LBF18107HO01: Difference between revisions

← Older edit
Editor (talk | contribs)
editors
12,511 edits
No edit summary
Editor (talk | contribs)
editors
12,511 edits
No edit summary
 
(12 intermediate revisions by the same user not shown)
Line 1: Line 1:
{{Lipid/Header}}
{{Hierarchy|{{PAGENAME}}}}
{{Hierarchy|{{PAGENAME}}}}


Line 4: Line 6:
|LipidBank=DFA8018
|LipidBank=DFA8018
|LipidMaps=LMFA01050121
|LipidMaps=LMFA01050121
|SysName=10-Ethoxy-9,13-Dihydroxy-11-Octadecenoic Acid
|SysName=10-Ethoxy-9,13-dihydroxy-11-octadecenoic acid
|Common Name=&&10-Ethoxy-9,13-Dihydroxy-11-Octadecenoic Acid&&
|Common Name=&&10-Ethoxy-9,13-dihydroxy-11-octadecenoic acid&&
|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415}}]]: m/e=343[M-173], 259[SMTO=CH-(CH2)7COOCH3], 173[SMTO=CH-(CH2)4CH3]
|Mass Spectra=GC-EI-MS(after methanolysis and trimethylsilylation)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415}}]]: m/e=343[M-173], 259[SMTO=CH-(CH2)7COOCH3], 173[SMTO=CH-(CH2)4CH3]
|IR Spectra=Isolated trans olefin(980-978cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), ether alcohol CO stretch(1090cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>), OH(3500-3420cm<SUP><FONT SIZE=-1>-</FONT></SUP><SUP><FONT SIZE=-1>1</FONT></SUP>) [[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613|{{RelationTable/GetFirstAuthor|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
|IR Spectra=Isolated trans olefin(980-978cm^{-1}), ether alcohol CO stretch(1090cm^{-1}), OH(3500-3420cm^{-1}) [[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613|{{RelationTable/GetFirstAuthor|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]
|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H-NMR: C9, 10(3.62ppm), C11, 12(5.63ppm), C13(4.12ppm), OH(5.6ppm), -OCH2CH3(1.16ppm), -OCH2CH3(3.44ppm)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415}}]]
|NMR Spectra=^1 H-NMR: C9, 10(3.62ppm), C11, 12(5.63ppm), C13(4.12ppm), OH(5.6ppm), -OCH2CH3(1.16ppm), -OCH2CH3(3.44ppm)[[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]][[Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415|{{RelationTable/GetFirstAuthor|Reference:Neff_WE:Frankel_EN:Scholfield_CR:Wesleder_D:,Lipids,1978,13,415}}]]
|Source=A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[the double bond: trans][[Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696|{{RelationTable/GetFirstAuthor|Reference:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1974,9,696}}]]. A bitter substansce in lecithin[[Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613|{{RelationTable/GetFirstAuthor|Reference:Sessa_DJ:Gardner_HW:Kleiman_R:Weisleder_D:,Lipids,1977,12,613}}]]. Production mechanism<!--8074-->.
|Chemical Synthesis=
|Metabolism=
}}
}}
{{Lipid/Footer}}

Latest revision as of 06:00, 15 April 2010

LipidBank Top
(トップ) 		Fatty acid
(脂肪酸) 		Glycerolipid
(グリセロ脂質) 		Sphingolipid
(スフィンゴ脂質) 		Journals
(雑誌一覧) 		How to edit
(ページの書き方)


Upper classes: LB LBF



IDs and Links
LipidBank DFA8018
LipidMaps LMFA01050121
CAS
KEGG {{{KEGG}}}
KNApSAcK {{{KNApSAcK}}}
mol LBF18107HO01
10-Ethoxy-9,13-dihydroxy-11-octadecenoic acid
Structural Information
10-Ethoxy-9,13-dihydroxy-11-octadecenoic acid
  • 10-Ethoxy-9,13-dihydroxy-11-octadecenoic acid
Formula C20H38O5
Exact Mass 358.271924326
Average Mass 358.51272
SMILES C(CCC(O)C=CC(C(O)CCCCCCCC(O)=O)OCC)CC
Physicochemical Information
A degradation product of hydroperoxylinoleate in the presence of Fe(III)-cystein[the double bond: trans] Gardner_HW et al.. A bitter substansce in lecithin Sessa_DJ et al.. Production mechanism.
Spectral Information
Mass Spectra GC-EI-MS(after methanolysis and trimethylsilylation) Gardner_HW et al. Neff_WE et al.: m/e=343[M-173], 259[SMTO=CH-(CH2)7COOCH3], 173[SMTO=CH-(CH2)4CH3]
UV Spectra
IR Spectra Isolated trans olefin(980-978cm-1), ether alcohol CO stretch(1090cm-1), OH(3500-3420cm-1) Gardner_HW et al. Sessa_DJ et al.
NMR Spectra 1H-NMR: C9, 10(3.62ppm), C11, 12(5.63ppm), C13(4.12ppm), OH(5.6ppm), -OCH2CH3(1.16ppm), -OCH2CH3(3.44ppm) Gardner_HW et al. Neff_WE et al.
Other Spectra
Chromatograms
[hide]Reported Metabolites, References
Biospecies ID Compound Name Reference Comment
n.a. LBF18107HO01 See above. Gardner_HW et al. 1974
n.a. LBF18107HO01 See above. Neff_WE et al. 1978
n.a. LBF18107HO01 See above. Sessa_DJ et al. 1977


Retrieved from "http://lipidbank.jp/mediawiki/index.php?title=LBF18107HO01&oldid=48510"