LBF18206HP02: Difference between revisions

Latest revision as of 06:00, 15 April 2010

Upper classes: LB LBF

10-Hydroperoxy-8,12-octadecadienoate

Structural Information
	10-Hydroperoxy-8,12-octadecadienoic acid
	10-Hydroperoxy-8,12-octadecadienoate

Formula	C18H32O4
Exact Mass	312.23005951199997
Average Mass	312.44428
SMILES	`CCCCCC=CCC(OO)C=CCCCCCCC(O)=O`
Physicochemical Information






	Oxidation of methyl linoleate by singlet oxygen Logani_MK et al. Sevanian_A et al. Fujimoto_K .


	Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously. Logani_MK et al. Sevanian_A et al. Fujimoto_K


Spectral Information
Mass Spectra	GC-EI-MS(after methanolysis, reduction and trimethylsilylation) Terao_Jet al. Frankel_EN et al.: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation) Chan_HWS :m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation) Terao_Jet al.
UV Spectra
IR Spectra	After methanolyzation and reduction Thomas_MJ et al. Terao_Jet al.: isolated double bond (3013-3010, 972-971cm^-1)
NMR Spectra	¹H-NMR(after methanolyzation and reduction) Thomas_MJ et al.: olefinic protons(5.55-5.59ppm), C10 (4.08-4.11ppm)
Other Spectra
Chromatograms

Reported Metabolites, References

Biospecies	ID	Compound Name	Reference
n.a.	LBF18206HP02	See above.	Chan_HWS 1977
n.a.	LBF18206HP02	See above.	Frankel_EN et al. 1979
n.a.	LBF18206HP02	See above.	Fujimoto_K 1986
n.a.	LBF18206HP02	See above.	Logani_MK et al. 1980
n.a.	LBF18206HP02	See above.	Sevanian_A et al. 1985
n.a.	LBF18206HP02	See above.	Terao_J et al. 1977
n.a.	LBF18206HP02	See above.	Thomas_MJ et al. 1980

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+{{Lipid/Header}}
 {{Hierarchy|{{PAGENAME}}}}
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 |LipidBank=DFA8003
 |LipidMaps=LMFA01040006
-|SysName=10-Hydroperoxy-8,12-Octadecadienoic Acid/10-Hydroperoxy-8,12-Octadecadienoate
+|SysName=10-Hydroperoxy-8,12-octadecadienoic acid
-|Mass Spectra=GC-EI-MS(after methanolysis, reduction and trimethylsilylation)<<8090/8019>>: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation)<<8020>>:m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation)<<8090>>
+|Common Name=&&10-Hydroperoxy-8,12-octadecadienoate&&
-|IR Spectra=After methanolyzation and reduction<<8091/8090>>: isolated double bond (3013-3010, 972-971cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>)
+|Mass Spectra=GC-EI-MS(after methanolysis, reduction and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]][[Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:Neff_WE:Bessler_TR:,Lipids,1979,14,961}}]]: m/e= 271[SMTO=CH-CH=CH-(CH2)6COOCH3], GC-EI-MS (after methylation, reduction and hydrogenation)[[Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100|{{RelationTable/GetFirstAuthor|Reference:Chan_HWS:,J. Am. Oil Chem. Soc.,1977,54,100}}]]:m/e= 201[CH(OH)(CH2)8COOCH3], 172[(CH2)8COOCH3+H], 169[C(OH)(CH2)8CO] GC-EI-MS(after methylation, reduction, hydrogenation and trimethylsilylation)[[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]]
-|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR(after methanolyzation and reduction)<<8091>>: olefinic protons(5.55-5.59ppm), C10 (4.08-4.11ppm)
+|IR Spectra=After methanolyzation and reduction[[Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544|{{RelationTable/GetFirstAuthor|Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544}}]][[Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,J. Am. Oil Chem. Soc.,1977,54,234}}]]: isolated double bond (3013-3010, 972-971cm^{-1})
+|NMR Spectra=^1 H-NMR(after methanolyzation and reduction)[[Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544|{{RelationTable/GetFirstAuthor|Reference:Thomas_MJ:Pryor_WA:,Lipids,1980,15,544}}]]: olefinic protons(5.55-5.59ppm), C10 (4.08-4.11ppm)
+|Source=Oxidation of methyl linoleate by singlet oxygen[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485|{{RelationTable/GetFirstAuthor|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]]<!--8044--><!--8045-->[[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365|{{RelationTable/GetFirstAuthor|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]<!--8048--><!--8049-->.
+|Chemical Synthesis=
+|Metabolism=
+|Biological Activity=Pysiological damages are induced by these hydroperoxides which are incorporated into bodies or synthesized endogenously.[[Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485|{{RelationTable/GetFirstAuthor|Reference:Logani_MK:Davies_RE:,Lipids,1980,15,485}}]]<!--8044--><!--8045-->[[Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365|{{RelationTable/GetFirstAuthor|Reference:Sevanian_A:Hochstein_P:,Annu. Rev. Nutr.,1985,5,365}}]][[Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:,Fragrance J. (in Japanese),1986,76,21}}]]<!--8048--><!--8049-->
 }}
+{{Lipid/Footer}}

IDs and Links
LipidBank	DFA8003
LipidMaps	LMFA01040006
CAS
KEGG	{{{KEGG}}}
KNApSAcK	{{{KNApSAcK}}}

mol	LBF18206HP02

LBF18206HP02: Difference between revisions

Latest revision as of 06:00, 15 April 2010

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