LBF20406HP02: Difference between revisions

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|LipidMaps=-
|LipidMaps=-
|SysName=8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid/8-Hydroperoxy-5,9,11,14-Eicosatetraenoate
|SysName=8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid/8-Hydroperoxy-5,9,11,14-Eicosatetraenoate
|Common Name=&&8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid/8-Hydroperoxy-5,9,11,14-Eicosatetraenoate&&
|Common Name=&&8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid&&8-Hydroperoxy-5,9,11,14-Eicosatetraenoate&&
|Mass Spectra=GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,595|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,595}}]][[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]][[Reference:Rabinovitch_H:Durand_J:Rigaud_M:Mendy_F:Breton_JC:,Lipids,1981,16,518|{{RelationTable/GetFirstAuthor|Reference:Rabinovitch_H:Durand_J:Rigaud_M:Mendy_F:Breton_JC:,Lipids,1981,16,518}}]]: m/e=406[M]; 316[M-HOTMS]; 65[SMTO=CHCH=CHCH=CHCH2CH=CH(CH2)4CH3]; GC-EI-MS(Me-ester; after reduction and TBDMS)(114): m/e=448[M], 391[M-(CH3)3C]; GC-EI-MS(Me-ester;after reduction, hydrogenation and TMS)
|Mass Spectra=GC-EI-MS(Me-ester; after reduction and TMS)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,595|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,595}}]][[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]][[Reference:Rabinovitch_H:Durand_J:Rigaud_M:Mendy_F:Breton_JC:,Lipids,1981,16,518|{{RelationTable/GetFirstAuthor|Reference:Rabinovitch_H:Durand_J:Rigaud_M:Mendy_F:Breton_JC:,Lipids,1981,16,518}}]]: m/e=406[M]; 316[M-HOTMS]; 65[SMTO=CHCH=CHCH=CHCH2CH=CH(CH2)4CH3]; GC-EI-MS(Me-ester; after reduction and TBDMS)(114): m/e=448[M], 391[M-(CH3)3C]; GC-EI-MS(Me-ester;after reduction, hydrogenation and TMS)
|UV Spectra=UV[[Reference:Porter_NA:Logan_J:Kontoyiannidou_V:,J. Org. Chem.,1979,44,3177|{{RelationTable/GetFirstAuthor|Reference:Porter_NA:Logan_J:Kontoyiannidou_V:,J. Org. Chem.,1979,44,3177}}]] conjugated diene: <FONT FACE="Symbol">l</FONT>max=235nm, UV(Me-ester)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]] conjugated diene: <FONT FACE="Symbol">l</FONT>max=232.5nm, UV(Me-ester; after reduction)[[Reference:Porter_NA:Wolf_RA:Yarbro_EM:Weenen_H:,Biochem. Biophys. Res. Commun.,1979,89,1058|{{RelationTable/GetFirstAuthor|Reference:Porter_NA:Wolf_RA:Yarbro_EM:Weenen_H:,Biochem. Biophys. Res. Commun.,1979,89,1058}}]] conjugated trans, cis diene:<FONT FACE="Symbol">l</FONT>max=236nm, conjugated trans, trans diene: <FONT FACE="Symbol">l</FONT>max=232.5n
|UV Spectra=UV[[Reference:Porter_NA:Logan_J:Kontoyiannidou_V:,J. Org. Chem.,1979,44,3177|{{RelationTable/GetFirstAuthor|Reference:Porter_NA:Logan_J:Kontoyiannidou_V:,J. Org. Chem.,1979,44,3177}}]] conjugated diene: <FONT FACE="Symbol">l</FONT>max=235nm, UV(Me-ester)[[Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587|{{RelationTable/GetFirstAuthor|Reference:Terao_J:Matsushita_S:,Agric. Biol. Chem.,1981,45,587}}]] conjugated diene: <FONT FACE="Symbol">l</FONT>max=232.5nm, UV(Me-ester; after reduction)[[Reference:Porter_NA:Wolf_RA:Yarbro_EM:Weenen_H:,Biochem. Biophys. Res. Commun.,1979,89,1058|{{RelationTable/GetFirstAuthor|Reference:Porter_NA:Wolf_RA:Yarbro_EM:Weenen_H:,Biochem. Biophys. Res. Commun.,1979,89,1058}}]] conjugated trans, cis diene:<FONT FACE="Symbol">l</FONT>max=236nm, conjugated trans, trans diene: <FONT FACE="Symbol">l</FONT>max=232.5n

Revision as of 09:02, 20 December 2008


Upper classes: LB LBF



IDs and Links
LipidBank DFA8080
LipidMaps -
CAS
KEGG {{{KEGG}}}
KNApSAcK {{{KNApSAcK}}}
mol LBF20406HP02
8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid
Structural Information
8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid/8-Hydroperoxy-5,9,11,14-Eicosatetraenoate
  • 8-Hydroperoxy-5,9,11,14-Eicosatetraenoic Acid
  • 8-Hydroperoxy-5,9,11,14-Eicosatetraenoate
Formula C20H32O4
Exact Mass 336.23005951199997
Average Mass 336.46567999999996
SMILES C(CC=CCC=CC=CC(OO)CC=CCCCC(O)=O)CCC
Physicochemical Information
Spectral Information
Mass Spectra GC-EI-MS(Me-ester; after reduction and TMS) TeraoJet al. TeraoJet al. RabinovitchHet al.: m/e=406[M]; 316[M-HOTMS]; 65[SMTO=CHCH=CHCH=CHCH2CH=CH(CH2)4CH3]; GC-EI-MS(Me-ester; after reduction and TBDMS)(114): m/e=448[M], 391[M-(CH3)3C]; GC-EI-MS(Me-ester;after reduction, hydrogenation and TMS)
UV Spectra UV Porter_NA et al. conjugated diene: lmax=235nm, UV(Me-ester) TeraoJet al. conjugated diene: lmax=232.5nm, UV(Me-ester; after reduction) Porter_NA et al. conjugated trans, cis diene:lmax=236nm, conjugated trans, trans diene: lmax=232.5n
IR Spectra IR(me-ester; after reduction) Porter_NA et al. conjugated trans, cis diene: 985, 950cm-1, conjugated trans, trans diene: 989cm-1; IR(Me-ester) TeraoJet al.: OOH group: 3400cm-1
NMR Spectra 1H-NMR(Me-ester) TeraoJet al.: OOH: 8.3ppm
Other Spectra
Chromatograms
Reported Metabolites, References
Biospecies ID Compound Name Reference Comment
n.a. LBF20406HP02 See above. Pace-Asciak_CR et al. 1983
n.a. LBF20406HP02 See above. Peers_KE et al. 1983
n.a. LBF20406HP02 See above. Porter_NA et al. 1981
n.a. LBF20406HP02 See above. Porter_NA et al. 1979
n.a. LBF20406HP02 See above. Porter_NA et al. 1979
n.a. LBF20406HP02 See above. Rabinovitch_H et al. 1981
n.a. LBF20406HP02 See above. Spector_AA et al. 1988
n.a. LBF20406HP02 See above. Terao_J et al. 1981
n.a. LBF20406HP02 See above. Terao_J et al. 1981
n.a. LBF20406HP02 See above. Yamagata_S et al. 1983
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