAGENAME}}}} | {{Hierarchy|{{PAGENAME}}}} | ||
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|LipidBank=DFA8076 | |LipidBank=DFA8076 | ||
|LipidMaps=LMFA01040057 | |LipidMaps=LMFA01040057 | ||
|SysName=Methyl-10,12,13,16- | |SysName=Methyl-10,12,13,16-bisepidioxy-9-hydroperoxy-14-octadecenoic acid | ||
|Common Name=&&Methyl-10,12,13,16- | |Common Name=&&Methyl-10,12,13,16-bisepidioxy-9-hydroperoxy-14-octadecenoic acid&& | ||
|Mass Spectra=GC-EI-MS(after reduction(PH3P) and TMS-derivatization)[[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]: m/e=259[SMTO=CH(CH2)7COOCH3]; 185[M-259]; GC-EI-MS(after reduction, hydrogenation, and TMS-derivatization)[[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]: m/e=389[M-259-HOTMS]; 387[M-261-HOTMS]; 297[387-HOTMS] | |Mass Spectra=GC-EI-MS(after reduction(PH3P) and TMS-derivatization)[[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]: m/e=259[SMTO=CH(CH2)7COOCH3]; 185[M-259]; GC-EI-MS(after reduction, hydrogenation, and TMS-derivatization)[[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]: m/e=389[M-259-HOTMS]; 387[M-261-HOTMS]; 297[387-HOTMS] | ||
|NMR Spectra= | |NMR Spectra=^1 H-NMR[[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]: C8: 1.6ppm; C9: 4.08ppm; C10, 12, 13, 16: 4.45ppm; C11: 2.1-2.7ppm; C14, 15: 5.68ppm; OOH: 8.45ppm | ||
|Source=It is produced from 10,12-epidioxy-9-hydroperoxides by singlet-oxygen mediated oxidation of 12-peroxyradical linoleate via 1,3-cyclization[[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]][[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]. | |||
|Chemical Synthesis= | |||
|Metabolism= | |||
}} | }} | ||
{{Lipid/Footer}} | |||
Latest revision as of 14:33, 26 May 2010
| LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
| IDs and Links | |
|---|---|
| LipidBank | DFA8076 |
| LipidMaps | LMFA01040057 |
| CAS | |
| KEGG | {{{KEGG}}} |
| KNApSAcK | {{{KNApSAcK}}} |
| mol | LBF18104HP01 |
| Methyl-10,12,13,16-bisepidioxy-9-hydroperoxy-14-octadecenoic acid | |
|---|---|
| |
| Structural Information | |
| Methyl-10,12,13,16-bisepidioxy-9-hydroperoxy-14-octadecenoic acid | |
| |
| Formula | C19H32O8 |
| Exact Mass | 388.20971799999995 |
| Average Mass | 388.45258 |
| SMILES | C(C(O2)CC(O2)C(OO)CCCCCCCC(=O)OC)(C=1)OOC(CC)C1 |
| Physicochemical Information | |
| It is produced from 10,12-epidioxy-9-hydroperoxides by singlet-oxygen mediated oxidation of 12-peroxyradical linoleate via 1,3-cyclization Frankel_EN Neff_WE et al.. | |
| Spectral Information | |
| Mass Spectra | GC-EI-MS(after reduction(PH3P) and TMS-derivatization) Neff_WE et al.: m/e=259[SMTO=CH(CH2)7COOCH3]; 185[M-259]; GC-EI-MS(after reduction, hydrogenation, and TMS-derivatization) Neff_WE et al.: m/e=389[M-259-HOTMS]; 387[M-261-HOTMS]; 297[387-HOTMS] |
| UV Spectra | |
| IR Spectra | |
| NMR Spectra | 1H-NMR Neff_WE et al.: C8: 1.6ppm; C9: 4.08ppm; C10, 12, 13, 16: 4.45ppm; C11: 2.1-2.7ppm; C14, 15: 5.68ppm; OOH: 8.45ppm |
| Other Spectra | |
| Chromatograms | |
| Reported Metabolites, References | |||||||||||||||
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