LBF18107MO01: Difference between revisions
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|LipidBank=DFA8035 | |LipidBank=DFA8035 | ||
|LipidMaps=LMFA01080004 | |LipidMaps=LMFA01080004 | ||
|SysName=13-Hydroxy-9,10- | |SysName=13-Hydroxy-9,10-dimethoxy-11-octadecenoic acid | ||
|Common Name=&&13-Hydroxy-9,10- | |Common Name=&&13-Hydroxy-9,10-dimethoxy-11-octadecenoic acid&& | ||
|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]: m/e=201[CHOCH3(CH2)7COOCH3](standard peak), 243[M-201] 173[SMTO=CH(CH2)4CH3] | |Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]: m/e=201[CHOCH3(CH2)7COOCH3](standard peak), 243[M-201] 173[SMTO=CH(CH2)4CH3] | ||
|IR Spectra=Methyl ester(CS2)[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]: trans olefin(973-970cm | |IR Spectra=Methyl ester(CS2)[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]: trans olefin(973-970cm^{-1}), OH(3600 and 3440cm^{-1}) | ||
|NMR Spectra= | |NMR Spectra=^1 H-NMR(methyl ester; CDCl3, 300MHz)[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]: C9(3.15-3.19ppm), C10(3.58-3.62ppm), C11(5.55-5.58ppm), C12(5.71ppm), C13(4.15ppm), C9OCH3(3.27-3.29ppm), C10OCH3(3.40-3.41ppm), J11-12=15.7Hz(trans unsaturation) | ||
|NOTE Spectra=ODR analysis[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]] | |NOTE Spectra=ODR analysis[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]] | ||
|Source=Oxidative products of 13-hydroperoxylinoleate in MeOH[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]]. | |||
|Chemical Synthesis= | |||
|Metabolism= | |||
|Other Spectra=ODR analysis[[Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508|{{RelationTable/GetFirstAuthor|Reference:Gardner:HW:Weisleder_D:Nelson_EC:,J. Org. Chem.,1984,49,508}}]] | |||
}} | }} | ||
{{Lipid/Footer}} |
Latest revision as of 21:00, 14 April 2010
LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
IDs and Links | |
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LipidBank | DFA8035 |
LipidMaps | LMFA01080004 |
CAS | |
KEGG | {{{KEGG}}} |
KNApSAcK | {{{KNApSAcK}}} |
mol | LBF18107MO01 |
13-Hydroxy-9,10-dimethoxy-11-octadecenoic acid | |
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Structural Information | |
13-Hydroxy-9,10-dimethoxy-11-octadecenoic acid | |
| |
Formula | C20H38O5 |
Exact Mass | 358.271924326 |
Average Mass | 358.51272 |
SMILES | C(CCC(O)C=CC(C(OC)CCCCCCCC(O)=O)OC)CC |
Physicochemical Information | |
Oxidative products of 13-hydroperoxylinoleate in MeOH Gardner et al.. | |
Spectral Information | |
Mass Spectra | GC-EI-MS(after methanolysis and trimethylsilylation) Gardner et al.: m/e=201[CHOCH3(CH2)7COOCH3](standard peak), 243[M-201] 173[SMTO=CH(CH2)4CH3] |
UV Spectra | |
IR Spectra | Methyl ester(CS2) Gardner et al.: trans olefin(973-970cm-1), OH(3600 and 3440cm-1) |
NMR Spectra | 1H-NMR(methyl ester; CDCl3, 300MHz) Gardner et al.: C9(3.15-3.19ppm), C10(3.58-3.62ppm), C11(5.55-5.58ppm), C12(5.71ppm), C13(4.15ppm), C9OCH3(3.27-3.29ppm), C10OCH3(3.40-3.41ppm), J11-12=15.7Hz(trans unsaturation) |
Other Spectra | ODR analysis Gardner et al. |
Chromatograms |
Reported Metabolites, References | ||||||||||
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