LBG00ukk:R:16402BC01:16402BC01: Difference between revisions

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{{Lipid/Header}}
{{Metabolite
{{Metabolite
|LipidBank=EEL0211
|LipidBank=EEL0211
|SysName= (S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol
|SysName= (S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol
|Common Name=&& (S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol&&
|Common Name=&&(S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol&&
|Mass Spectra=(CI, methane) 69(100), 81(68.4), 93(29.9), 107(13.8), 123(26.3), 135(13), 149(15.5), 161(7.5), 171(4.6), 189(11.3), 207(34.9), 217(11.1), 273(18.4), 477(18.8), 545(2.5), 750(M+1, 1.3)<<0174>>,  
|Mass Spectra=(CI, methane) 69(100), 81(68.4), 93(29.9), 107(13.8), 123(26.3), 135(13), 149(15.5), 161(7.5), 171(4.6), 189(11.3), 207(34.9), 217(11.1), 273(18.4), 477(18.8), 545(2.5), 750(M+1, 1.3)<<0174>>,  
|NMR Spectra=<SUP><FONT SIZE=-1>1</FONT></SUP>H NMR (300MHz,CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>) 0.10(6H, s, 2CH<SUB><FONT SIZE=-1>3</FONT></SUB> on Si), 0.85(9H, s, 3CH<SUB><FONT SIZE=-1>3</FONT></SUB> on tert-butyl), 1.55-1.75(30H, m, 10CH<SUB><FONT SIZE=-1>3</FONT></SUB> on geranylgeranyl), 1.95-2.15(24H, br m, 12CH<SUB><FONT SIZE=-1>2</FONT></SUB> on geranylgeranyl), 3.44-3.65(5H, m), 3.95(2H, d, J=6.6Hz), 4.13(2H, d, J=6.8Hz), 5.05(6H, br m), 5.36(2H, m)<BR><SUP><FONT SIZE=-1>1</FONT></SUP><SUP><FONT SIZE=-1>3</FONT></SUP>C NMR(75MHz, CDCl<SUB><FONT SIZE=-1>3</FONT></SUB>)-5,2(q), 16.1(q), 16.7(q), 17.8(q), 18.4(q), 25.8(q), 26.0(q), 26.5(t), 26.8(t), 26.9(t), 39.7(t), 38.8(t), 63.1(t), 67.0(t), 70.8(t), 73.4(t), 78.6(d), 121.3(d), 123.9(d), 124.1(d), 124.3(d), 127.4(d), 127.5(d), 128.2(d), 131.1(s), 134.8(s), 135.1(s), 138.4(s),139.6(s)<<0174>>,  
|NMR Spectra=^1 H NMR (300MHz,CDCl_3 ) 0.10(6H, s, 2CH_3  on Si), 0.85(9H, s, 3CH_3  on tert-butyl), 1.55-1.75(30H, m, 10CH_3  on geranylgeranyl), 1.95-2.15(24H, br m, 12CH_2  on geranylgeranyl), 3.44-3.65(5H, m), 3.95(2H, d, J=6.6Hz), 4.13(2H, d, J=6.8Hz), 5.05(6H, br m), 5.36(2H, m)<BR>^{13}C NMR(75MHz, CDCl_3 )-5,2(q), 16.1(q), 16.7(q), 17.8(q), 18.4(q), 25.8(q), 26.0(q), 26.5(t), 26.8(t), 26.9(t), 39.7(t), 38.8(t), 63.1(t), 67.0(t), 70.8(t), 73.4(t), 78.6(d), 121.3(d), 123.9(d), 124.1(d), 124.3(d), 127.4(d), 127.5(d), 128.2(d), 131.1(s), 134.8(s), 135.1(s), 138.4(s),139.6(s)<<0174>>,  
|Chromatograms=TLC (Rf= 0.15 ethyl acetate-hexane(1:50))<<0174>>,  
|Chromatograms=TLC (Rf= 0.15 ethyl acetate-hexane(1:50))<<0174>>,  
}}
}}
{{Lipid/Footer}}

Latest revision as of 21:00, 14 April 2010

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IDs and Links
LipidBank EEL0211
LipidMaps [1]
CAS
KEGG {{{KEGG}}}
KNApSAcK {{{KNApSAcK}}}
mol LBG00ukk:R:16402BC01:16402BC01
(S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol
LBG00ukk:R:16402BC01:16402BC01.png
Structural Information
(S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol
  • (S) -1-O- (tert-butyldimethylsilyl) -2,3-di-O-geranylgeranylglycerol
Formula C51H94O3Si
Exact Mass 782.697223407
Average Mass 783.37576
SMILES C(C)(C)=CCCC(=CCCC(C)=CCCC(C)=CCOC([H])CO[Si](C(C)(C)C)(C)C)C
Physicochemical Information
Spectral Information
Mass Spectra (CI, methane) 69(100), 81(68.4), 93(29.9), 107(13.8), 123(26.3), 135(13), 149(15.5), 161(7.5), 171(4.6), 189(11.3), 207(34.9), 217(11.1), 273(18.4), 477(18.8), 545(2.5), 750(M+1, 1.3)<<0174>>,
UV Spectra
IR Spectra
NMR Spectra 1H NMR (300MHz,CDCl3) 0.10(6H, s, 2CH3 on Si), 0.85(9H, s, 3CH3 on tert-butyl), 1.55-1.75(30H, m, 10CH3 on geranylgeranyl), 1.95-2.15(24H, br m, 12CH2 on geranylgeranyl), 3.44-3.65(5H, m), 3.95(2H, d, J=6.6Hz), 4.13(2H, d, J=6.8Hz), 5.05(6H, br m), 5.36(2H, m)
13C NMR(75MHz, CDCl3)-5,2(q), 16.1(q), 16.7(q), 17.8(q), 18.4(q), 25.8(q), 26.0(q), 26.5(t), 26.8(t), 26.9(t), 39.7(t), 38.8(t), 63.1(t), 67.0(t), 70.8(t), 73.4(t), 78.6(d), 121.3(d), 123.9(d), 124.1(d), 124.3(d), 127.4(d), 127.5(d), 128.2(d), 131.1(s), 134.8(s), 135.1(s), 138.4(s),139.6(s)<<0174>>,
Other Spectra
Chromatograms TLC (Rf= 0.15 ethyl acetate-hexane(1:50))<<0174>>,



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