LBF18302HP03: Difference between revisions
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{{Lipid/Header}} | |||
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|LipidBank=DFA8066 | |LipidBank=DFA8066 | ||
|LipidMaps=LMFA01040050 | |LipidMaps=LMFA01040050 | ||
|SysName=Methyl-9,15- | |SysName=Methyl-9,15-dihydroperoxy-10,12,16-octadecatrienoic acid | ||
|Mass Spectra=GC-EI-MS(after reduction and TMS-derivatization) | |Common Name=&&Methyl-9,15-dihydroperoxy-10,12,16-octadecatrienoic acid&& | ||
|UV Spectra=Conjugated diene: | |Mass Spectra=GC-EI-MS(after reduction and TMS-derivatization)[[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]]: m/e=157[(CH2)7COOCH3] 143[SMTO=CHCH=CHCH3] | ||
|IR Spectra=OOH group: 3700-3140cm | |UV Spectra=Conjugated diene: lambda max=237nm[[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]] | ||
|NMR Spectra= | |IR Spectra=OOH group: 3700-3140cm^{-1}[bonded], 3520-3510cm^{-1}[free]; conjugated trans, cis diene: 985-979cm^{-1}, 953-935cm^{-1}; isolated trans unsaturation: 968-960cm^{-1}[[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]] | ||
|NMR Spectra=^1 H-NMR[[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]]: C2: 2.31ppm; C8, 14: 1.75-1.85ppm; C9, 15: 4.40ppm; C10, 11, 12, 13, 16, 17: 5.25-6.90ppm; C18: 1.8ppm; OOH: 7.83-7.88ppm[[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]] | |||
|Source=It is produced from 9- or 15-hydroperoxy isomer during oxidation of linoleate by singlet-oxygen[[Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197|{{RelationTable/GetFirstAuthor|Reference:Frankel_EN:,Prog. Lipid Res.,1984,23,197}}]][[Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Weisleder_D:,Lipids,1982,17,780}}]][[Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:,Lipids,1984,19,952}}]]. | |||
|Chemical Synthesis= | |||
|Metabolism= | |||
|Biological Activity=It reacts with DNA in the presence of Fe ions and ascorbic acid[[Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100|{{RelationTable/GetFirstAuthor|Reference:Fujimoto_K:Neff_WE:Frankel_EN:,Biochim. Biophys. Acta,1984,795,100}}]]. | |||
}} | }} | ||
{{Lipid/Footer}} |
Latest revision as of 08:13, 26 May 2010
LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
IDs and Links | |
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LipidBank | DFA8066 |
LipidMaps | LMFA01040050 |
CAS | |
KEGG | {{{KEGG}}} |
KNApSAcK | {{{KNApSAcK}}} |
mol | LBF18302HP03 |
Methyl-9,15-dihydroperoxy-10,12,16-octadecatrienoic acid | |
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Structural Information | |
Methyl-9,15-dihydroperoxy-10,12,16-octadecatrienoic acid | |
| |
Formula | C19H32O6 |
Exact Mass | 356.219888756 |
Average Mass | 356.45378 |
SMILES | CC=CC(OO)CC=CC=CC(OO)CCCCCCCC(=O)OC |
Physicochemical Information | |
It is produced from 9- or 15-hydroperoxy isomer during oxidation of linoleate by singlet-oxygen Frankel_EN Neff_WE et al. Neff_WE et al.. | |
It reacts with DNA in the presence of Fe ions and ascorbic acid Fujimoto_K et al.. | |
Spectral Information | |
Mass Spectra | GC-EI-MS(after reduction and TMS-derivatization) Neff_WE et al.: m/e=157[(CH2)7COOCH3] 143[SMTO=CHCH=CHCH3] |
UV Spectra | Conjugated diene: λ max=237nm Neff_WE et al. |
IR Spectra | OOH group: 3700-3140cm-1[bonded], 3520-3510cm-1[free]; conjugated trans, cis diene: 985-979cm-1, 953-935cm-1; isolated trans unsaturation: 968-960cm-1 Neff_WE et al. |
NMR Spectra | 1H-NMR Neff_WE et al.: C2: 2.31ppm; C8, 14: 1.75-1.85ppm; C9, 15: 4.40ppm; C10, 11, 12, 13, 16, 17: 5.25-6.90ppm; C18: 1.8ppm; OOH: 7.83-7.88ppm Neff_WE et al. |
Other Spectra | |
Chromatograms |
Reported Metabolites, References | |||||||||||||||||||||||||
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