LBG00kkk:R:R:16402BC01: Difference between revisions

Editor (talk | contribs)
editors
12,508 edits
No edit summary
 
Editor (talk | contribs)
editors
12,508 edits
 
(9 intermediate revisions by the same user not shown)
Line 1: Line 1:
{{Lipid/Header}}
{{Metabolite
{{Metabolite
|LipidBank=EEL0208
|LipidBank=EEL0208
|SysName= (S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol
|SysName= (S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol
|Reflactive=[<FONT FACE="Symbol">a</FONT>]<sub>D</sub><sup>25</sup>=+7.5° (C0.83, CHCl<SUB><FONT SIZE=-1>3</FONT></SUB>)<<0174>>
|Common Name=&&(S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol&&
|Mass Spectra=(EI 70eV)69(100), 93(22), 121(10.6), 135(15.9), 161(5.7), 175(2.9), 189(1.9), 203(2.9), 225(2.4), 272(3.9), 389(M-CH<SUB><FONT SIZE=-1>3</FONT></SUB>, 2.1), 404(M<SUP><FONT SIZE=-1>+</FONT></SUP>, 0.7)<<0174>>,  
|Reflactive=[ alpha ]^{25}_D =+7.5° (C0.83, CHCl_3 )<<0174>>
|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H NMR (300MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)1.33(3H, s, CH<SUB><FONT SIZE=-1>3</FONT></SUB>), 1.42(3H, s, CH<SUB><FONT SIZE=-1>3</FONT></SUB>), 1.55-1.65(15H, m, 5CH<SUB><FONT SIZE=-1>3</FONT></SUB> on geranylgeranyl), 1.9-2.1(12H, br m, 6CH<SUB><FONT SIZE=-1>2</FONT></SUB> on geranylgeranyl), 3.38-3.68(3H, br m), 4.0-4.1(3H, m), 4.23-4.3(1H, m), 5.08[3H, br m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.3[1H, t, J=6.8Hz H at C(2) on geranylgeranyl]<BR><SUP><FONT SIZE=-1>1</FONT></SUP><SUP><FONT SIZE=-1>3</FONT></SUP>C NMR(75MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)16.1(q), 16.6(q), 17.8(q), 25.5(q), 25.8(q), 26.4(t), 26.7(t), 26.87(t), 26.93(q), 39.7(t), 39.81(t), 39.87(t), 67.1(t), 68.1(t), 71.1(t), 74.9(d), 109.5(s), 120.7(d), 123.9(d), 124.3(d), 124.5(d), 131.4(s), 135.1(s), 135.4(s), 140.6(s)<<0174>>,  
|Mass Spectra=(EI 70eV)69(100), 93(22), 121(10.6), 135(15.9), 161(5.7), 175(2.9), 189(1.9), 203(2.9), 225(2.4), 272(3.9), 389(M-CH_3 , 2.1), 404(M^+ , 0.7)<<0174>>,  
|NMR Spectra=^1 H NMR (300MHz,CDCl_3 )1.33(3H, s, CH_3 ), 1.42(3H, s, CH_3 ), 1.55-1.65(15H, m, 5CH_3  on geranylgeranyl), 1.9-2.1(12H, br m, 6CH_2  on geranylgeranyl), 3.38-3.68(3H, br m), 4.0-4.1(3H, m), 4.23-4.3(1H, m), 5.08[3H, br m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.3[1H, t, J=6.8Hz H at C(2) on geranylgeranyl]<BR>^{13}C NMR(75MHz,CDCl_3 )16.1(q), 16.6(q), 17.8(q), 25.5(q), 25.8(q), 26.4(t), 26.7(t), 26.87(t), 26.93(q), 39.7(t), 39.81(t), 39.87(t), 67.1(t), 68.1(t), 71.1(t), 74.9(d), 109.5(s), 120.7(d), 123.9(d), 124.3(d), 124.5(d), 131.4(s), 135.1(s), 135.4(s), 140.6(s)<<0174>>,  
|Chromatograms=silica gel flash chromatography (Rf=0.35, ethyl acetate-hexane(2:23) )<<0174>>,  
|Chromatograms=silica gel flash chromatography (Rf=0.35, ethyl acetate-hexane(2:23) )<<0174>>,  
}}
}}
{{Lipid/Footer}}

Latest revision as of 06:00, 15 April 2010

LipidBank Top
(トップ) 		Fatty acid
(脂肪酸) 		Glycerolipid
(グリセロ脂質) 		Sphingolipid
(スフィンゴ脂質) 		Journals
(雑誌一覧) 		How to edit
(ページの書き方)


IDs and Links
LipidBank EEL0208
LipidMaps [1]
CAS
KEGG {{{KEGG}}}
KNApSAcK {{{KNApSAcK}}}
mol LBG00kkk:R:R:16402BC01
(S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol
Structural Information
(S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol
  • (S) -1,2-O-Isopropylidene-3-O-geranylgeranylglycerol
Formula C29H56O3
Exact Mass 452.422945658
Average Mass 452.75314
SMILES O(C(C)(C)O)CC([H])C
Physicochemical Information
Spectral Information
Mass Spectra (EI 70eV)69(100), 93(22), 121(10.6), 135(15.9), 161(5.7), 175(2.9), 189(1.9), 203(2.9), 225(2.4), 272(3.9), 389(M-CH3, 2.1), 404(M+, 0.7)<<0174>>,
UV Spectra
IR Spectra
NMR Spectra 1H NMR (300MHz,CDCl3)1.33(3H, s, CH3), 1.42(3H, s, CH3), 1.55-1.65(15H, m, 5CH3 on geranylgeranyl), 1.9-2.1(12H, br m, 6CH2 on geranylgeranyl), 3.38-3.68(3H, br m), 4.0-4.1(3H, m), 4.23-4.3(1H, m), 5.08[3H, br m, H at C(6), C(10) and C(14) on geranylgeranyl], 5.3[1H, t, J=6.8Hz H at C(2) on geranylgeranyl]
13C NMR(75MHz,CDCl3)16.1(q), 16.6(q), 17.8(q), 25.5(q), 25.8(q), 26.4(t), 26.7(t), 26.87(t), 26.93(q), 39.7(t), 39.81(t), 39.87(t), 67.1(t), 68.1(t), 71.1(t), 74.9(d), 109.5(s), 120.7(d), 123.9(d), 124.3(d), 124.5(d), 131.4(s), 135.1(s), 135.4(s), 140.6(s)<<0174>>,
Other Spectra
Chromatograms silica gel flash chromatography (Rf=0.35, ethyl acetate-hexane(2:23) )<<0174>>,



Retrieved from "http://lipidbank.jp/mediawiki/index.php?title=LBG00kkk:R:R:16402BC01&oldid=60797"