LBF18203HP01
LipidBank Top (トップ) |
Fatty acid (脂肪酸) |
Glycerolipid (グリセロ脂質) |
Sphingolipid (スフィンゴ脂質) |
Journals (雑誌一覧) |
How to edit (ページの書き方) |
IDs and Links | |
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LipidBank | DFA8056 |
LipidMaps | LMFA01040040 |
CAS | |
KEGG | {{{KEGG}}} |
KNApSAcK | {{{KNApSAcK}}} |
mol | LBF18203HP01 |
Methyl-10,12-epidioxy-9-hydroperoxy-13,15-octadecadienoate | |
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Structural Information | |
Methyl-10,12-epidioxy-9-hydroperoxy-13,15-octadecadienoic acid | |
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Formula | C19H32O6 |
Exact Mass | 356.219888756 |
Average Mass | 356.45378 |
SMILES | C(O1)(CC(C=CC=CCC)O1)C(OO)CCCCCCCC(=O)OC |
Physicochemical Information | |
Auto oxydation of linoleate Neff_WE et al. Coxon_DT et al.. Oxydation of linoleate in the presence of Fe(III)-ascorbic acid Toyoda_I et al.. Photoenhancemant of linoleate peroxydation[Type II] Neff_WE et al. Neff_WE et al.. Production mechanism Frankel_EN Frankel_EN . | |
It reacts with DNA in the presence of Fe ions and ascorbic acid Fujimoto_K et al.. | |
Major secondary products of linolenate by autooxidation Frankel_EN Neff_WE et al.. It is formed through 1, 3 cyclization of 12-peroxy radical of linolenate Frankel_EN Frankel_EN Frankel_EN Chan_HWS et al. Coxon_DT et al.. A level of epidioxy hydroperoxides produced by autooxidation of linolenate decreased by supplementation of antioxidants Peers_KE et al.. | |
Spectral Information | |
Mass Spectra | GC-EI-MS(after reduction(PH3P) and TMS) Neff_WE et al.: m/e=397[M-CH3]; 259[SMTO=CH(CH2)7COOCH3]; GC-EI-MS(after reduction with NaBH4 or KI andTMS) Frankel_EN et al.: m/e=259[SMTO=CH(CH2)7COOCH3]; 183[SMTO=CH-CH=CH-CH=CH-CH2CH3] |
UV Spectra | Conjugated diene: λ max=231-236nm ToyodaIet al. Neff_WE et al. Coxon_DT et al. Neff_WE et al. |
IR Spectra | OOH group: 3520 cm-1[free], 3700-3100cm-1[bonded]; olefinic protons: 3020-3000cm-1; CONJUGATE TRANS, CIS DIENES: 990-980cm-1, 955-947cm-1 Neff_WE et al. Coxon_DT et al. Neff_WE et al. Neff_WE et al. |
NMR Spectra | 1H-NMR Neff_WE et al. Neff_WE et al. Coxon_DT et al.: C9: 3.92-4.21; C10: 4.45-4.47; C11: 2.19-2.47, 2.81-2.87; C12: 4.77-4.80; C13: 5.57-5.62; C14: 6.65-6.68; C15: 5.96-6.65; C16: 5.50-5.55; OOH: 9.05-9.56ppm; J13-14=15Hz[C13-14 : trans]; J15-16=10Hz[C15-16: cis]13C-NMR Neff_WE et al. Neff_WE et al.: C9: 86.0; C10, 12: 83.8, 83.0 |
Other Spectra | |
Chromatograms |
Reported Metabolites, References | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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