LBF20307PG41: Difference between revisions

Latest revision as of 09:03, 21 October 2010

Upper classes: LB LBF

5-trans- Prostaglandin A₂

Structural Information
	(trans-5,trans-13)-(8R,12S,15S)-15-Hydroxy-9-oxoprost-5,10,13-trienoic acid
	5-trans- Prostaglandin A₂ (5E,13E)-(8R,12S,15S)-15-Hydroxy-9-oxoprost-5,10,13-trienoic acid
	5-trans- PGA_2
Formula	C20H30O4
Exact Mass	334.21440944799997
Average Mass	334.4498
SMILES	`C(CC[C@H](O)C=C[C@H]([C@H]1CC=CCCCC(O)=O)C=CC(=O)1)CC`
Physicochemical Information



	[ α ]_D +128°(CHCl₃) Bundy_GL et al.


	5-trans-Prostaglandin A_2 was isolated from Gorgonian, Plexaura homomalla. Bundy_GL et al.





Spectral Information
Mass Spectra	HREIMS m/z 478.2998 for TMS derivative C_{26}H_{46}O₄ Si₂, calcd 478.2932. Bundy_GL et al.
UV Spectra	λ _max 217 nm( ε 9050)) Bundy_GL et al.
IR Spectra
NMR Spectra
Other Spectra
Chromatograms

Reported Metabolites, References

Biospecies	ID	Compound Name	Reference	Comment
n.a.	LBF20307PG41	See above.	Bundy_GL et al. 1972

@@ Line 6: / Line 6: @@
 |LipidBank=XPR8054
 |LipidMaps=LMFA03010100
-|SysName= (5E, 13E) - (8R,12S,15S) -15-Hydroxy-9-oxoprost-5,10,13-trienoic acid
+|SysName=(trans-5,trans-13)-(8R,12S,15S)-15-Hydroxy-9-oxoprost-5,10,13-trienoic acid
-|Common Name=&&5-trans- Prostaglandin A_2&&
+|Common Name=&&5-trans- Prostaglandin A_2&&(5E,13E)-(8R,12S,15S)-15-Hydroxy-9-oxoprost-5,10,13-trienoic acid&&
 |Optical=[ alpha ]_D  +128°(CHCl_3 )[[Reference:Bundy_GL:Daniels_EG:Lincoln_FH:Pike_JE:,J. Am. Chem. Soc.,1972,94,2124|{{RelationTable/GetFirstAuthor|Reference:Bundy_GL:Daniels_EG:Lincoln_FH:Pike_JE:,J. Am. Chem. Soc.,1972,94,2124}}]]
 |Mass Spectra=HREIMS m/z 478.2998 for TMS derivative C_{26}H_{46}O_4  Si_2 , calcd 478.2932.[[Reference:Bundy_GL:Daniels_EG:Lincoln_FH:Pike_JE:,J. Am. Chem. Soc.,1972,94,2124|{{RelationTable/GetFirstAuthor|Reference:Bundy_GL:Daniels_EG:Lincoln_FH:Pike_JE:,J. Am. Chem. Soc.,1972,94,2124}}]]