LBF18109HP01: Difference between revisions
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|LipidBank=DFA8010 | |LipidBank=DFA8010 | ||
|LipidMaps=LMFA01040011 | |LipidMaps=LMFA01040011 | ||
|SysName=12,13-Epoxy-11- | |SysName=12,13-Epoxy-11-hydroperoxy-9-octadecenoic acid | ||
|Common Name=&&12,13-Epoxy-11- | |Common Name=&&12,13-Epoxy-11-hydroperoxy-9-octadecenoic acid&& | ||
|Mass Spectra=GC-EI-MS(after methylation, reduction and trimethylsilylation)[[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]][[Reference:Hamberg_M:Gotthammar_B:,Lipids,1973,8,737|{{RelationTable/GetFirstAuthor|Reference:Hamberg_M:Gotthammar_B:,Lipids,1973,8,737}}]]: m/e= 285[SMTO=CH-CH=CH-(CH2)7COOCH3] | |Mass Spectra=GC-EI-MS(after methylation, reduction and trimethylsilylation)[[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]][[Reference:Hamberg_M:Gotthammar_B:,Lipids,1973,8,737|{{RelationTable/GetFirstAuthor|Reference:Hamberg_M:Gotthammar_B:,Lipids,1973,8,737}}]]: m/e= 285[SMTO=CH-CH=CH-(CH2)7COOCH3] | ||
|IR Spectra=After methylation and reduction[[Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157|{{RelationTable/GetFirstAuthor|Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157}}]][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]] | |IR Spectra=After methylation and reduction[[Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157|{{RelationTable/GetFirstAuthor|Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157}}]][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]] | ||
|NMR Spectra= | |NMR Spectra=^1 H-NMR(after methylation and reduction)[[Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157|{{RelationTable/GetFirstAuthor|Reference:Galliard_T:Phillips_DR:Matthew_JA:,Biochim. Biophys. Acta,1975,409,157}}]][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]] | ||
|Source=Major reactive products between 13-hydroperoxylinoleate (or linoleate) and soy bean extracts(pH=6.9)[[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]]. Production mechanism[[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]][[Reference:Gardner_HW:,J. Agric. Food Chem.,1975,23,129|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:,J. Agric. Food Chem.,1975,23,129}}]]. | |Source=Major reactive products between 13-hydroperoxylinoleate (or linoleate) and soy bean extracts(pH=6.9)[[Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Weisleder_D:Kleiman_R:,Lipids,1978,13,246}}]]. Production mechanism[[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]]<!--8030-->[[Reference:Gardner_HW:,J. Agric. Food Chem.,1975,23,129|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:,J. Agric. Food Chem.,1975,23,129}}]]<!--8074-->. | ||
|Chemical Synthesis= | |Chemical Synthesis= | ||
|Metabolism= | |Metabolism= |
Latest revision as of 21:00, 14 April 2010
LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
IDs and Links | |
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LipidBank | DFA8010 |
LipidMaps | LMFA01040011 |
CAS | |
KEGG | {{{KEGG}}} |
KNApSAcK | {{{KNApSAcK}}} |
mol | LBF18109HP01 |
12,13-Epoxy-11-hydroperoxy-9-octadecenoic acid | |
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Structural Information | |
12,13-Epoxy-11-hydroperoxy-9-octadecenoic acid | |
| |
Formula | C18H32O5 |
Exact Mass | 328.224974134 |
Average Mass | 328.44368000000003 |
SMILES | O(C1CCCCC)C(C(OO)C=CCCCCCCCC(O)=O)1 |
Physicochemical Information | |
Major reactive products between 13-hydroperoxylinoleate (or linoleate) and soy bean extracts(pH=6.9) Gardner_HW et al.. Production mechanism Frankel_EN Gardner_HW . | |
Spectral Information | |
Mass Spectra | GC-EI-MS(after methylation, reduction and trimethylsilylation) Gardner_HW et al. HambergMet al.: m/e= 285[SMTO=CH-CH=CH-(CH2)7COOCH3] |
UV Spectra | |
IR Spectra | After methylation and reduction GalliardTet al. Gardner_HW et al. Gardner_HW et al. |
NMR Spectra | 1H-NMR(after methylation and reduction) GalliardTet al. Gardner_HW et al. Gardner_HW et al. |
Other Spectra | |
Chromatograms |
Reported Metabolites, References | |||||||||||||||||||||||||||||||||||
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